Electron Arrangement Flashcards

1
Q

The arrangement of electrons around the nucleus was studied by…………

A

Niels Bohr(1922)

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2
Q

What is a continuous spectrum?

A

It is when white light passes through a prism, and the white light is broken up into an array of colours

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3
Q

What is line spectrum

A

It is when light from a hydrogen discharge tube is passed through a prism, a series of narrow coloured lines are formed

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4
Q

What is a hydrogen discharge tube?

A

Glass tube filled with gas at low pressure with an electric current running through it.

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5
Q

Differentiate between a spectrometer and a spectroscope

A

A spectrometer is a device used to carry out measurements on spectra, while spectroscopes are simply used to observe spectra

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6
Q

What colours do the following salts of metals give when burned

Sodium

Potassium

Lithium

Barium

Copper

Strontium

A

Yellow

Lilac

Crimson

Green

Blue/Green

Red

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7
Q

What is an energy level?

A

It is the fixed energy value that an electron in an atom may have

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8
Q

What is the ground state?

A

It is where electrons occupy the lowest available energy levels

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9
Q

What is the excited state?

A

It is where electrons occupy higher energy levels than those in the ground state

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10
Q

Explain Bohr Theory

A
  1. An electron occupies fixed energy levels
  2. At its ground state it occupies the lowest available energy levels
  3. It can jump to a higher energy level if it receives a certain amount of energy
  4. Energy absorbed must exactly equal the energy difference between ground state and excited state according to E2-E1=hf
  5. Because the excited state is unstable the electron falls back to ground state
  6. It emits the excess energy in the form of a photon of light (hf)
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11
Q

Name the three series

A

Balmer series- in the visible spectrum so we can see li es

Paschen- in infrared region

Lyman- in the ultraviolet region

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12
Q

What are the limitations of the Bohr Theory

A
  1. It only applied to electrons in the hydrogen atom
  2. Doesn’t take wave like motion into account
  3. Doesn’t take sub levels into account
  4. Doesn’t take the Uncertainty Principle into account
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13
Q

How do lines on emission spectrum provide evidence for existence of energy levels

A
  1. Lines on emission spectrum are produced when an electron falls from the excited state to the ground state
  2. The line is the light energy produced when it calls
  3. The light energy is the difference between the energy levels so shows the existence of energy levels.
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14
Q

What is Atomic Absorption Spectrum

A

Atomic absorption measures the amount of light at a resonant wavelength, which passes through a cloud of atoms and is absorbed by them

When white light is passed trough a sample of gas and then a prism, the light that emerges will have certain wavelengths missing. This spectrum is called Atomic Absorption Spectrum

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15
Q

Name some some uses of Atomic Absorption Spectrum

A
  1. Used to identify unknown gas samples
  2. Detects concentration of an element present a light source of that element must be used
  3. The intensity of light before and after the sample is measured and this difference equals the concentration of the element present
  4. Used to measure the amount of lead in a sample of water
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16
Q

Name the different energy sub levels

A

1s, 2s, 2p, 3s, 3p, 3d, 4s, 4p, 4d, 4f, 5s, 5p, 4d, 4f, 5s, 5p, 5d, 5f, 6s, 6p, 6d, 6f, 7s, 7p, 7p, 7d, 7f

17
Q

Define an energy sub level

A

An energy sublevel is a sub division of a main energy level and consists of one or more orbitals of the same energy

18
Q

What was Louis De Broglie’s contribution

A

All moving particles have a wave associated with them, this proved that electrons do not travel in precise paths.

19
Q

What is Heisenberg’s Uncertainty Principle

A

It is impossible to measure at the same time both the velocity and position of an electron

20
Q

What is an orbital

A

An orbital is a region in space within which there is a probability of finding an electron

21
Q

What is Schrodinger’s contribution

A

Used mathematical equations to work out the probability of finding an electron in any sub level

22
Q

What shape is the S orbital

A

Spherical

23
Q

What shape is the P orbital

A

It is a dumb bell

24
Q

How many electrons are in s, p, and d energy levels respectively

A

2, 6, 10

25
Q

list all the energy levels available for the first 36 elements in the periodic table

A

1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p

26
Q

How are Balmer series lines formed

A

They are formed when one set of electron transitions from higher levels to the level where n = 2 gives rise to the lines in the visible spectrum.

27
Q

What implications did De Boglie’s theory on the wave nature of the electron have on Bohrs Theory

A

If the electron has a wave motion, then Bohr’s picture fit travelling in a precise path at a precise distance from the nucleus cannot give q full picture of the situation