Electronic Structure of the Atom Flashcards

(38 cards)

1
Q

nodes

A

empty spaces between subshells

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2
Q

S subshell

A

in all 7 pel, 1 orbital, max 2 electrons

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3
Q

P subshell

A

2-7 pel, 3 orbitals, max 6 electrons

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4
Q

d subshell

A

3-7 pel, 5 orbitals, max 10 electrons

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5
Q

f subshell

A

3-5 pel, 7 orbitals, max 14 electrons

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6
Q

S subshell shape

A

shperical

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7
Q

p subshell shape

A

dumbbell

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8
Q

d subshell shape

A

dumbbell and spherical

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9
Q

f subshell

A

dumbbell and spherical

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10
Q

electron configurations

A

short hand configurations used to indicate the location of electrons in an atom

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11
Q

valence electrons

A

electrons found in the outer most principle energy level

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12
Q

orbital energy diagrams

A

indicate the location of electrons as well as the energy of the electron

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13
Q

hybridization

A

occurs when electrons shift to higher or lower orbitals

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14
Q

elements that hybridize naturally

A

carbon, silicon, chromium, molybdenum, tungsten?

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15
Q

Aufbau principle

A

electrons enter orbitals with the lowest energy first

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16
Q

Pauli Exclusion Principle

A

no two electrons in any atom may have the same set of quantum numbers; therefore electrons within the same orbitals must have opposite spins

17
Q

Hund’s Rule

A

within a subshell; one electron will enter each orbital with parallel spins before pairing will begin

18
Q

electronegativity

A

the ability of an atom in a chemical compound to attract electrons

19
Q

Why does the electronegativity of an atom increase as you go up and across on the periodic table?

A

because as the number of protons increase down the group, the attractions decreases with distance

20
Q

electron shielding

A

when the valence electrons never feel the full force of the protons (attractive forces)

21
Q

ionization energy

A

the energy required to remove a valence electron

22
Q

What is the relationship between the atomic radius and the periodic table?

A

It increases as you go down and across from right to left.

23
Q

light

A

electromagnetic waves, which travel through a vacuum at a rate of 3.0x10^10 cm/sec

24
Q

How do you calculate frequency?

A

Frequency = # of waves (cycles) / second

25
speed of light (C)
3.0 x 10^10 cm / sec
26
blue shift
towards
27
red shift
away
28
line (discontinuous) spectra
when an element in its gas state exposed to an electric charge and the light emitted is passed through a prism
29
quantum numbers
used to indicate the location of electrons in an atom
30
ground state
when electrons are in the lowest possible energy levels
31
n
pel
32
l
subshell
33
m1
orbital
34
ms
e spin
35
John Dalton
defined the atom as an indestructible mass
36
Joseph Thomson
discovered the negatively charged electron, developed "Plum Pudding" model
37
Ernest Rutherford
discovered nucleus with protons and neutrons, couldn't explain why electrons didn't collapse (they were quantized)
38
Schrodiner
Schrodinger equation: describes mathematically the location and energy of electrons in the hydrogen atom