combustion Flashcards

1
Q

describe combustion

A

combustion reacts give out heat and have large negative enthalpies

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2
Q

what happens when there is more carbon present during a combustion reaction

A

the more carbons present, the greater the heat output

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3
Q

define a fuel

A

substances that release heat energy when they undergo combustion

they also store a large amount of energy for a small amount of weight

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4
Q

define incomplete combustion

A

when fuels are burnt in a limited supply of oxygen, the poisonous gas carbon monoxide, CO is formed

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5
Q

when is incomplete combustion most common

A

incomplete combustion often happens with long chain hydrocarbons which need more oxygen to burn compared with shorter chains

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6
Q

state all pollution products that may occur when hydrogen-carbon based fuels burn

A

carbon monoxide
nitrogen oxides
sulfur dioxide
particulates
sulfur dioxide
unburnt hydrocarbons
carbon dioxide
water vapour

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7
Q

how is carbon monoxide made

A

by incomplete combustion

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8
Q

how are nitrogen oxides produced

A

when there is enough energy for nitrogen and oxygen in the air to combine

For example, this happens in a petrol engine at high temperatures present. these oxides may react with water vapor and oxygen in the air to form nitric acid. they are therefore contributors to acid rain and photochemical smog

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9
Q

what are the three type of nitrogen oxide

A

NO
NO2
N2O4

THEY ARE OFTEN ABBREVIATED TO NOX

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10
Q

How is sulfur dioxide made

A

it is produced from sulfur-containing impurities present in crude oil. this oxide combines with water vapour and oxygen in the air to form sulfuric acid

sulfur dioxide is a contributor to acid rain

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11
Q

what can carbon particulates do

A

exacerbate asthma and cause cancer

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12
Q

what do unburnt hydrocarbons do

A

unburnt hydrocarbons may enter the atmosphere and these are significant greenhouse gases

they contribute to photochemical smog which can cause a variety of health problems

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13
Q

what does sulfur dioxide do

A

a gas that causes acid rain by combining oxygen and water in the atmosphere to form sulfuric acid

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14
Q

what are the gases given out by power stations called

A

flue gases

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15
Q

what is the process of removing sulfur dioxide called

A

flue gas desulfirisation

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16
Q

explain the method of flue gas desulfirisation

A

a slurry of calcium oxide and water is sprayed into the flue gas which reacts with the calcium oxide and water to form calcium sulfite, which can be further oxidized to calcium sulfate this is also called gypsum

17
Q

define gypsum

A

gypsum is a saleable product as it is used to make builders’ plaster and plasterboard

18
Q

what happens in the alternative process of flue gas desulfirisation

A

an alternative process uses calcuim carbonate rather than calcuim oxide

19
Q

what produces the most of the pollutatnts

A

the internal combustion engine produces most of the pollutants, though sulfur is now removed from petrol so that sulfur dioxide has become less of a problem

20
Q

what do all new cars have

A

all new cars with petrol engines are now equipped with catalytic converters in their exhaust systems.

these reduce the output of carbon monoxide, nitrogen oxides, and unburnt hydrocarbons in the exhaust gas mixture

21
Q

what is the catalytic convertor made of

A

the catalytic convertor is a honeycomb made of ceramic material coated with platinum and rhodium metals

these are the catalysts.

22
Q

what does the honeycomb shape provide for the catalytic convertor

A

an enormous surface area, so a little of expensive metals goes a long way

23
Q

what happens with the polluting gases in the catalytic convertor

A

as the polluting gases pass over the catalyst, they react with each other to form less harmful products

the reactions take place on the surface of the catalyst, on the layer of platinum and rhodium metals

24
Q

explain why greenhouse gases become very warm inside

A

green house gases become very warm inside.

visible rays from the sun pass through the glass

rather than escaping their energy is absorbed by everything inside the greenhouse and re-radiated as infrared energy, which is heat

infrared energy has a longer wavelength and cannot pass back out through the glass

25
Q

why is carbon dioxide important

A

it traps infrared radiation so that the Earth’s atmosphere heats up

this is important for life because, without carbon dioxide and other greenhouse gases, the earth would be too cold to sustain life

26
Q

why does the concentration of water vapour stay roughly the same

A

because of the equilibrium that exists between the water vapour and liquid water

27
Q

what would happen if the temperature of the atmosphere rises

A

there will be more water vapour in the air and therefore more greenhouse warming.

this may be offset by greater cloud formation and clouds reflect solar radiation

28
Q

define carbon-nuetral

A

activities that produce no cabron dioxide emissions overall are referred to as carbon neutral