electrolysis + reactivity Flashcards

(35 cards)

1
Q

what is electrolysis

A

splitting of ionic substances using electricity

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2
Q

what are electrolytes

A

ionic compounds either in molten state or dissolved in water

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3
Q

what are electrodes made of and why

A

-usually graphite
-conductive and inert

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4
Q

positive electrode

A

anode

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5
Q

negative electrode

A

cathode

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6
Q

postive ions

A

cations

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7
Q

negative ions

A

anions

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8
Q

what happens when ions reach an electrode

A

gain or lose electrons so form atoms/molecules of an element

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9
Q

why do electrolytes have to be in molten state/dissolved

A

ions are free to move therefore can carry charge

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10
Q

why are the electrodes inert

A

so electrolyte doesn’t form a new substance by reacting with electrodes

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11
Q

reactivity series

A

potassium
sodium
calcium
magnesium
aluminium
carbon
zinc
iron
hydrogen
copper
silver
gold

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12
Q

what does electrolysing water do

A

splites water molecules into hydrogen and oxygen

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13
Q

equation for electrolysis of water

A

2H2O (l) -> 2H2 (g) + O2 (g)

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14
Q

what ions could be produced in electrolysis of water

A

OH- and H+

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15
Q

how do you know what positive ion is discharged

A

element lower in reactivity series

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16
Q

how do you know what negative ion is discharged

A

a halide ion before OH-

17
Q

halide ions

A

group 7: F-, Cl-, Br-, I-

18
Q

what does OH- produce when discharged

19
Q

what is oxidation

A

-loss of elctrons
-gain of oxygen

20
Q

what is reduction

A

-gain of electrons

21
Q

where does reduction happen

22
Q

where does oxidation happen

23
Q

reduction half equation example

A

Na+ + e- -> Na

24
Q

oxidation half equation example

A

2Cl- -> Cl2 + e-

25
what side is the electron on of a reduction half equation
left
26
what side is the electron on of a oxidation half equation
right
27
metal + water -> ?
metal hydroxide + hydrogen
28
metal + acid -> ?
salt + hydrogen
29
what determines reactivity
its ability to lose electrons
30
why does reactivity increase as you go down group 1
-number of electron shells increases -outermost electron is further from positive nucleus -weaker forces of attraction so less energy is required to overcome
31
describe a displacement reaction as redox reaction
during displacement, the more reactive metal loses electrons (is oxidised) + less reactive metal gains those electrons (is reduced).
32
how are metals less reactive than carbon extracted
reduction with carbon
33
acid + metal oxide -> ?
salt + water
34
acid + metal hydroxide -> ?
salt + water
35
acid + metal carbonate -> ?
salt + water + carbon dioxide