Crude oil, hydrocarbons and alkanes. Flashcards

Fractional distillation, combustion,

1
Q

What is crude oil

A

A finite resource consisting mainly of plankton that was buried in the mud- crude oil is the remains of ancient biomass formed in covalent bonds.

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2
Q

What are hydrocarbons

A

These are compounds made of hydrogen and carbon, they make up the majority of the compounds in crude oil and most of them are alkanes.

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3
Q

What is the general formula for alkanes

A

CnH2n+2

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4
Q

How are alkanes formed?

A

The cracking of longer chained alkanes.

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5
Q

What is methanes chemical configuration

A

CH4

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6
Q

What is ethane’s chemical configuration?

A

C2H6

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7
Q

What is propanes chemical configuration?

A

C3H8

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8
Q

What is butane’s chemical configuration?

A

C4H10

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9
Q

What are alkenes

A

Alkenes are hydrocarbons with a double bond (some formed during the cracking process)

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10
Q

State the test for alkenes and properties.

A

Alkenes are more reactive than alkanes and react with bromine water. Bromine water changes from orange to colourless in the presence of alkenes.

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11
Q

What are fractions?

A

The hydrocarbons in crude oil split into fractions. Each fraction contains molecules with a similar number of carbon atoms in them, all fractions have different boiling points. This process is fractional distillation.

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12
Q

What are the fractions used as?

A

Fractions can be processed to produce fuels and feedstock for petrochemical industry.

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13
Q

State examples of fractional distillation fuels

A

Kerosene, petrol diesel etc

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14
Q

State 3 examples of useful materials made by the petrochemical industry

A

Solvents, lubricants, polymers.

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15
Q

What is cracking

A

The breaking of long chain hydrocarbons into the smaller chains. The smaller chains are more useful and can be done by either catalytic cracking steam cracking.

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16
Q

What is catalytic cracking?

A

The heavy fraction is heated until vaporised. After vaporisation, the vapour is passed over a hot catalyst in a cracker forming smaller, more useful hydrocarbons.

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17
Q

What is steam cracking?

A

The heavy fraction is heated until vaporised. After vaporisation, the vapour is mixed with steam in a cracker and heated to a very high temperature forming small, more useful hydrocarbons.

18
Q

What 3 alkenes/alkanes form decane?

A

Pentane, propene, ethane

19
Q

What are alkenes used to produce?

A

They produce polymers and also used as the starting materials of many other chemicals, such as alcohol, plastics and detergents.

20
Q

Why do we crack king hydrocarbon chains?

A

Without cracking, many of the long hydrocarbons would be wasted as there is not much demand for these as for the shorter chains.

21
Q

What is the word equation for complete combustion

A

Oxygen + alkane (ethane) = water + carbon dioxide + energy

22
Q

What is the word equation for incomplete combustion?

A

Alkane (ethane) + oxygen = carbon + carbon monoxide + water + energy

23
Q

What is the equation for alkenes

A

CnH2n

24
Q

What does crude oil need in order to be formed ( 5 things)

A

The remains of dead animals / plants - plankton and algae
No oxygen
High temperatures
High pressures - layers of sand/dirt/rock
Millions of years

25
Q

What is meant by the term ‘homologous series’

A

A collection of compounds with the same general formula that differ only in the carbon chain length.

26
Q

Differences between alkanes / alkenes

A

Alkanes
-no double bonds
-saturated
-less reactive
Alkenes
-double bond (only one)
-unsaturated
-more reactive

27
Q

What does saturated mean?

A

Only single bonds and bonds cannot be broken.

28
Q

As the molecule increases, the boiling point..

A

Increases

29
Q

As the molecule increases, the volatility (cleaner flame)….

A

Decreases, larger molecules have more of an unclean flame

30
Q

As the molecule increases, the viscosity..

A

Also increases (more easier to flow)

31
Q

As the molecule increases, the flammability..

A

Decreases

32
Q

State the 5 steps to the separation of crude oil in fractional distillation.

A
  1. Crude oil is heated until vaporised in a furnace around 400degrees
    2.the vapour enters the column
    3.the column is hotter at the bottom and cooler at the top
    4.hydrocarbons condense at different temperatures, depending on their boiling points,
    5.large hydrocarbons have higher boiling points as they have move intermolecular forces within their atoms, meaning the bonds are harder to break which requires more energy.
33
Q

State uses of petroleum

A

Stored in canisters that can be used to heat food in barbecues / caravans. It’s cheap but also expensive.

34
Q

State uses of petrol.

A

This fuels cars, it is less expensive than diesel and petrol cars cannot run on diesel. (Smaller vehicles)

35
Q

State uses of kerosene

A

Fuels jet engines for planes and is very expensive

36
Q

State uses of diesel

A

This is more expensive than petrol and it fuels cars. Diesel cars cannot run on petrol.

37
Q

State uses of residue. (Lubricating oil, paraffin wax and bitumen)

A

Leftovers, quite cheap used for tea on roads and seals roofs.

38
Q

State differences between the two combustions (incomplete / complete)

A

Complete
- unlimited supply of oxygen
- ‘clean’ combustion
-hydrocarbon burnt out completely leaving products water and carbon dioxide.
-burning candle wax
Incomplete
-lack of oxygen
-‘dirty’ combustion
-hydrocarbon is not burnt out fully, forming carbon, carbon monoxide and water,

39
Q

State examples of incomplete combustion

A

Burning wood
Burning fossil fuels.

40
Q
A