Chemistry fundamentals Flashcards

(42 cards)

1
Q

ammonium

A

NH4+

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2
Q

Hydronium

A

H3O+

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3
Q

Acetate

A

CH3CO-

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4
Q

Bicarbonate

A

HCO3-

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5
Q

Cyanide

A

CN-

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6
Q

Hydroxide

A

OH-

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7
Q

Nitrate

A

NO3-

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8
Q

Nitrite

A

NO2-

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9
Q

Perchlorate

A

ClO4-

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10
Q

Carbonate

A

CO3(2-)

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11
Q

Sulfate

A

SO4(2-)

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12
Q

Sulfite

A

SO3(2-)

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13
Q

Phosphate

A

PO4(3-)

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14
Q

covalent bonds

A

are only formed between nonmetal elements

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15
Q

bond dissociation energy

A

the energy necessary for a complete separation of the bond is given by the vertical distance on the graph between the energy at the bond length and zero

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16
Q

nonpolar covalent bond

A

when electrons are shared equally between molecules with equivalent electronegativities

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17
Q

polar covalent bonds

A

when electrons are not shared equally because of a difference in electronegativity

18
Q

ionic bonds

A

occur most often between metals and nonmetals

19
Q

dipole moment

A

is an example of intermolecular forces and occurs when the center of positive charge in a bond does not coincide with the center of negative charges. given by the equation mew=qd. q is the magnitude of the charge at either end and d is the distance between the centers of charge

20
Q

strongest type of dipole-dipole interaction

A

hydrogen bond

21
Q

hydrogen bonds occur between

A

a hydrogen that is covalently bound to flourine, oxygen, and nitrogen

22
Q

cations that have large and small charges are designated differently as

A

ous for small

ic for big

23
Q

oxyanions are named

A

ate as the more oxygens

itse as the least amount of oxygens

24
Q

for acids the names for more oxygens and less

A
more = ous
less= ic
25
N units
kg ms-2
26
empirical formula
is the smallest ratio of whole numbers that can be used to represent these proportions
27
molecular formula
represent the exact number of elemental atoms in each molecule
28
percent yield equation
actual yield/theoretical yield *100
29
difference between thermodynamic and kinetic
thermodynamic product is more stable but it requires higher energy input and is produced more slowly. the kinetic product is less stable but can be formed more rapidly because the required energy input is lower. high temps favor the thermodynamic product while low temps favor the kinetic product
30
rate constant for chemical kinetics
rate constant is affected by pressure, catalysts, and temperature
31
reaction rate
describes how quickly the concentration of the reactants or products are changing over the course of the reaction
32
rate constant
molarity per second
33
steps after the slow step do not what? steps before the slow step do what?
contribute to the rate law while ones before do
34
heterogenous catalyst
is in a different phase than the reactants and products, such as when gas or aqueous particles react on a solid
35
reaction rates can be enhanced by
increasing the surface area of a catalyst
36
homogenous catalyst
is in the same phase as the reactants and products
37
a catalyst affects the
kinetics of a reaction but not the thermodynamics
38
reaction rate of reactions in gas vs liquid
in gas and liquids the reaction rate will be the similar in similar concentrations. The rate of a reaction is affected by stirring or shaking in liquids as well as increasing the temperature
39
radioactive decay
concerns atoms that spontaneously break apart
40
half-life
is the length of time necessary for one half of a given amount of substance to decay
41
half-life follows what order
first order reaction and the constant can be expressed as At=Aoe^(-kt)
42
beta-decay what particle is released
a neutron is broken down but a proton is added. meaning that the mass number stays the same. a neutrino is released which is a massless particle