Conductivity - Fang Flashcards

(37 cards)

1
Q

what are the uses of electric properties of materials?

A

1 - computing (nanotech)
the processing and transmissions of information electronically
2 - fibre optic communication for insulators
3 - transportation locking devices semiconductor uses
4 - healthcare pacemakers which stimulate the hearts
5 - energy a lot of oxide semiconducting materials, e.g. for silicon in solar panels

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2
Q

what did jj thomson do?

A

discovered the electron via
catthode rays in a device were streams of negatively charged particles
by varying the magnitude of e fields and magnetic fields found mass to charge ratio

electrons were basic constituent of all matter
1000 times lighter than hydrogen

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3
Q

what are charge carriers?

A

an atomic scale species in which the conduction of electricity in materials occurs

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4
Q

what are the types of charge carriers?

A

electrons - simplest with 1.6 x 10-19 of charge
holes - abstract concept, missin gelectron in an electron cloud with 1.6 x 10-19 of positive charge

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5
Q

what are anions and cations?

A

they are charge carries in ionic materials
a serves as negative charge carries 1.6 x 10-19
c serves as positive charge carrier of 1.6 x 10-19

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6
Q

fill in the blank
the valence of each ion indicates ____ or ______ charge in _____ of single electron charge

A

the valence of each ion indicates positive or negative charge in multiples of single electron charge

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7
Q

how can we find the conductivity?

A

the reciprocal of resistivity is conductivity, sigma
sigma = 1/rho so per ohm per metre

respectively, to find conductance = 1/resistance per ohm

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8
Q

what is joule heating?

A

the passage of electrons through a material
creates generation of heat
due to large number of collisions

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9
Q

simple planetary model of atomic structure

A

electrons orbit around a nucleus (sun)

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10
Q

pauli exclusion principle

A

no two electrons can occupy precisely the same state

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11
Q

using the pauli exclusion principle, explain how the solid sodium has half an energy level

A

large number of atoms release the electron in the outer energy level which all lie on the 3s energy level. each electron slightly on a higher energy level. because the spacing is minimal, the valence energy band is half-filled permitting high mobility with outer electrons
the energy termed is the valence band

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12
Q

what happens when the temperature is 0k?

A

the energy levels of the valence band are completely full up to the midpoint

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13
Q

define fermi level

A

the energy of the highest filled state in the energy band at 0k

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14
Q

define the fermi function

A

the probability that an energy level is occupied by an electron

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15
Q

why are metals good electrical conductors?

A

thermal energy sufficient enough in promoting electrons above fermi level towards unoccupied energy levels
the accessibility of unoccupied levels in adjacent atoms yield high mobility of conduction electrons
known as free electrons through solid

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16
Q

what happens to conductivity in metals as temperature increases?

A

decreases
due to the drop in electron mobility, as thermal agitation increases in a crystalline structure
wavelike electrons can move through crystalline structure effectively when structure is perfect

17
Q

what is drude’s first assumption

A

matter consists of
1 - lightly negatively charged ions which are mobile
2 - heavy static ions which are static

18
Q

drude’s second assumption

A

the only interactions is electron ion interactions which take place over a very short time
1 - the electron-electron interaction is neglected
2 - the electron-ion interaction is neglected

19
Q

drude’s third assumption

A

the probability of electron having a short collision time is dt/t

20
Q

drude’s fourth assumption

A

after each collision an electron emerges in a random direction and with a speed which is appropriate to the local temperature

21
Q

mean free path of an electron

A

the average distance travelled by an electron between two successive collisions inside the metal in the presence of the applied field

22
Q

why are electrons almost negligible in insulators compared to conductors?

A

as insulators have a large band gap, most electrons do not have have enough energy to be promoted to the conduction band

23
Q

what is they key factor for insulators density?

A

n carrier density, really low, therefore conductivity is really low

24
Q

capacitor

A

parallel plate insulator between two metal electrodes, the charge will build up on capacitor surface

25
charge density
directly proportional to electric field strength
26
dielectric strength
limiting voltage gradient, which appreciable current flow occurs and the dielectric fails
27
semi conductor
matierals with conductivity intermidiate between those of conductors and insulators
28
intrinsic elemental superconductors
both electrons and holes are charge carriers; the number of electrons is equal to the number of holes a hole is missing due to a valence electron
29
in semi conductors why does the conductivity increase with temperature?
the number of electrons that are able to jump from valence band to conduction band increases as charge carrier increases exponentially
30
hall effect
if current is affected by the magnetic field there should be a state of stress the electricity passing through one side of the wire
31
how is the hall voltage generated?
during magnetic field charge carriers experience a force - lorentz charge carriers detour inducing an electric force which is equal and opposite to lorentz force seperation of charge creates a steady an electric field, and a voltage - hall
32
extrinsic semi conductor
results from impurity additions such as dopants there is ntype (negative) and ptype (positive)
33
what is the difference between an n type and p type semi conductor?
with the example silicon phosphorus in an n type dopant because it has 5 electrons, one extra in conduction band aluminium is a p type dopant as it has 3 valence electrons, the shortage of one electron can become a hole
34
describe n-type si
4 out of 5 electrons in P is needed for bonding the extra electron is relative unstable and produces a donor level near the conduction band as a result the conduction band is Eg - Ed
35
describe p-type si
a 3 electrons are used for bonding, but with 1 missing al's hole is in acceptor level near the valence band and an si electron is easily promoted to this level creating a hole the fermi level is shifted downwards
36
what is the general observation of the p-n junction
when voltage is applied to the junction, the holes go to the negative electrode and the electrons go to the positive electrode only a minimal current can flow this reverse bias leads to the polarisation of the diode if voltage is reversed forwards bias occurs
37