equilibrium II Flashcards

1
Q

what is partial pressure

A

the pressure an individual gas exerts

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2
Q

what is the total pressure

A

sum of all the partial pressure of the individual gases

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3
Q

what is a mole fraction

A

portion of a gas mixture that is a particular gas

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4
Q

mole fraction of gas in a mixture equation

A

mole fraction of gas in a mixture= number of moles / total number of moles of gas in the mixture

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5
Q

partial pressure of a gas equation

A

partial pressure of gas = mole fraction x total pressure of the mixture

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6
Q

What is Kp and how is it different from Kc?

A

Kp is an equilibrium constant used for equilibria involving gases. Its expression is similar to Kc, but instead of concentrations, it deals with partial pressures of gases.

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7
Q

What is the expression for the equilibrium constant
Kp for the reaction
aA+bB⇌dD+eE involving gases?

A

K = p(D)^dp(E)^e(g)/p(A)^ap(B)^b

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8
Q

When writing an expression for Kp for a heterogeneous equilibrium, what components should be included?

A

Only include gases in the expression

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9
Q

How do changes in concentration, pressure, and temperature affect equilibrium constants kc and kp

A

Concentration and pressure changes do not affect the values of kc and kp
. They alter the amounts of products and reactants at equilibrium, but the ratio remains constant.
Temperature changes affect both the amounts of products and reactants at equilibrium and the values of the equilibrium constants.

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10
Q

What effect do catalysts have on the position of equilibrium and the values of Kc and Kp

A

Catalysts have no effect on the position of equilibrium or the value of Kc and Kp
They cannot increase yield, but they do accelerate the approach to equilibrium.

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