chemistry semester 1 topic test Flashcards

(67 cards)

1
Q

John Dalton (1803):

A

Dalton introduced the modern atomic theory, suggesting that all matter is made of atoms, which are indivisible and indestructible particles. He also proposed that atoms of a given element are identical in mass and properties. ​He proposed the solid sphere model.

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2
Q

Dmitri Mendeleev (1869):

A

Mendeleev developed the periodic table, arranging chemical elements by atomic mass and predicting the existence and properties of undiscovered elements, demonstrating the periodic nature of the elements. ​

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3
Q

J.J. Thomson (1897):

A

Thomson discovered the electron through his experiments with cathode rays, proposing the “plum pudding” model of the atom, which depicted electrons embedded within a positively charged sphere. ​

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4
Q

Jean Baptiste Perrin (1909):

A

Perrin provided experimental evidence for the existence of atoms by studying Brownian motion, he determined the size of atoms and molecules.

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5
Q

Ernest Rutherford (1911):

A

Rutherford discovered the atomic nucleus by conducting the gold foil experiment, leading him to propose a model of the atom with a dense, positively charged nucleus surrounded by electrons. ​

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6
Q

Niels Bohr (1913):

A

Bohr proposed a model of the atom where electrons orbit the nucleus in discrete energy levels, explaining the stability of atoms. His model provided a simple visual aid of energy levels within an atom and how electrons were sorted within them. (positively charged nucleus with electrons around it)

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7
Q

Henry Moseley (1913):

A

Moseley determined that an element’s atomic number corresponds to the number of protons in its nucleus, leading to the reorganization of the periodic table based on atomic number rather than atomic mass. ​

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8
Q

Francis William Aston (1922):

A

Aston discovered isotopes using a mass spectrograph, demonstrating that elements can have atoms with the same number of protons but different masses due to varying numbers of neutrons. ​

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9
Q

James Chadwick (1932):

A

Chadwick discovered the neutron, a neutral particle within the atomic nucleus, which explained the existence of isotopes and led to a deeper understanding of atomic structure. ​

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10
Q

elements

A

the simplest substance only made up of one type of atom

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11
Q

what are atoms made of?

A

Atoms are made of protons and neutrons in the nucleus and electrons in electron shells.
Particle Relative Atomic Mass Charge
Proton 1 +1
Neutron 1 0
Electron 1/1836 -1

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12
Q

electron configuration

A
  • Electrons are not evenly spread but exist in layers called shells or energy levels.
    • The arrangement of electrons in these shells is often called the electron configuration.
    • Each shell has a maximum number of electrons that it can hold. Electrons will fill the shells closest to the nucleus first (attracted to the nucleus).
      ○ 1st shell: 2
      ○ 2nd shell: 8
      ○ 3rd shell: 8
    • Electron arrangement: eg (2, 8, 8)
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13
Q

elements on the periodic table

A

Elements are arranged in increasing atomic number (number of protons -> since all elements are neutral also the number of electrons).
Changes in the number of particles in the nucleus (protos or neutrons) are very rare. They only occur in nuclear processes such as radioactive decay, nuclear bombs, nuclear reactors.

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14
Q

relative atomic mass and isotopes

A

They also have a second larger number which is the relative atomic mass (number of protons + neutrons).
This number is usually not an integer and has decimal point because it is the average of all the isotopes (versions of the element with the same atomic number but different number of neutrons).
Properties of isotopes:
○ Virtually identical in their chemical reactions
○ Neutrons make little difference to chemical properties but do affect physical properties such as melting point and density.
Natural samples of elements are often a mixture of isotopes.

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15
Q

periodic table groups and trend

A

Tells you the number of valence electrons (electrons in the outer shell)
You skip the 10 columns of transition metals in the middle (1, 2 …, 3, 4, 5, 6 7, 0/8)
TRENDS DOWN A GROUP: number of valence electrons is same. Number of complete electron shells increases by one. Elements usually have similar chemical properties.

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16
Q

periodic table row and trend

A

Tells you the number of filled energy shells with at least one electron in them.
TRENDS ACROSS A PERIOD: the number of valence shell electrons increases by one. The number of complete outer shells stays the same.

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17
Q

group 1 and 2 (name and reactivity)

A

If something is in Group 1 + 2 it is alkali or alkali earth metals. They make up the S block and they are reactive metals. The reactivity of metal increases going down the group. This is because going down they toms are larger in size with more energy shells, meaning the valence electrons get further away from the nucleus so the force of attraction is weaker. The further an electron is from the positive nucleus the less energy it takes to be removed and the more reactive the element will be.

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18
Q

groups 3 - 12

A

Transition metals group 3 - 12 are less reactive and can sometimes have multiple valencies. They make up the D block.

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19
Q

poor metals

A

Poor metals a staircase that begins at aluminium with the first step having two elements aluminium and gallium. They make up the P block.

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20
Q

semi metals

A

have the properties of a metal and a non metal. A staircase from boron ending with polonium.

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21
Q

group 17 (reactivity and name)

A

Non metals: include halogen group 17 -> very reactive and dangerous. The reactivity of a non metal decreases going down the group because atoms of element get larger going down the group. The outer shell gets further away from the nucleus and is shielded by more electrons. The further the outer shell is from the positive attraction of the nucleus, the harder it is to attract another electron to complete the outer shell, decreasing reactivity.

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22
Q

what are the diatomic particles

A

There are 7 non metals that exist as diatomic particles: H, N, O, F, Cl, Br, I

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22
Q

group 18

A

Non metals also include the noble gases which are safe and don’t react with anything. All monatomic and do not form bonds with other elements. Similarly unreactive up and down the group.

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23
Q

valence electrons

A

the electrons in the outer shells

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24
Valency
the combining power of an atom and is equal to the number of hydrogen atoms it could combine with or displace from a compound.
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positive ions
cations
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negative ions
anions
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molecule
two or more atoms bonded together. only present in COVALENT substances
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ions
charged particles. only present in IONIC compounds
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Ionic bonds
Ionic compounds = metal ion + non metal ion Both have incomplete outer shells and hence unstable. Electron transfer for full outer shell. Positive and negative ions are attracted to each other due to electrostatic attraction.
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drawing ionic lattice
draw a 4x4 positive then negative square. label one of each atom and then bonds (held together by electrostatic attraction between oppositely charged ions). Give a title eg NaCl ionic lattice
31
drawing ionic particles
- Write the name of elements -> no circle for nucleus, first circle is the first shell. - DO NOT draw valence shell electrons (last shell is filled). Put brackets around the diagram and put the charge in the top right (loose or gain electrons).
32
covalent bonds
Non metal and non metal They share electrons This joins them together to form a covalent bong Consists of pairs of shared electrons. You can have a single (share two electrons), double (share 4) or triple (share 6) bonds.
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simplified dot and cross diagrams
There are two ways to draw a simplified dot and cross where you only draw the electrons in the outer shell or you can draw it with a sold line to show the amount of bonds (no electrons)
34
simple covalent structures
- These are covalent molecules that only contain a few atoms These substance have low melting and boiling points and hence are liquids or gases at room temperature. Eg water, oxygen, carbon dioxide - The covalent bonds within these molecules (intramolecular) are strong but the bonds between molecules (intermolecular) are weak and easy to break.
35
molecular solid
- Substances that contain simple covalent molecules but are solid at room temperature. Eg Iodine. - They form 3D molecular lattices and held together by weak forces of attraction. - Properties: low melting and boiling point, soft and brittle (usually) and cannot conduct electricity) ○ They have these properties because weak forces of attraction between the molecules can be broken by small amount of energy. Hence soft and brittle, low melting/boiling point. ○ They can't conduct electricity because there are no free electrons or ions to carry the charge.
36
lewis structures
- Show only valence electrons and the bonds and lone pairs that result. - Dots = lone pair Line = shared/bonded
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formula for ionic compounds
The metal always goes first The compound must have no charge - the charge of the elements have to cancel each other out. Criss cross the charges and then simply. E.g Na2O 2 Na+ ions are needed to balance a O 2- ions.
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neutralisation
when an acid and base react with each other to form a neutral substance ○ Acid + metal hydroxide -> salt + water ○ Acid + metal oxide -> salt + water ○ Acid + metal carbonate -> salt + water+ carbon dioxide ○ Acid + metal hydrogen carbonate -> salt + water + carbon dioxide
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metal and acid
○ Acid + metal -> salt + hydrogen
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metal and oxygen
Metal + oxygen -> metal oxide
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Precipitation:
the formation of a solid from two solutions AB (aq) + CD (aq) -> AD(s) + BC(aq) Must use state symbols
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* Combustion:
the exothermic oxidation of a substance Burning elements: A + B -> AB Burning compounds: Fuel + oxygen -> carbon dioxide + water
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Displacement:
when a more reactive element in a compound a less reactive element Metal and metal compound: AB + C -> A + BC Halogen and metal halide: A + BC -> AB + C
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ionic equations
Start by writing out the molecular formula, balanced and with state symbols, Then for any ionic substances in solution, or any molecular substances that ionise (acids but only sulfuric, nitric and hydrochloric eg 2H+(aq) and SO42-(aq) ) split them into their ions and write with state symbols. NOTE: solids will not separate and stay the same with no change and solid state symbol Then cancel out any spectator ions and both sides - these are ions that are not involved in the reaction. Rewrite the equation with only the species in reaction - this is the ionic equation Make sure the equation is balanced for both atoms and charge.
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oxidation
the loss of electrons, the gain of oxygen, the loss of hydrogen.
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reduction
the gain of electrons, the loss of oxygen, the gain of hydrogen
47
oil rig
"Oxidation is loss, Reduction is gain"
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half equation
must be balanced, oxidation have electrons as products, reduction have electrons as reactants.
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types of redox reactions
* Metal & Acid * Metal & Oxygen * Combustion * Displacement
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single displacement
Metal displacements only occur if the lone metal is more reactive then the metal already in the compound. If the lone metal is higher in the reactivity series then the displacement reaction occurs otherwise no reaction.
51
reactivity series
Potassium, Sodium, Calcium, Magnesium, Aluminium, Zinc, Iodine, Nickel, Tin, Lead, Copper, Silver, Gold, Platinum "Please Stop Calling Me A Zebra I Never Tried Liking Cute Silly Goofy Penguins"
52
precipitate
an insoluble solid that forms from an aqueous reaction.
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solubility table
ALL RULES * All group I salts are soluble * All ammonium salts are soluble * All nitrates are soluble * All ethanoates are soluble Assume that some that is slightly soluble is insoluble (you may see a precipitate form especially if produced in large quantities)
54
making observations
8. Describe observations for standard reactions using information on the data sheets. MAKING OBSERVATIONS 1) You need to describe a chemical change - What do the reactants look like? - What do you observe during the reaction? - What do the products look like? 2) You need to use unambiguous language: - Give the state solid, liquid, gas (do not say metal) - Colours (basic eg red, orange, yellow) - not silver or gold § Can use words like pale/bright - No colour = colourless - Clear (transparent) or opaque? - Do not really use translucent as it means kind of shimmery - Say is something is clear etc then the colour 3) Never use chemical names in observations
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observations of colour
The data sheet has information for solubility in precipitations, and the colour of precipitates if not white. Then also the colour of ions in aqueous solutions, and the colour of other gases and solids. It is also has the colour of halogens in different states.
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what is an observation
recognising and noting a fact or occurrence, what you see, feel, hear, smell, taste. Eg the liquid is clear and blue
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what is an inference
a proposed explanation that can be tested further by investigation eg if we add sodium hydroxide to the solution a blue precipitate will form.
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what is a hypothesis
a conclusion derived from observations. E.g the liquid is clear and blue therefore it is a copper solution
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mole
one mole of a substance is the relative atomic mass or relative formula mass in grams.
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avagadro's constant
one mole of any substance contains 6.022 x 10^23 atoms
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relative atomic mass
the average mass of an elements atoms compared to 1/12th of the mass of a carbon-12 atom (no unit because it is a ratio)
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relative formula mass
the mass of a compound or a molecule. You find it by writing down the written formula for the molecule, finding the atomic mass of each atom and add them together.
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molar mass
the mass of one mole of a substance (measured in grams) - worked out the same as relative formula mass,
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mole and mass calculations
N = m/Mr
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STP
At standard temperature and pressure (STP), defined as 0 deg C and 100kPa, one mole of gas occupies 22.71L.
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gas calculations
One mole of any gas occupies the same volume at a given temperature and pressure. n = V/22.71