chemistry of life Flashcards

(49 cards)

1
Q

what charge does a nucleus have and why is this ?

A

the nucleus is positively charged and this is because it only contains protons and neutrons.
porotns are positively charged, whereas neutrons have a neutral/no charge

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2
Q

what is the mass of one proton/neutron ?

A

1 Da

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3
Q

what is an element ?

A

a pure substance that contains only one kind of atom

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4
Q

98% of organic tissues are made of only 6 elements. what are these elements ?

A

carbon, hydrogen, nitrogen, oxygen, phosphorous and sulphur

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5
Q

what is atomic number of an element ?

A

the number of protons in an antom of that element

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6
Q

what is the atomic weight of an element ?

A

is the average mass of a representative sample of atoms of that element, with all the isotopes in their normally occuring proportions

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7
Q

what are isotopes of an element ?

A

atoms with the same number of protons and eletrons but a different number of neutrons

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8
Q

why do isotopes of the same element behave in the same way in chemical reactions ?

A

because their electronic configuration has remained the same

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9
Q

what is a radioisotope ?

A

this is an unstable isotope and these spontaneously give off energy in the form of radiation. this comes from the atomic nucleus.

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10
Q

what is the spontaneous release of energy called in radioisotopes ?

A

radioactive decay - this release of energy transforms the original atom

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11
Q

what can radioisotopes be used as ?

A

tracers - living cells cannot distinguish between isotopes of the same element

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12
Q

what is an orbital ?

A

this is the volume of space within the atom where the electron is likely to be. This is because the location of a given electron in an atom is impossible to determine

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13
Q

the energy level of an electron is higher when in a shell …

A

farther from the nucleus

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14
Q

what is the octet rule ?

A

an atom will always tend to become stable by filling the outermost shell with 8 electrons

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15
Q

how are molecules formed ?

A

when two atoms with incomplete outer shells react, each atoms will share, donate, or receive electrons so that both atoms end up with complete outer shells. these atoms will then remain close forming a molecule

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16
Q

what is a compound ?

A

this is a pure substance made up of two or more different elements bonded together in a fixed ratio

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17
Q

what are the two main types of chemical bond ?

A

covalent bonds and ionic attractions

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18
Q

briefly explain what a covalent bond is ?

A

the sharing of electrons

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19
Q

briefly explain what ionic attractions are ?

A

is when an atoms gains or loses on or more electrons to achieve stability

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20
Q

when do chemical reactions occur ?

A

when moving atoms collide with sufficient energy to combine or to change their bonding partners

21
Q

when do covalent bonds form ?

A

when two atoms attain stable elctron numbers in their outermost shells by sharing one or more pairs of electrons

22
Q

what are the features of covalent bonds ?

A

they are very strong so require a lot of energy to break
at temperatures where life exists, the covalent bonds of biological molecules are quite stable
one bonds means 2 electrons are shared

23
Q

is the sharing of electrons in a covalent bond equal ?

24
Q

why is the sharing of electrons in covalent bonds not always equal ?

A

this is because atoms in a covalently bonded molecule continually compete for shared electrons. the attraction for shared electrons is called electronegativity and the more electronegative atoms pull harder .

25
what are ions ?
are electrically charged particles that form when atoms gain or lose one or more electrons
26
ions can form bonds that result in stable solid compounds. these are called
salts
27
ions can interact with polar molecules. this is because ...
both are charged
28
explain how salts dissolve in water using NaCl as an example .
water molecules surround the individual ions, separating them. the negatively charged chloride ions will attract the positive poles of the water molecules the positively charged sodium ions will attract the negative poles of water molecules the polarity of water is one reason it is such a good biological solvent
29
how do hydrogen bonds form ?
in water, the negatively charged oxygen atom of a water molecule is attracted to the positively charged hydrogen atoms of another water molecule.
30
are hydrogen bonds weak or strong ?
thry are weak but high numbers create a strong bond
31
why does water have a tetrahedral shape ?
the four pairs of electrons in the outer shell of the oxygen atom repel one another. this gives water molecules a tetrahedral shape
32
what are the properties of water ?
the ability of iceto float the melting and freezing temperatures of water the ability of heat to store and transfer heat (heat capacity) waters ability to dissolve many substances, and its inability to dissolve many others
33
why does ice float ?
in ice individual water molecules are held in place by hydrogen bonds. these are farther apart from one another in ice than they are in water. so ice is less dense than water and this is why it floats
34
what is the biological importance of ice floating ?
if ice sunk then a pond would freeze from the bottom up (becoming a solid block of ice in the winter) and it would kill most of the organisms living there. however because ice floats is forms this insulating layer on the top of the pond. this reduces heat flow to the cold air above and so fish, plants and other organisms are not subjected to temperatures lower that 0
35
what is meant by the specific heat capacity ?
the amount of heat energy required to raise the temperature of 1 gram of a substance by 1 degrees
36
why does water have a relatively high specific heat capacity ?
this is because there are many hydrogen bonds connecting the water molecules in ice, and these most be broken to change water from a solid to a liquid
37
specific heat capacity indicates the ability of a substance to ...
store heat e.g. water has a higher heat capacity compared to sand, and this is why sand cools much more quickly compared to water
38
water also has a high heat of vaporization. this means ...
a lot of energy is required to change water from its liquid to its gaseous state - a lot of the energy is used to break the many hydrogen bonds between the water molecules the heat must be absorbed from the environment in contact with the water
39
how does sweating cool the human body ?
sweat evaporates from the skin, and so it uses up some of the adjacent body heat
40
what is cohesion ?
cohesion is defined as the capacity of water molecules to resist coming aart from one another when placed under tension
41
explain the benefits of cohesion in trees ?
water's cohesive strength allows narrow columns of liquid water to move from the roots to the leaves of tall trees, so when water evaporates from the leaves, the entire column moves upwards in response to the pull of molecules at the top .
42
what is adhesion ?
this is the attraction of water molecules to other molecules of a different type
43
adhesion helps water repel ...
the force of gravity e.g. water will "cling" to vertical surfaces
44
why is the surface of water exposed to air difficult to puncture ?
because the water molecules at the surface hydrogen-bonded to other water molecules below them
45
a solution is produced when ...
a substance (the solute) is dissolved in a liquid (the solvent) -if the solvent is water then the solution is called an aqueous solution
46
what is pH ?
it is the concentration of hydrogen ions
47
why do we need to maintain a relatively stable pH in cells ?
chemical processes are very sensitive to concentration of hydrogen and hydroxide ions
48
how do buffers work ?
thry accept hydrogen ions from the solution when they are in excess -with buffers, biological fluids resist changes to their own pH
49
What huffer contributes to the ph stability in blood ?
carbonic acid