definitions Flashcards

1
Q

base peak

A

Peak of greatest abundance in a mass spectrum.

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2
Q

molecular ion peak

A

A peak produced by an ion formed by the removal of one
electron from a molecule.

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3
Q

m+1 peak

A

A peak produced by a molecular ion with an increased mass
due to the presence of one carbon-13 atom.

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4
Q

fragmentation ion

A

A positively charged ion produced when the molecular ion
breaks apart.

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5
Q

L RES MR

A

A spectrum which does not show the spin-spin splitting
pattern.

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6
Q

high res mr

A

A spectrum which does show the spin-spin splitting pattern.

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7
Q

doublet

A

A signal which appears as a pair of lines of equal intensity

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8
Q

triplet

A

A signal which appears as three lines in the approximate
intensity ratio (1:2:1)

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9
Q

quartet

A

A signal which appears as four lines in the approximate
intensity ratio (1:3:3:1)

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10
Q

transition metal

A

An element which forms at least one stable ion with a
partially filled d-subshell.

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11
Q

complex

A

A central metal atom or ion with ligands bonded by
co-ordinate bonds.

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12
Q

ligand

A

An ion or molecule with a lone pair of electrons which forms a
co-ordinate bond with a central metal atom or ion in a
complex.

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13
Q

co ord number

A

The number of co-ordinate bonds to a central metal atom or
ion in a complex.

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14
Q

monodentate

A

A ligand which uses only one lone pair of electrons to form a
co-ordinate bond with a central metal atom or ion in a
complex.

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15
Q

standard electrode potential

A

The potential difference measured when a half-cell is connected
to the standard hydrogen electrode under standard conditions.

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16
Q

emf

A

The potential difference measured when two half-cells are
connected.

17
Q

primary amine

A

Only one carbon atom directly bonded to the nitrogen atom
and therefore has the (-NH2) group.

18
Q

coupling

A

A reaction in which two benzene rings are linked together
through an azo (-N=N-) group.

19
Q

condensation polymers

A

Polymers formed by the elimination of small molecules such as
water or hydrogen chloride when monomers bond together.

20
Q

Biodegradable polymers

A

A polymer which can be broken down by action of micro organisms

21
Q

Monomers

A

Small molecules which join together to form a polymer