Energetics Ai Flashcards

1
Q

What is the definition of enthalpy?

A

Enthalpy is the total heat content of a system, represented by the symbol H.

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2
Q

True or False: Enthalpy change is the heat content change at constant pressure.

A

True

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3
Q

What is the formula for calculating enthalpy change (ΔH)?

A

ΔH = H(products) - H(reactants)

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4
Q

Fill in the blank: The standard enthalpy change of formation is the enthalpy change when one mole of a compound is formed from its elements in their _____ states.

A

standard

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5
Q

What is the unit of enthalpy change?

A

Kilojoules per mole (kJ/mol)

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6
Q

What does a negative ΔH value indicate?

A

It indicates that the reaction is exothermic.

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7
Q

What does a positive ΔH value indicate?

A

It indicates that the reaction is endothermic.

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8
Q

What is the standard enthalpy change of combustion?

A

The enthalpy change when one mole of a substance is completely burned in oxygen under standard conditions.

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9
Q

Calculate the enthalpy change if 100 kJ of heat is absorbed.

A

ΔH = +100 kJ

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10
Q

What is Hess’s Law?

A

Hess’s Law states that the total enthalpy change for a reaction is the same, regardless of the number of steps taken.

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11
Q

True or False: The enthalpy change of a reaction can be determined by the sum of the enthalpy changes for individual steps.

A

True

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12
Q

What is the formula for calculating the enthalpy change using bond enthalpies?

A

ΔH = Σ(bond enthalpies of bonds broken) - Σ(bond enthalpies of bonds formed)

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13
Q

Fill in the blank: The enthalpy of reaction can also be expressed as the heat absorbed or released at constant _____ and volume.

A

pressure

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14
Q

What is the significance of the standard state?

A

The standard state is the most stable form of a substance at 1 atm pressure and a specified temperature, usually 298 K.

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15
Q

What is the standard enthalpy change of neutralization?

A

The enthalpy change when one mole of water is formed from the reaction of an acid and a base.

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16
Q

Calculate the enthalpy change for a reaction if the energy required to break bonds is 500 kJ and the energy released from forming bonds is 300 kJ.

A

ΔH = 500 kJ - 300 kJ = +200 kJ

17
Q

What is meant by ‘specific heat capacity’?

A

Specific heat capacity is the amount of heat required to raise the temperature of 1 gram of a substance by 1 degree Celsius.

18
Q

What is the formula for calculating heat energy (q)?

19
Q

True or False: The heat energy absorbed by a substance can be calculated using its mass, specific heat capacity, and temperature change.

20
Q

What does ‘ΔT’ represent in the heat energy equation?

A

ΔT represents the change in temperature.

21
Q

What is the standard enthalpy of formation for elements in their standard state?

A

Zero (0 kJ/mol)

22
Q

Fill in the blank: The enthalpy of vaporization is the heat required to convert a unit mass of a substance from _____ to vapor.

23
Q

What is the enthalpy change for a reaction if the total energy of products is 1200 kJ and the total energy of reactants is 1000 kJ?

A

ΔH = 1200 kJ - 1000 kJ = +200 kJ

24
Q

What type of reaction is characterized by the absorption of heat?

A

Endothermic reaction

25
What type of reaction is characterized by the release of heat?
Exothermic reaction
26
What is the standard enthalpy change of reaction for the decomposition of water?
The standard enthalpy change of reaction for the decomposition of water is positive.
27
Calculate the heat change when 50 g of water is heated from 20°C to 100°C, given specific heat capacity of water is 4.18 J/g°C.
q = 50 g * 4.18 J/g°C * (100°C - 20°C) = 16720 J
28
What is the enthalpy change when 1 mole of methane is burned?
It is the standard enthalpy of combustion of methane.
29
Fill in the blank: The heat of fusion is the heat required to convert a unit mass of a substance from _____ to solid.
liquid
30
What is the relationship between bond strength and enthalpy change in a reaction?
Stronger bonds require more energy to break, resulting in larger enthalpy changes.
31
What is the term for the heat absorbed or released during a chemical reaction?
Thermochemical change
32
True or False: The calorimeter is an instrument used to measure the heat of reactions.
True
33
What is the principle behind a bomb calorimeter?
It measures the heat of combustion of a sample under constant volume.
34
What does the term 'latent heat' refer to?
Latent heat refers to the heat required for a substance to change its state without changing its temperature.
35
Fill in the blank: The enthalpy change of a reaction can be influenced by _____ and concentration.
temperature
36
What is the effect of increasing temperature on the enthalpy change of an endothermic reaction?
It increases the enthalpy change.
37
Calculate the enthalpy change for a reaction with a ΔH of -150 kJ.
The reaction is exothermic with an enthalpy change of -150 kJ.