Concrete Flashcards
(151 cards)
Manufacture process of cement
- begins w/ decomp of CaCO₃ @ ~900°C
- leaves calcium oxide CaO + libreates gaseous carbon dioxide (calcination)
- clincering process, CaO reacts @ high temp (1400-1500°C) w/ silica, alumina, ferrous oxide to form silicates, aluminates, ferrites of calcium which comprise the clincer
- clincer ground/milled together w/ gypsum + other additives to produce cement
decomp of CaCO3
CaCo₃–> CaO + CO₂
concrete
construction material composed of crushed rock/gravel + sand bound together w/ a hardened paste of cement and water
basic materials of concrete
- cement
- aggregates
- water
- admixtures
- voids
portland cements
- Ordinary Portland Cement (OPC)
- Rapid Hardening Portland Cement (RHPC)
- Sulphate Resistant Portland Cement (SRPC)
- White Portland Cement (WPC)
Portland cement - raw materials in clinker
- limestone
- iron stone
- sand
- shale
- clay
- other
unsustainability of cement manufacturing
- manif results in high levels of CO₂ output, third ranking producer of anthropogenic CO₂ in world
- 1 tonne of cement prod 780kg of CO₂
- 4-5% of total CO₂ emissions worldwide caused by cement prod
- extraction + processing: landscape degradation
- dust + noise pollution
- energy consumption + vehicle pollution of transportation
anthropogenic
man-made
cement manufacture
- limestone, shale, silica, iron oxides quarried from ground
- rock materials run thru crusher that turns rock into smaller pieces
- crushed limestone + Si + shale + iron oxides mixed together and run thru rotary kiln
- rotary kiln continuously mixes ingredients + “calcines” limestone so that CO₂ is driven off, forming clinker
- clinker ground to fine powder + mixed w/ gypsum (helps moderate how fast cement sets)
- bagged for sale
alternative cementitious (cement-like) materials
- blastfurnace slag cement (GGBS)
- pulverised-fuel ash cement (PFA)
- metakaolin
- rice husk ash
- silica fume
GGBS
- by-prod of iron smelting, quenched slag forms granules
- generally blended with OPC up to 70%
- reduced early age strength + early heat of hydration
- lower carbon footprint
how cements in Europe are classed
-based on perc of portland cement that has ben replaced/substituted
classes of cements in Europe
CEM I - OPC/RHPC (100% cement)
CEM II (65% cement)
CEM III (45% cement)
CEM IV (<45%)
CEM II-IV: OPC with limestone, PFA, or GGBS
when water is added to cement
- each compound undergoes hydration + contributes to final concrete product
- only calcium silicate contributes to strength
- tricalcium silicate: early strength, reacts more rapidly
- dicalcium silicate: late strenth
equation of hydration
Cement + H₂O -> Calcium Silicate Hydrate (C-S-H) + Ca(OH₂) + H₂O
cement compounds
Tricalcium Silicate C₃S
Dicalcium Silicate C₂S
Tricalcium aluminate C₃A
Tetracalcium aluminoferrite C₄AF
Gypsum
setting of cement and hardening of concrete
- a process of crystallization
- crystals form after certain length of time (initial set time), + interlock w/ each other
- cement + water that has crystallized in this way encloses aggregate particles + produces dense material
heat effect on setting and hardening
- speeds up setting + hardening of cement
- cold slows down + can even completely stop process
cement hydration
- setting + hardening results from chem reaction between cement + water, not drying process
- reaction exothermic + irreversible
- heat produced: “Heat of Hydration”
- usually workable up to 2 hours before it begins to set, then harden
- strength gain initially rapid, becoming progressively less
- strength gain continues indefinitely, provided moisture present (CURING)
cement at start of hydration vs at end
- hydration not yet occured, pores filled with water
2. hardening cement paste, majority of space filled with C-S-H
heat of hydration evolution stages
stage 1 stage 2 stage 3 stage 4 stage 5
stage 1
- initial dissolution
- hydrolysis of cement compounds occur rapidly w/ significant temp increase
stage 2
- dormant period
- evolution of heat slows down
- conc in a plastic state which allows problem free transportation + placing
stage 3 + 4
- concrete starts to harden
- heat evol increases due to hydration of tricalcium silicate