chemistry of hydrocarbon Flashcards

(15 cards)

1
Q

C1-C4

A

GASES

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2
Q

C5–C17

A

LIQUIDS

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3
Q

C18 ONWARS

A

SOLIDS

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4
Q

whats the decreasing order of reactivity for free sub reaction of alkanes

A

f2>cl2>br2>i2

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5
Q

which radical is more reacitve?

A

3 degree radical

H in 3 deg radical is also more reactive

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6
Q

can free radical sub take place in dark?

A

no even if we increase the moles

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7
Q

methoads of preparation of alkane

A

wurtz reac
sebastier senden reac
reduction of R-X
hydrogenolysis

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8
Q

condition for partial hydrogenation of alkyne

A

pd(conc h2so4)/ quinoline

Ni / liq nh3 (-33C)

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9
Q

reactions of ethene

A

addition: MACHR (markonikov’s rule, addition of sulphuric acid, catalytic hydrogenation, halogenation, reaction with hbr)
oxidative: CHOPA (combustions, hydroxylation, ozonolysis, polymerization, addition of oxygen)

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10
Q

order of ease of addition of halogen in alkene

A

f2> cl2> br2> i2

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11
Q

order of reactivity of halogen acids

A

HI> HBR> HCL

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12
Q

WHEN DOES ETHENE POLYMERIZE TO POLYETHYLENE AND PLYTHENE?

A

AT 400C AND 100 ATM

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13
Q

RESONANCE ENERGY OF BENZENE

A

+150.5 KJ/MOL

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14
Q

sequence of hybridization in benzene

A

sp2 - sp3 - sp2

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15
Q

electrophile name always ends in -ium

A

nitronium (no2+)
chloronium (cl2+)
carbonium ch3+

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