ESTERFICATION Flashcards

1
Q

True or false? The purpose of refluxing this reaction is to maintain a constant temperature.
True
FALSE

A

false

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2
Q

True/False Le Chatelier’s principle says that equilibrium will respond to external changes in order to re-establish equilibrium. In this experiment you will perturb an equilibrium, push it to the side of the products by using a high concentration of one of the reactants.

True
False

A

True

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3
Q

Why should the “water IN” connection be at the bottom of the condenser and not the top? Select all that apply.

Connecting at the bottom ensures that the condenser is filled with water.
The condenser is colder at the bottom.
It warms up the condenser better

A

Connecting at the bottom ensures that the condenser is filled with water.
The condenser is colder at the bottom.

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4
Q

Why can’t you isolate the product in your reaction by crystallization?

The product is a solid
The product is a liquid

A

The product is a liquid

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5
Q

What method will you use to isolate your product?
recrystallization
extraction
distillation

A

extraction

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6
Q

You will need to extract the acid catalyst and any unreacted acid reactant using a base solution. What base will you use?
sodium hydroxide
sodium chloride
sodium sulfate
sodium bicarbonate

A

sodium bicarbonate

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7
Q

After extracting you will need to dry the reaction mixture. What will you use to dry it with?
sodium hydroxide
sodium chloride
sodium sulfate
sodium bicarbonate

A

sodium sulfate

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8
Q

What is the role of the Amberlyst-15 catalyst?
To speed up the reaction
To lower the activation energy barrier
To enable the reactants to overcome the activation energy barrier
All of the above!

A

All of the above!

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9
Q

What is the purpose of refluxing the reaction?
To heat the reaction mixture
To provide thermal energy to the reactants
To enable the reactants to overcome the activation energy barrier
All of the above!

A

All of the above!

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10
Q

The sodium sulfate is added at the end of the procedure as a drying agent. Which is/are the most important intermolecular forces between the sodium sulfate and the water?

There are two correct answers. Both need to be selected for credit.

Dipole-Dipole Forces

Ion-Dipole Forces

Hydrogen bonding
Induced Dipole (London Dispersion Forces)
Hydrophobic interactions

A

Ion-Dipole Forces

Hydrogen bonding

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11
Q

Extraction of unreacted acetic acid into the water layer is aided by converting it from its neutral form into an ionic form because ions are more soluble in water. What is the charge on the acetic acid in its ionic form?
positive
Negative

A

Negative

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12
Q

During extraction, the organic layer is on the top and the aqueous layer is at the bottom. Which is more dense, the organic layer or the aqueous layer?
Organic layer
Aqueous layer

A

Aqueous layer

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13
Q

Why is it better to use the weaker base here?

The ester will react with the stronger base
Using NaHCO3 helps extraction by liberating CO2
Using NaHCO3 makes the reaction involved in extraction irreversible
All of the above!

A

All of the above!

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14
Q

Why does the water go into the bottom of a water condenser and not the top?
A. So that the water fills the condenser
B. So that the cold part is at the bottom
Both A and B are correct!
Actually, water should go in to the top, not the bottom

A

Both A and B are correct!

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15
Q

For the biodiesel lab experiment

Choose the correct reagents for the reaction
Choose the correct catalyst for the reaction

A
  1. canola oil/methanol
  2. 2/ potassium carbonate
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15
Q

For the biodiesel lab experiment

Choose the correct reagents for the reaction
Choose the correct catalyst for the reaction

A
  1. canola oil/methanol
  2. 2/ potassium carbonate
16
Q

How many C=C double bond(s) does the following unsaturated fatty acids in Canola oil have?

I: trans-oleic acid

II: cis-oleic acid

III: linoleic acid

A

I: 1, II: 1, III: 2

17
Q

Is this reaction acid catalyzed or base catalyzed?
Acid catalyzed
Base catalyzed

A

Base catalyzed

18
Q

What is the purpose of adding acetic acid (vinegar) to the reaction flask after the reaction is complete?
Used as a drying agent
Neutralize the acid before extraction

Neutralize the base before extraction

A

Neutralize the base before extraction

19
Q

Carbonic acid is unstable in water and will spontaneously decompose into _____ and ____

A

carbon dioxide and water

20
Q

After adding acetic acid in water (vinegar) what will be in the organic layer?
Ethyl ester
Glycerol
Methyl ester
Acetic acid

A

Methyl ester

21
Q

fter adding acetic acid in water (vinegar) what will be in the aqueous layer?!
CH3COOK
Water
Glycerol
Methy ester
Ethyl ester

A

CH3COOK
Water
Glycerol