Definitions Flashcards

1
Q

Relative Atomic Mass (Ar)

A

The weighted average of the masses of the isotopes relative to 1/12 of a carbon-12 atom

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2
Q

Relative Molecular Mass (Mr)

A

The mass of one molecule of a substance relative to 1/12 of the mass of carbon-12 atom

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3
Q

Mass Number

A

The sum of the protons and neutrons in the nucleus of an atom

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4
Q

Atomic Number

A

The number of protons in the nucleus of an atom

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5
Q

Isotope

A

Atoms of the same element with different numbers of neutrons

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6
Q

First Ionisation Energy

A

The minimum energy required to remove one mole of electrons from an atom in its gaseous state

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7
Q

Electronegativity

A

A measure of the tendency of an atom in a molecule to attract a binding pair of electrons towards itself

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8
Q

Ligand

A

An atom, ion or molecule that can donate a pair of electrons to a central metal ion to form a dative covalent (coordinate) bond
[LEWIS BASES]

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9
Q

Exothermic Reaction

A

A reaction that releases heat to the surroundings
(As a result of forming products with stronger bonds than the reactants. Exothermic reactions have negative ∆H values)

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10
Q

Endothermic Reaction

A

A reaction that absorbs heat from its surroundings
(As a result of forming products with weaker bonds than the reactants. Endothermic reactions have positive ∆H values)

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11
Q

Standard State

A

The most stable state of an element or compound under the specified conditions

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12
Q

Standard Conditions

A

Temperature: 298K
Pressure: 100 kPa (1 atm)

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13
Q

Standard Enthalpy Change of a reaction (ΔH θ)

A

The heat energy transferred under standard conditions for a reaction

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14
Q

Average Bond Enthalpy

A

The energy required to break one mole of the same type of bond in the gaseous state averaged over a variety of similar compounds

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15
Q

Standard Enthalpy change of Formation

A

The enthalpy change when 1 (one) mole of a substance is formed from its elements in their standard states, under standard condtitions

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16
Q

Standard Enthalpy of Combustion

A

The enthalpy change when 1 (one) mole of a substance in its standard states burns completely in excess oxygen under standard conditions

17
Q

Lattice Enthalpy

A

The amount of energy required to separate one mole of ionic compound into isolated gaseous ions under standard conditions

18
Q

Electron Affinity

A

The energy change when 1 (one) mole of gaseous atom gains 1 (one) mole of electrons to form a gaseous ion, under standard conditions

19
Q

Rate of Reaction

A

The increase in concentration of products or the decrease in concentration of reactants per unit time

20
Q

Activation Energy

A

The minimum energy needed (by reactants) to start/initiate a reaction

21
Q

Arrhenius Acid/Base

A

Acid is an H+ donor; Base is an OH- donor

22
Q

Brønsted Lowry Acid

A

An acid is a proton (hydrogen ion) donor

23
Q

Brønsted Lowry Base

A

A base is a proton (hydrogen ion) acceptor

24
Q

Lewis Acid

A

An acid is an electron pair acceptor

25
Lewis Base
A base is an electron pair donor
26
Oxidation
The loss of electrons from a species during a chemical reaction
27
Reduction
The gain of electrons by a species during a chemical reaction
28
Oxidizing Agent
A species that brings about oxidation by removing electrons from another reactant. During the reaction the oxidizing agent gains electrons and so is reduced
29
Reducing Agent
A species that brings about reduction by giving electrons to another reactant. During the reaction the reducing agent loses electrons and so is oxidized
30
Standard Electrode Potential
The is the electrode potential of a half-cell relative to the hydrogen half-cell, which is assigned a value of zero. (Also known as standard reduction potential) It is measured at standard conditions Standard conditions for SHE - H2(g) at 100 kPa and 298K - acidic solution, [H+] 1.0 mol dm^-3 - inert platinum electrode