Chemistry topic 1 Flashcards

(42 cards)

1
Q

What does the nuclear structure show you?

A

The atomic mass and the atomic number

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2
Q

What is the mass number?

A

The sum of protons and neutrons in the nucleus

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3
Q

What is the atomic number

A

The number of protons in the atom

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4
Q

What is the relative charge of a proton?

A

Positive, +1

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5
Q

What is the relative charge of an electron?

A

Negative, -1

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6
Q

What is the relative charge of a neutron?

A

Neutral, 0

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7
Q

What is the relative charge of an atom?

A

Positive

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8
Q

Where is the main mass of an atom?

A

In the nucleus

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9
Q

What is the maximum number of electrons allowed in the first four shells of an atom?

A

1 = 2 electrons
2 = 8 electrons
3 = 8 electrons
4 = electrons

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10
Q

How big is an atoms’ radius?

A

0.1 nanometers

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11
Q

How big is the radius of an atoms’ nucleus?

A

1 x 10 to the power of -14 (1/10 000 of an atom)

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12
Q

Describe an electron

A

Move in shells, negatively charged, their volume determines an atoms size, they have virtually no mass.

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13
Q

What is an element?

A

A substance which is made up of atoms that all have the same number of protons in their nucleus

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13
Q

What is an ion?

A

A type of atom that has either lost, or gained electrons to become either positive or negatively charged

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14
Q

Which part of an atom determines the type of atom it is?

A

The number of protons in its nucleus, eg. An atom with one proton in its nucleus is hydrogen but by two protons, it becomes helium.

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15
Q

What are the names of the following symbols?
Mg, O, C, Na, Fe, Pb

A

Mg = magnesium
O = oxygen
C = carbon
Na = sodium
Fe = iron
Pb = lead

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16
Q

What is an isotope?

A

An isotope is a different form of an element, which has a different number of neutrons but the same of protons. (So same atomic number, but different mass number). Eg carbon-12 and carbon-13

17
Q

What is relative atomic mass?

A

It is used to describe an element as a whole instead of a mass number because it takes into account the different masses and abundances (amounts) of all the isotopes that make up an element.

18
Q

What is the formula for relative atomic mass?

A

Sum of (isotopic abundance x isotopic mass number) divided by the total sum of abundances of all the isotopes.

19
Q

How do atoms join together to make compounds?
(Ionic and covalent)

A

When elements react, atoms combine to form a compound. Making bonds involves losing or gaining electrons, and when this happens to metals, the atom will become either a positive or negative ion. (This is called ionic bonding) whereas when this occurs with none metals, they share electrons, which is called covalent bonding.

20
Q

What does a formula show you?

A

What the atoms are in a compound, e.g carbon dioxide is made up of two oxygen and one carbon atom. (So it’s written as C02)

21
Q

Balancing symbol equations

A

The reactants need to equal the products so…
H2SO4 + NaOH goes to Na2SO4 + H2O

22
Q

What is a mixture REALLY?

A

There is no chemical bond (unlike a compound), there can be a mix of elements or compounds, easily separated by filtration (e.g saltwater). The properties of a mixture are just a mixture of properties which can be easily separated such as air into nitrogen, oxygen, carbon dioxide and argon.

23
Q

Explain in simple terms the steps for chromatography?

A
  1. Draw a pencil line near the bottom of a sheet of filter paper.
  2. Add a spot of ink to the line and place in a beaker of solvent. (Make sure the ink isn’t touching)
  3. The solvent will seep up the paper and carry the ink with it.
  4. The end result should be a chromatogram, you’ll be able to compare the results of different colours.
24
What is Filtration?
Can be used if your product is an insoluble solid, which needs to be separated from a mixture, Or it can be used for purification. Simply place some filter paper in pot a funnel, and pour the mixture into a beaker (the residue will be left behind).
25
What is the evaporation method?
1. Pour a solution into an evaporating dish. 2. Slowly heat (the solvent will evaporate and the solution will become gradually more concentrated) 3. Keep heating until you are left with dry crystals.
26
What is the method for crystallisation?
1. Pour the solution into an evaporating dish and gently heat, solvent will evaporate. 2. Once some crystals start to form, remove from the heat and leave to cool. 3. The salt should start to form crystals as it becomes insoluble in the highly concentrated, cold solution. 4. Filter the crystals and dry with towel or leave.
27
What is the method for separating rock salt? Clue…. (It uses both filtration and crystallisation)
1. Grind the mixture to ensure the crystals are small and will dissolve more easily. 2. Put the mixture into water and stir, only the salt will dissolve, not the sand. 3. Filter the mixture, the grains of sand will be left as residue. 4. Evaporate the water form the salt so it forms dry crystals.
28
Describe the method for simple distillation?
1. The solution is heated, the part with the lowest boiling point will evaporate first. 2. The Vapour is then cooled, condenses and is collected as a liquid. 3. The rest of the solution is left behind in the flask. You can use simple distillation to separate saltwater, as the water is condensed and you’ll be left with salt. However, the problem with it is the mixture of components have to have very different boiling points…
29
What is fractional distillation?
If you have a mixture of liquids with SIMILAR boiling points eg. Crude oil, then this method will work. 1. Place your mixture in a fractionating column, and heat (the lowest boiling point will evaporate first). 2. When the temp of the thermometer reaches the temp of its boiling point, it will reach the top of the column. 3. Liquids with higher boiling points will start to evaporate, but the column is taller towards the top so they’ll only get part way down before condensing agin. 4. Once the first liquid has been collected, you raise the temp of the Bunsen burner until the next one reaches the top.
30
How has the theory of atomic structure changed over time?
1. 19th century, John dalton describes the atom as a solid sphere, and spheres make up other elements. 2. 1897 and Jj Thompson concludes that the atoms weren’t solid spheres but a plum pudding (ball of pos charge, electrons stuck in it). 3. Rutherford uses the alpha particle experiment (fired alpha particles at a sheet of gold, some deflected some passed through), to prove the electron surround the nucleus. 4. Bohr discovered that the electrons must be in a shells, a certain distance from the nucleus. 5. Further experiments concluded that the nucleus contained protons. Then James Chadwick carried out an experiment proving that neutrons existed too!
31
Electronic structure rules:
- The shells closest to the nucleus are always filled first. - atoms are much happier with a full shell, however most atoms don’t have a full outer shell, making them more reactive. - only a certain amount of electrons allowed per shell 1st = 2, 2nd = 8 3rd = 8 4th = 2
32
How were elements arranged in the periodic take in the 1800s?
- By relative atomic mass + their physical and chemical properties. - the scientists had no idea about atomic structure and could only measure atomic mass.
33
Who developed the periodic table? And how?
Dmitri Mendeleev 1869, categorised elements in order of atomic mass, or similar properties. He left gaps to ensure all elects stayed in similar groupings. HOWEVER…………. the discovery of isotopes confirmed that Mendeleev should have considered properties as isotopes of the same element have different chemical properties.
34
How is the modern periodic table arranged?
- in order of increasing atomic (proton) number, meaning there are repeating patterns periodically -metals and non metals - the rows are called periods, each representing another full shell of electrons. - elements with similar properties from Columns (groups).
35
What are the properties of metals?
- metals are elements which can form positive ions when they react. - metallic bonding (which causes them to have similar physical properties). - strong, malleable, good conductors, high melting and boiling points.
36
What are the properties of non metals?
- don’t form positive ions - tend to look dull - brittle, low density and don’t conduct
37
How does the electronic structure of an atomic affect how well they’ll react?
Atoms generally react to form a full outer shell, they do this by losing or gaining electrons. - Metals to the left of the periodic table don’t have many electrons to remove, and metals to the bottom have electrons which are a long way from the nucleus so weaker attraction, meaning it’s easy to form positive ions. - non metals to right if the table have lots of electrons, and non metals towards the top have a electrons with a strong attraction, so it’s hard for them to share or gain electrons.
38
What are the properties of the group 1 elements? (ALKALI METALS)
- alkali metals lithium, sodium etc… - one electron in their outer shell increases reactivity -soft, low density. - going down the group, the reactivity increase, lower boiling/melting points, and higher atomic mass. - form ionic compounds with non metals. - produces hydrogen gas when reacting with water. - reaction with chlorine produces a salt. - react with oxygen to form oxide/ peroxide/ superoxide.
39
What are the properties of the group 7 elements? (Halogens)
- all non metals, with coloured vapours, Fluorine (yellow gas), chlorine (green gas), Bromine (red brown volatile liquid), iodine (purple vapour). - become less reactive down the group, higher boils/melting points and higher atomic masses. - all have 7 electrons in the outer shell. - form molecular compounds (covalent bonding) - form ionic bond with metals - more reactive halogens will displace less reactive ones
40
What are the properties of the group 0 elements? (Noble gases)
- all colourless gases (don’t react) - boiling points will increase due to an increased number of electrons. -they are unreactive as they all have full outer shells of electrons. -includes neon, helium, argon etc…
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