exam 1 Flashcards

1
Q

solution

A

homogenous mixture

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2
Q

solvent

A

what there’s most of

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3
Q

solute

A

what is getting dissolved/less of

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4
Q

soluble

A

solute readily dissolves in solvent

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5
Q

insoluable

A

only a small part dissolves

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6
Q

enthalpy

A

exothermic/downhill/the drive to maximum randomness/more powerful/sometimes favors solution formation/negative/bond forming

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7
Q

entropy

A

always favors solution forming/endothermic/random order in regard to energy/positive/bond breaking

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8
Q

dispersion factors

A

every molecule

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9
Q

dipole dipole

A

attraction from negative and positive side of polar molecules

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10
Q

hydrogen bond

A

bond with nitrogen and fluorine for nonpolar

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11
Q

ion dipole forces

A

neutral molecule that has a dipole and an ion

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12
Q

dipole

A

bond or molecule that has opposite charges on the ends

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13
Q

miscible

A

substances that can mix in any proportion from a homogeneous mixture

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14
Q

non volatile

A

a substance that does not readily evaporate into a gas under normal conditions

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15
Q

molarity

A

moles of solute and liters of solution

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16
Q

molality

A

moles of solute /kg if solvent

17
Q

temperature

A

gas: more solvable at cold than hot
solids: varies with solute but mostly higher temps
liquids: more solvable at higher temp

18
Q

molar mass

A

mass of solute/mass of solvent and solute

19
Q

nonvolatile solute causes

A

vapor pressure of solution to lower
boiling point of solution to be greater
melting point of solution to be lower
increases osmotic pressure of solution

20
Q

catalyst

A

increase rate of reactions. consumed early in mechanism and regenerate later.

21
Q

intermediates

A

generated early consumed later

22
Q

zero order

A

linear: [a] half life: [a]/2k

23
Q

first order

A

linear:In[a] half life In[2]/k

24
Q

second order

A

linear : 1/[a] half life 1/k[a]

25
unimolecular
rearrangement or decomposition k[a]
26
bimolecular
collision k[a][b] or k[a]^2
27