Definitons Flashcards

(56 cards)

1
Q

Empirical formula

A

A formula which shows the simplest whole number ratio of atoms of each element in a compound

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2
Q

Molecular formula

A

A formula which shows the actual number of atoms of each element in a molecule

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3
Q

Molar gas volume

A

The volume of one mole of gas under specified conditions of temperature and pressure e.g. 24dm^3 at 20°C and one atmosphere pressure

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4
Q

Percentage yield

A

Actual yield
———————— x100
Theoretical yield

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5
Q

Atom economy

A

Mass of desires product (RFM)
———————————————
Total mass of products (RFM)

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6
Q

Homologous series

A

Compounds which have the same general formula, similar chemical properties, show a gradation in physical properties and successive members differ by a CH2 unit

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7
Q

Functional group

A

Reactive group within a compound

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8
Q

Structural isomers

A

Molecules that have the same molecular formula but a different structural formula

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9
Q

Geometric isomers

A

Molecules with the same structural formula, but different arrangement of atoms due to the presence of one or more C=C bonds

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10
Q

Saturated hydrocarbon

A

Contains no C=C or C=C bonds

-

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11
Q

Hydrocarbon

A

Contains carbon and hydrogen only

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12
Q

Substitution

A

Replacing one atom or group with a different atom or group

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13
Q

Homolytic fission

A

Bond breaking in which one of the shared electrons goes to each atom

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14
Q

Heterolytic fission

A

Bond breaking in which both electrons in the shared pair go to a single atom

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15
Q

Radical

A

A particular with an unpaired electron

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16
Q

Unsaturated hydrocarbon

A

Contains at least one C=C or C(triple bond)C

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17
Q

Sigma bond

A

A covalent bond formed by the linear overlap of atomic orbitals

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18
Q

Pi bond

A

A covalent bond formed with the sideways overlap of p orbitals

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19
Q

Bond length

A

The distance between the nuclei of two covalently bonded atoms

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20
Q

Hydrogenation

A

Addition of a hydrogen molecule across a C=C

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21
Q

Electrophile

A

An ion of molecule that attacks regions of high electron density

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22
Q

Primary carbocation

Secondary carbocation

Tertiary carbocation

A

A carbocation which has one carbon atom directly bonded to the positively charged carbon

A carbocation that has 2 carbons directly bonded to the positively charged carbon

A carbocation that has 3 carbons directly bonded to the positively charged carbon

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23
Q

Polymerisation

A

Joining together of many small molecules (monomers) to form a large molecule

24
Q

Monomers

A

Many small molecules which join together to form a polymer

25
Polymer
A large molecule formed when monomers join together
26
Primary halogenoalkane Secondary halogenoalkane Tertiary halogenoalkane
A halogenoalkane which has one/two/three carbons directly bonded to the carbon atom that is bonded to the halogen
27
Reflux
Repeated boiling and condensing of a reaction mixture
28
Hydrolysis
Breaking up molecules by reaction with water
29
Nucleophile
An ion or molecule, with a lone pair of electrons, that attacks regions of low electron density
30
Elimination
A reaction in which a small molecule is removed from a larger molecule
31
Miscibility
Liquids which mix in all proportions i.e form a single layer
32
Primary alcohol Secondary alcohol Tertiary alcohol
An alcohol which has one / two / three carbons directly bonded to the carbon atom that is bonded to the OH group
33
Ground state
A molecular vibration which is in the lowest possible energy state
34
Wave number
The reciprocal of the wavelength and it is measured in cm^-1 Wave number = 1 ————————— Wavelength(cm^3)
35
Endothermic
A reaction in which the enthalpy of the products is greater than the enthalpy of the reactants
36
Exothermic
A reaction in which the enthalpy of the products is less than the enthalpy of the reactants
37
Standard conditions
298K and 100kPa
38
Standard enthalpy change
Change in heat energy at constant pressure, measured at standard conditions
39
Standard enthalpy of combustion
The enthalpy change when one mole of a substance is completely burnt in oxygen under standard conditions
40
Standard enthalpy of formation
The enthalpy change when one mole of a compound is formed from its elements under standard conditions
41
Standard enthalpy of neutralisation
The enthalpy change when one mole of water is produced in a neutralisation reaction under standard conditions
42
Conservation of energy
Energy cannot be created or destroyed but it can change from one form to another
43
Hess’s Law
The enthalpy change for a reactions is independent of the route taken, provided the initial and final conditions are the same
44
Average bond enthalpy
The energy required to break one mole of a given bond averaged over many compounds
45
Reaction rate
The change of the concentration of a reactant or product with respect to time
46
Catalyst
A substance which increases the rate of a chemical reaction but does not get used up
47
Activation energy
The minimum amount of energy required for a reaction to occur
48
Reversible
A reaction which goes in both the forward and backwards direction
49
Dynamic equilibrium
Rate of forward reaction is equal to the rate of the backwards reaction
50
Equilibrium
A reversible reaction in which the amount of each reactant / product remains constant
51
Homogenous
A reaction in which all the reactants and products are in the same physical state
52
Heterogenous equalibria
A reaction in which all the reactants and products are not in the same physical state
53
Kc
Look in definitions book
54
Heterogenous catalyst
The catalyst is in a different phase from the reactants
55
S-block elements
An element which has an atoms outer electron in an s - subshell
56
Solubility
The maximum mass of solute that will dissolve 100g of solvent at a stated temperature