Chemistry Quantum Mechanic P1 Flashcards

(31 cards)

1
Q

Electromagnetic Radiation

A

A type of energy that travels through space at a constant speed of 3.00 x
108 m/s

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2
Q

Photon

A

A photon is a single “packet” of electromagnetic radiation. Photons can be considered
particles, but they have no mass

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3
Q

Amplitude

A

The height of a wave crest.

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4
Q

Wavelength

A

The distance between adjacent crests in a wave

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5
Q

Frequency

A

The number of cycles to pass through a stationary point in a given time. Usually measured
in Hertz (Hz) or cycles per second (s-1)

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6
Q

Planck’s Constant

A

6.626 x 10-34 J * s

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7
Q

Emission Spectrum

A

Wavelengths of light emitted by a particular element. The emission spectrum of
each element is unique and can be used to identify the element

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8
Q

Nuclear Model of the Atom

A

Model of the atom in which most of the atom’s mass, and all of its
positive charge, is concentrated in a small area called the nucleus. The nucleus us surrounded by a
negatively-charged electron cloud

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9
Q

Bohr Model of the Atom

A

A model of the atom in which electrons can only orbit the nucleus at specific
fixed “distances

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10
Q

Quantum Mechanical Model of the Atom

A

A model of the atom in which electrons occupy orbitals –
regions of space where an electron is likely to be found

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11
Q

Diffraction

A

When a wave passes through a small opening, it spreads out. Each opening acts as a new
wave source

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12
Q

Constructive Interference

A

When two waves with overlapping crests interact, the result is a wave with
twice the amplitude

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13
Q

Destructive Interference

A

When the crest of one wave overlaps with the trough of a different wave,
they cancel each other out

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14
Q

Two-Slit Experiment

A

An experiment that was used to demonstrate the wave-like nature of light and
electrons. When a beam of light, or electrons, passes through two slits, the resulting waves interfere

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15
Q

The de Broglie Wavelength

A

Quantifies the wave-like nature of matter

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16
Q

Complementary Properties

A

Properties that cannot be observed simultaneously. The more that is
known about one property, the less is known about the other

17
Q

Heisenberg’s Uncertainty Principle

A

The principle stating that due to the wave-particle duality, it is
impossible to precisely determine both the position and velocity of a particle at the same time.

18
Q

Orbitals

A

Regions of space where an electron is likely to be found.

19
Q

Shell

A

Shells are regions of space around an atom that can hold many orbitals. Each row of the periodic
table corresponds to a shell

20
Q

Orbital Types

A

There are four types of orbitals: s, p, d, and f. Each type has a different shape

21
Q

Degenerate Orbitals

A

Orbitals that have the same energy

22
Q

List 3 different types of electromagnetic radiation

A

Radiowaves, microwaves, gamma rays, x rays, visible light, uv light

23
Q

T/F Electromagnetic radiation has particle-like properties and wave-like properties.

24
Q

How do atoms emit light

A

When electrons fall from high to low energy state

25
What devices can be used to separate light into constituent colors, each with different energy?
Prism
26
Why did the discovery of the emission spectrum suggest the nuclear model revision
Nuclear model could not explain individual lines in emission spectrum
27
Why is the quantum mechanical model necessary? What flaws are in the Bohr model?
Bohr model only addresses hydrogen, We need it for other elements as well.
28
Since de Broglie wavelength applies to all objects regardless of size. Why cant we observe wave-like properties of macroscopic items like baseballs?
1. mass is too large compared to electron; causes the wavelength to decrease 2. wavelength goes unnoticed due to size difference
29
T/F In quantum mechanics, the observation of an event affects its outcome.
True
30
Why does Heisenberg's uncertainty principle cause orbitals to be considered regions of 3-d space where electrons are likely to be found rather than the path electrons travels?
The principle tells us that we cant know both velocity and position at the same time. Therefore we cant find its path traveled.
31
T/F orbitals represent the path traveled by an electron
False