enthalpy change definitions Flashcards
(12 cards)
standard lattice enthalpy
the enthalpy change when 1 mole of an ionic lattice is formed from its gaseous ions under standard conditions. this value is always exothermic
standard enthalpy change of formation
the enthalpy change that takes place when 1 mole of a compound is formed from its elements under standard conditions, with all reactants and products in their standard states as well. it can have either an exothermic or endothermic value
standard enthalpy change of atomisation
the enthalpy change that takes place for the formation of 1 mole of gaseous atoms from the element in its standard state under standard conditions. this value is always endothermic
first ionisation energy
the enthalpy change required to remove one electron from each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions . this value is always endothermic
first electron affinity
the enthalpy change that takes place when 1 electron is added to each atom in 1 mole of gaseous atoms to form 1 mole of gaseous 1- ions this value is usually exothermic. second electron affinities always have an endothermic value
standard enthalpy change of solution
the enthalpy change that takes place when 1 mole of a solute dissolves in a solvent
enthalpy change of hydration
the enthalpy change that accompanies the dissolving of gaseous ions in water to produce 1 mole of aqueous ions
what happens when an ionic lattice dissolves in water
bonds between the ionic lattice break to form a gas. bonds between the gaseous ions and the water are made
standard enthalpy change of reaction
the enthalpy change when the reaction occurs in the molar quantities shown in the chemical equation under standard conditions
standard enthalpy change of formation
the enthalpy change when 1 mole of a compound is formed from its elements in their standard states under standard conditions
standard enthalpy change of combustion
the enthalpy change when 1 mole of a substance is completely burned in oxygen under standard conditions
enthalpy change of neutralisation
the enthalpy change when an acid and alkali react together , under standard conditions to form 1 mole of water