Definitions Flashcards
What is the Principle of the Mass Spectrometer
To separate and deflect
Positively charged Ions
According to their atomic masses
When moving in a magnetic field
Energy Level
Orbital which electrons of equal energy can occupy
Visible Lines in Hydrogen Emission Spectrum
Balmer Series
Atomic Radius
Half the distance between the two nuclei of atoms of the same element in a single covalent bond
First Ionisation Energy
The minimum energy required
To completely remove
The most loosely bound electron
Of a neutral gaseous atom
In it’s ground state
Electronegativity
The relative force of attraction an atom has for the shared pair of electrons in a covalent bond
Isotopes Definition
Atoms of the same element which differ by atomic mass (number of neutrons in nucleus)
Radio Isotope Definition
Isotope atom with an unstable nucleus
Half-Life
Time taken for half of the sample to decay
What happens to an atom after alpha decay
Looses a ‘He’ atom
Radioactivity
Spontaneous decay of a nucleus, releasing radiation
Mole / Avogadro’s Constant
A mole of a substance is the amount of a substance that contains 6x10^23 particles of that substance
Chemical Equilibrium
A state of chemical balance where the rate of the forward reaction equals the rate of the reverse reaction
Dynamic Reaction
A reaction where the forward and backwards reactions are both occurring continuously
Le Chatelier’s Principle
If a reaction at equilibrium is put under stress, the equilibrium will shift to relieve the stress
Avogadro’s Law
Equal volumes of gases at the same temperature and pressure have equal number of moles
Charles’s Law
For a gas of a definite mass, at a constant pressure, the volume of the gas is directly proportional to the Kelvin temperature
Boyle’s Law
For a gas of a definite mass at a constant temperature, the volume of a given mass of any gas is inversely proportional to its pressure
Gay-Lussac’s Law of Combining Values
In a reaction between gases the volumes of the reacting gases and the volumes of any gaseous products are in the ratio of small whole numbers provided the volumes are measured at the same temperature and pressure
Kinetic Theory of (Ideal) Gases
- Volume is negligible compared to space it occupies
- No attractive or repulsive forces between particles
- Particles are in constant random motion and are constantly hitting walls of container and themselves
- Average kinetic energy of the particles is or optional to Kelvin temperature
- All collisions are perfectly elastic
Real Gas vs Ideal Gas
Molecules have volume, when gas it at high pressure / low volume it is not ok to say volume is negligible
Intermolecular forces are present
Collisions are not perfectly elastic
Ideal Gas
An ideal gas is one which obeys all the gas laws under all conditions of temperature and pressure
When do real gases behave most like ideal gases?
High Temperatures
Low Pressures / High Volumes
Arrhenius Acids / Bases
Dissociates in water to form H+ / OH-