exam 1 Flashcards
solution
homogenous mixture
solvent
what there’s most of
solute
what is getting dissolved/less of
soluble
solute readily dissolves in solvent
insoluable
only a small part dissolves
enthalpy
exothermic/downhill/the drive to maximum randomness/more powerful/sometimes favors solution formation/negative/bond forming
entropy
always favors solution forming/endothermic/random order in regard to energy/positive/bond breaking
dispersion factors
every molecule
dipole dipole
attraction from negative and positive side of polar molecules
hydrogen bond
bond with nitrogen and fluorine for nonpolar
ion dipole forces
neutral molecule that has a dipole and an ion
dipole
bond or molecule that has opposite charges on the ends
miscible
substances that can mix in any proportion from a homogeneous mixture
non volatile
a substance that does not readily evaporate into a gas under normal conditions
molarity
moles of solute and liters of solution
molality
moles of solute /kg if solvent
temperature
gas: more solvable at cold than hot
solids: varies with solute but mostly higher temps
liquids: more solvable at higher temp
molar mass
mass of solute/mass of solvent and solute
nonvolatile solute causes
vapor pressure of solution to lower
boiling point of solution to be greater
melting point of solution to be lower
increases osmotic pressure of solution
catalyst
increase rate of reactions. consumed early in mechanism and regenerate later.
intermediates
generated early consumed later
zero order
linear: [a] half life: [a]/2k
first order
linear:In[a] half life In[2]/k
second order
linear : 1/[a] half life 1/k[a]