Energy I Flashcards

1
Q

Activation energy

A

minimum energy required for a reaction to occur

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2
Q

exothermic

A

more energy released in the formation of bonds than is absorbed in bond breaking

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3
Q

enthalpy (H)

A

the heat content of reactions

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4
Q

enthalpy change of combustion

A

the enthalpy change that occurs when one mole of a substance reacts completely with oxygen under standard conditions with all reactants and products in their standard states

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5
Q

standard conditions

A

298K, 100kPa, 1moldm-3

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6
Q

enthalpy change of reaction

A

enthalpy change that accompanies a reaction in the molar quantities shown in a chemical equation

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7
Q

enthalpy change of formation

A

enthalpy change that occurs when one mole of a compound is formed from its elements under standard conditions

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8
Q

average bond enthalpy

A

the average energy needed for 1 mole of a given type of gaseous bond to undergo homolytic fission in a gaseous molecule

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9
Q

q=mcΔT

A

heat released into and absorbed from surroundings = mass of water * specific heat capacity of water * change in temperature

q is measured in J

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10
Q

ΔH =

A

q / mol

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11
Q

Hess’ law for ΔcH

A

reactants- products

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12
Q

Hess’ law for ΔfH

A

products- reactants

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13
Q

homogenous equilibrium

A

all reactants and products in the same states

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14
Q

heterogenous equilibrium

A
  • reactants and products in different states
  • only include gaseous + aqueous in the equation
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15
Q

calculating equilibrium concentration

A

I nitial moles
C hange
E quilibrium
[ ] concentration

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16
Q

calculating equilibrium concentration example

A

0.60 mol of H2(g) was mixed with 0.40 mol of I2(g) in a sealed container with a volume 1.0 dm3.
The mixture was allowed to reach equilibrium and it was found that 0.28 mol of H2(g) remained.

H2 + I2 <——> HI
I 0.60 0.40 0
C -0.32 -0.32 +0.64
E 0.28 0.08 0.64
[] 0.28 0.08 0.64

17
Q

Kc (equilibrium constant) =

A

[ products ] / [reactants]
If:
4A + 5B <—–> 4C + 5D
then Kc =
([C]⁴ * [D]⁵) / ([A]⁴ * [D]⁵)

18
Q

position of equilibrium

A

the extent of the forwards and backwards reaction

19
Q

the value of Kc indicates….

A

the position of equilibrium,
if Kc> 1 then equilibrium lies to the right as products>reactants