CI 1 Flashcards

1
Q

What conditions are needed for making ammonia?

A

Iron catalyst
High pressures
High temperature (450C)

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2
Q

Why is a nitrogen molecule very unreactive?

A

Triple bond
High bond enthalpy

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3
Q

Ammonia (gas) formula

A

NH3

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4
Q

What bonds does an ammonia molecule have?

A

1 lone pair
3 N-H single bonds

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5
Q

What does the lone pair in ammonia do?

A

Allows it to form dative covalent bonds
Allows it to act as a base
To form an ammonium ion

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6
Q

Ammonium ion formula

A

NH4+

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7
Q

Equation to convert ammonia to ammonium

A

NH3 + H+ = NH4+

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8
Q

What bonds do ammonium ions have?

A

1 dative bond
3 single bonds

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9
Q

What color is NO?

A

Colorless gas

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10
Q

What color is NO2?

A

Brown gas

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11
Q

What color is N2O?

A

Colorless gas

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12
Q

Where does nitrogen (IV) oxide come from?

A

Formed from oxidation of NO in the atmosphere

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13
Q

Where does dinitrogen (I) oxide come from?

A

Formed in the soil by denitrifying bacteria

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14
Q

What happens to nitrate ions when oxygen levels are low?

A

anaerobic bacteria reduce them to nitrogen
NO3- -> NO -> N2O -> N2

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15
Q

Nitrate (V) formula

A

NO3-

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16
Q

What is the formula for nitrite?

A

NO2-
Aka nitrate (III)

17
Q

What is the equation for the formation of the nitrate (III) ion?

A

NH4+ + 1.5O2 -> NO2- + 2H+ + H2O

18
Q

What is the equation for the formation of the nitrate (V) ion?

A

Further oxidation from the nitrate (III) ion

NO2- + 0.5O2 -> NO3-

19
Q

How do we test for ammonium ions?

A

1) add sodium hydroxide
2) heat gently
3) Ammonia should be given off

20
Q

How do we test for nitrate (V) ions?

A

1) add sodium hydroxide
2) add Devarda’s alloy
3) heat gently
4) damp red litmus paper turns blue

21
Q

Test for ammonia gas?

A
  • Strong smell
  • Red litmus turns blue
  • white fumes with hydrogen chloride gas from HCL
22
Q

How do you conduct the brown ring test to test for nitrate ions?

A

-Add iron sulfate
-Add concentrated sulfuric acid
-Watch for a brown ring in the test tube

23
Q

What is the bond shape and angle of an ammonia molecule?

A

Pyramidal
107 degrees

24
Q

What is the bond shape and angles of an ammonium ion molecule?

A

Tetrahedral
90 degrees