chemistry of hydrocarbon Flashcards
(15 cards)
C1-C4
GASES
C5–C17
LIQUIDS
C18 ONWARS
SOLIDS
whats the decreasing order of reactivity for free sub reaction of alkanes
f2>cl2>br2>i2
which radical is more reacitve?
3 degree radical
H in 3 deg radical is also more reactive
can free radical sub take place in dark?
no even if we increase the moles
methoads of preparation of alkane
wurtz reac
sebastier senden reac
reduction of R-X
hydrogenolysis
condition for partial hydrogenation of alkyne
pd(conc h2so4)/ quinoline
Ni / liq nh3 (-33C)
reactions of ethene
addition: MACHR (markonikov’s rule, addition of sulphuric acid, catalytic hydrogenation, halogenation, reaction with hbr)
oxidative: CHOPA (combustions, hydroxylation, ozonolysis, polymerization, addition of oxygen)
order of ease of addition of halogen in alkene
f2> cl2> br2> i2
order of reactivity of halogen acids
HI> HBR> HCL
WHEN DOES ETHENE POLYMERIZE TO POLYETHYLENE AND PLYTHENE?
AT 400C AND 100 ATM
RESONANCE ENERGY OF BENZENE
+150.5 KJ/MOL
sequence of hybridization in benzene
sp2 - sp3 - sp2
electrophile name always ends in -ium
nitronium (no2+)
chloronium (cl2+)
carbonium ch3+