Electro Spectro Flashcards
(24 cards)
what is electromagnetic radiation?
waves that have both wavelength and frequency
what is the symbol and unit of wavelength?
lambda, metres
usually given in nm for visible light
what is wavelength?
the distance between adjacent wave crests
what is the symbol and unit of velocity in waves?
C and m s-1
what is velocity?
the rate of advance of any one wave crest
what is the symbol and unit of wavenumber?
V, m-1
what does wavenumber represent?
number of waves in 1 metre of radiation
what is the symbol and unit of frequency?
f, Hertz (Hz)
what is frequency?
the number of wavelengths or cycles passing a point in 1 second
what is the electromagnetic spectrum?
types of radiation arranged in order of wavelength
what is the dual nature of electromagnetic radiation?
it behaves as both a wave and as a particle (photon)
what is a photon?
a particle of electromagnetic radiation carrying quantised energy proportional to frequency
what happens when a photon is absorbed?
energy is gained as electrons are promoted to a higher energy level
what happens when a photon is emitted?
energy is lost as electrons drop to a lower energy level
that one wavenumber energy equation
E = lhcv
what is the energy unit of one mole of photons?
KJ mol-1
what is absorption spectroscopy?
radiation is absorbed by atoms as electrons are promoted to higher energy levels
what is emission spectroscopy?
radiation is emitted as excited electrons drop to lower energy levels
how are absorption spectra produced?
by measuring how the intensity of absorbed light varies with wavelength
how are emission spectra produced?
by meauring the intensity of light emitted at different wavelengths
what do emission lines in atomic spectra provide evidence for?
discrete (quantised) energy levels in atoms
what can absorption and emission spectra be used for?
to identify and quantify elements in a sample
in atomic spectroscopy, what is the concentration of an element related to?
the intensity of light emitted or absorbed
relationship between wavelength frequency and energy
as wavelength increases, frequency and energy decreases