electron structure and shapes of molecules Flashcards

1
Q

shells

A

split into 4 Subshells

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2
Q

s

A

1 orbital can hold 2 electrons

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3
Q

p

A

3 orbitals can gold 6 electrons

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4
Q

d

A

5 orbitals can hold 6 electrons

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5
Q

f

A

7 orbitals hold 14 electrons

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6
Q

principle quantum no 1

A

sub shells 1s
no of electrons 2

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7
Q

principle quantum no2

A

2s 2p 8 electrons

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8
Q

principle quantum no 3

A

3s 3p 3d 18 electrons

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9
Q

higher shell no

A

the further it is from the nucleus
has a higher energy

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10
Q

orbital shapes S

A

1 ORBITAL
holds 2 electrons
spherical
2 electrons can move anywhere in this sphere

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11
Q

P orbital

A

3 orbitals can hold 6 electrons
dumbbell
when 2 electrons occupy 1 orbital they spin in opposite directions

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12
Q

ionic bonding

A

ionic compounds are oppositely charged ions held together by electrostatic attractions
most ionic compounds dissolve in water
polar molecules they attract positive and negative ions and break up the structure
conduct electricity when molten or dissolved in solution as ions are free to move
hmp as strong electrostatic forces of attraction between oppositely charged ions

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13
Q

covalent bonding

A

sharing of outer electrons in order for atoms to obtain full shell
electrostatic attraction between shared electrons and positive nucleus

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14
Q

dative covalent

A

1 atom donates two electrons 2 atom or ion 2 form a bond

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15
Q

lp next to lp

A

repel more than 2bp

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16
Q

bp

A

repel eachother equally

17
Q

linear

A

2bp 180

18
Q

trignol planar

A

3bp and can also have 2lp
120

19
Q

tetrahedral

A

4bp
109.5

20
Q

octahedral

A

6bp
90

21
Q

pyramidal

A

3bp 1lp
107

22
Q

bent

A

2bp 2lp
104.5

23
Q

square planar

A

4bp 2lp
90

24
Q

electronegativity

A

ability of an atom to attract electrons towards itself in a covalent bond
the bigger the difference in electronegativity the more ionic it is

25
Q

polar bonds

A

covalent bonds can become polar if the atoms attached to it have a difference in electronegativity
bigger difference in electronegativity the more polar the bond will be

26
Q

induced dipole dipole

A

any atom or molecule with electrons can form a dipole when they move near another atom
electrons move from one end to another = temp dipole
atoms move away dipole interactions destroyed
delta + attracted to delta - on other atom (force of attraction)

27
Q

induced dipole dipole forces

A

hold some molecules in crystal structure
weak induced dipole dipole hold i2 molecules together
strong covalent bonds hold the 2 iodine molecules together

28
Q

bigger molecule

A

more IDD forces as larger electron cloud
when we boil a liquid we break IDD not covalent bonds

29
Q

permanent dipole dipole

A

weak electrostatic forces exist between molecules with polarity
permanent dipole dipole is stronger

30
Q

polar molecule test

A

charged rod near steady stream of polar liquid
liquid bends towards rod as molecules align to face oppositely charged rod

31
Q

hydrogen bonding

A

occurs in very electronegative elements
h bond occurs when h molecule forms bond with lone pair on N/O/F

32
Q

ice

A

regular structure held by hydrogen bonds
molecules further apart making ice less dense than water
hf has a hip than hcl as it has hydrogen bonding