Day 1 (additional) Flashcards

1
Q

Which of the following is unsaturated fatty acid?

Lauric Acid
Myristic Acid
Oleic Acid
Palmitic Acid

A

Oleic Acid

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2
Q

Ozonolysis of cyclohexene produces

A

Adipic acid

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3
Q

Recording Soectrophotometers sometimes operate with feedback loops that vary the power of the reference beam until it matches the power of the beam through the sample. This mode of operation

a. Eliminates the need for a continuous source
b. Require two monochromators
c. eliminates the need for non-absorbing solvents
d. makes the detector to a null device, with the result that nonlinear response to a radiant power would not be deleterious

A

d. makes the detector to a null device, with the result that nonlinear response to a radiant power would not be deleterious

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4
Q

The amount of chlorine available in water after disinfection is called

A

Residual Chlorine

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5
Q

Which of the following is a covalent oxide
-BeO
-MgO
-K2O
-Rb2O

A

BeO

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6
Q

Conductance measurements at infinite dilution will be valid for the determination of the solubility of difficulty soluble salts and saturation point because

a. They have very low concentrationd at their saturation point
b. They conduct minimal current
c. at infinite dilution the concentration cannot be achieved
d. they are strong electrolytes

A

a. They have very low concentrations at their saturation point

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7
Q

Refers to the uptake and translocation of metal contaminants in the soil by plant roots into the above ground portion of the plants

A

phytoextraction

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8
Q

Which of the following is not a hexose?

a. Ribose
b. Fructose
c. Altrose
d. Mannosr

A

a. Ribose

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9
Q

Vinylbenzene is also known as

A

Styrene

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10
Q

Microorganisms that use carbon dioxide as their carbon source

A

photo-autotrophs

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11
Q

What sequence of processes must be done to obtain m-nitrotoluene?

A

Nitration then Alkylation

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12
Q

One of these statements is not correct for ideal gases

a. The volume occupied by the gas is negligible compared to the volume of the containing vessel
b. the product of PV is a constant
c. the ratio of density/pressure is a constant at a given temperature
d. PV/T is a constant for a known quantity of a gas

A

b. the product of PV is a constant

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13
Q

Which of the following might be used as an electrode?

a. a stick
b. a nail
c. a glass rod
d. a soda straw

A

b. a nail

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14
Q

Addition of Grignard Reagent to ketones results in the formation of ________ alcohol.

A

Dihydric

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15
Q

The reaction of alkylhalide and an alkoxide to produce ether is called

A

Williamson synthesis

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16
Q

The process in petroleum refining that increases the yield of the most useful fractions is

A

Cracking

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17
Q

Which of the following organisms are considered coencytic?

a. protozoa
b. algae
c. molds
d. fungi

A

c. molds

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18
Q

All of the following processes will produce a ketone EXCEPT

a. Hydration of alkynes
b. Ozonolysis of alkenes
c. Friedel-Crafts alkylation
d. Reduction of alcohols with NaBH4

A

c. Friedel-Crafts Alkylation

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19
Q

Which of the following is a protein?

a. collagen
b. enzymes
c. hemoglobin
d. all of these

A

d. all of these

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20
Q

Basic Amino Acid

a. lysine
b. Arginine
c. Histidine
d. all of these

A

d. All of these

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21
Q

Part of the nutrient cycles in which chemical nutrients reside in the soil, watet, or air

A

environmental phase

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22
Q

A visible concentrated growth of algae or other algae or other aquatic life/plants is called

A

bloom

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23
Q

The ________ is a global undertaking on global warming and greenhouse gases

A

Kyoto Protocol

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24
Q

Chemicals which are trested by the manufacturer showing the actual percentages of impurities and labeled on the containers are called

a. reagent grade chemicals
b. analytical reagent
c. certified reagent
d. all of these

A

d. all of these

25
The Compound CFCl3 is used as a/an
Refrigerant
26
The oxidatuoh state of oxygen is usually -2, except in peroxides, it is -1. Which of the following compounds is peroxide? a. KO2 b. Na2O2 c. H2O d. BaO
b. Na2O2
27
The current DENR secretary
Maria Antonia Luzo-Lozayga
28
An increase in the temperature of the reactants causes an increase in the rate of reaction. The best explanation is: As the temperature increases, a. the concentration of reactants increases b. the activation energy decreases c. the collision frequency increases d. the fraction of collisions with total kinetic energy > Ea increases
d. the fraction of collisions with total kinetic energy > Ea increases
29
Basic Properties are characteristic if all alkaline earth metal oxides except one. Its formula is BeO MgO SO2 B2O3
BeO
30
Two liquids form a solution and release a certain amount of heat. How does the pressure above the solution compare to that predicted by Raoult's Law? a. It will be the same b. It will be greater c. It will be smaller d. It will show positive deviation
c. It will be smaller
31
The method of standard addition compensates for matrix effects provided a. the addition does not dilute the sample appreciably and does not itself introduce quantities of interfering substances b. the addition dilutes the sample enough that the concentrations of interfering substances are lowered to neglible values c. the addition contains none of the substance being determined d. the addition contains a large enough quantity of some substance to a swamp out sample variations
a. the addition does not dilute the sample appreciably and does not itself introduce quantities of interfering substances
32
The temperature at which a real gas obeys the ideal gas law over an appreciable pressure range
Boyle Temperature
33
Chopping the source beam in conjuction with the use of a tuned AC amplifier in an atomic absorption spectrophotometer accomplishes the following a. a recording potentiometer can be used instead of a voltmeter for the readout b. a less sensitive detector can be ysed instead of the usual photomultiplier tube c. a cooler can be used without decreasing the population of ground-state atons d. radiation emitted by excited atoms in the flame will bit interfere with the absorbance measurement
d. radiation emitted by excited atoms in the flame will bit interfere with the absorbance measurement
34
Which if the following is not a correct element-precipitating agent pair? Cl-AgNO3 Mg-(NH4)2HPO4 Al-HCl Zn-H2S
Al-HCl
35
For a faced-centered cubic unit cell, each corner contributes _____ lattice points to the unit cell
1/8
36
The reagent that will yield diol from a given alkene: a. Hot, acidic, KMnO4 b. O3, Zn, and H2O c. OsO4 in NaHSO4 d. H+ / H2O
c. OsO4 in NaHSO4
37
A genie is willing to grant you any wish if you can pick which of his carbon functional group would boil second to the last. Choices: Alcohol, ether, ester, and carboxylic acid. What would you choose to get a wish come true?
Alcohol
38
Butanol is _____ volatile than diethyl ether since it could gorm stronger IMFA through _______
Less, H-bonding
39
Which functional grouo/s do not react through electrophilic addition? a. Alkanes b. Alkenes c. Alkynes d. None of these
a. Alkanes
40
Reaction of acetone with methyl magnesium bromide, followed by protonation produces a:
Tertiary Alcohol
41
Which among the following statements about covalent bonds is/are correct? a. Sigma bonds possess lower energy than pi bonds, due to its hybridization b. sp3-hybridized MO's typically tetrahedral electronic geometry c. Tertiary carbocations are relatively stable, and more easily formed than secondary carbocations d. All of the above
D. All of the above
42
Which among the following aromatic compounds is more reactive than benzene towards Aromatic substitution reactions? a. Chlorobenzene b. Nitrogenzene c. Phenyl ethanoate d. Ethyl benzene
c. Phenyl Ethanoate
43
Which among the following materials is most reactive towards SN2 reactions? a, 2-chloro-2-methyl propane b. 2-chloro propane c. 1-chloro propane d. All of the choices above
c. 1-chloro propane
44
administrative order issued by DENR includes "navigable waters" as one of its classification
DAO 2016-08
45
Which persistant organic pollutant included in the initial list of the 12 POPs under stockholm convention is not considered as a pesticide? a. Chlordane b. Dieldrin c. Heptachlo d. Hexachlorobenzene
d. Hexachlorobenzene
46
Esterification can be achieved by reactant the following pairs of reagent: a. Alocohol and carboxylic acid b. Alcohol and acid anhydride c. Alcohol and Acyl Halide d. All of these
d. All of these
47
Trace Metal which causes disintegration of the bones or more commonly called itai-itai disease
Cd
48
composition of acid rain
nitric acid and sulfuric acid
49
In titration of weak acid with a strong base, which of the following is the best indicator to be used? a. Bromcresol green b. Methyl orange c. Methyl red d. Phenolphthalein
d. Phenolphthalein
50
Biochemical compounds are either hydrophobic, hydrophilic or ampiphatic. Classify the following compounds: glucose, stearic acid, soaps, fatty acids
hydrophilic, ampiphatic, ampiphatic, hydrophobic
51
Taurine, a beta amino acid belongs to the acidic group of:
-SO2OH
52
trans-2-pentene and Cyclopentane are ________ isomers
constitutional
53
The millenium prize problems consists of seven problems in mathematics that wete stated by the clay mathematics institute. You want to become the seconr person to solve one of these problems. What is the first millenium prize problem solved?
Poincaré Conjecture
54
Which of the following has the highest MCL: Xylene, Benzene, Lindane, Heptachlor
Xylene
55
Arrange the following in terms of increasing toxicity: 1: heptachlor 2: Dieldrin 3: DDT 4: As 5: Chromium
3, 1, 4, 2, 5
56
most abundant by MASS on earth
Iron
57
Thunderbolts and lightning, very, very, frightening me. When lightning strikes sand, it fuses grains to create a small glass-like tube. what is the name of this compund?
Fulgurite
58
He established law of constant proportions, concept of allotropy, discovered cerium and selenium, and the vital force theory
Jöns Jacob Berzelius
59
The lack of this enzyme is responsible for Asian flush when drinking alcohol
Aldehyde dehydrogenase 2