electrochemistry 🛁 Flashcards

1
Q

which electrode is the cathode and anode?

A

positive electrode: anode
negative electrode: cathode

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2
Q

describe what happens at each anode

A

__ ions migrate towards the cathode. __ ions are discharged where they gain/lose electrons to form __

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3
Q

what ions are present in aqueous solution?

A

H+, OH-, ions from compound

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4
Q

what factors affect the ion preferentially discharged?

A

1) relative position of ions in the electrochemical series
2) concentration of electrolyte
3) nature of electrodes

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5
Q

which ions will be preferentially discharged if present in a concentrated electrolyte?

A

lead, iron, zinc, iodide, bromide, chloride

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6
Q

describe the process of preferential discharge (H+ and Na+)

A

sodium ions and hydrogen ions are attracted to the cathode. hydrogen ions are preferentially discharged because they gain electrons more easily to produce hydrogen gas

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7
Q

describe what happens when copper electrodes are used

A

__ ions are attracted to the anode. however, both ions are not discharged, instead the copper anode, being a reactive anode, itself loses electrons. coper in the anode loses electrons to produce copper (II) ions which go into the electrolyte

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8
Q

why does the copper(II) sulfate electrolyte not fade when using copper electrodes?

A

for each copper(II) ion discharged, another one is formed at the anode which goes into the solution, hence concentration of copper(II) ions stay the same

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9
Q

applications of electrolysis

A

1) purification of copper
2) electroplating

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10
Q

describe electron flow in a simple cell

A

electrons flow from the more reactive metal to the less reactive metal

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11
Q

which electrodes are positive and negative and what ions do they attract?

A

more reactive metal: negative electrode
less reactive metal: positive electrode, attracts cations

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12
Q

what reaction occurs at the zinc terminal? (zn and cu)

A

Zn -> Zn2+ + 2e-

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13
Q

what reaction occurs at the copper terminal?

A

2H+ + 2e- -> H2

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14
Q

briefly describe fuel cells

A

reactants are continuously supplied to produce electricity directly (2H2 + O2 -> H2O)

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15
Q

advantages of fuel cellss

A

water is produced as the waste product, which can be drank by astronauts in space

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