Exam 1 Flashcards

(41 cards)

1
Q

What bonds can rotate?

A

Single bonds

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2
Q

Cis configuration

A

Substituents are on the same side

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3
Q

Trans configuration

A

Substituents are on opposite sides

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4
Q

Isomers

A

different compounds with the same molecular formula

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5
Q

Constitutional isomers

A

Same molecular formula but different arrangement of atoms or connectivity (aka structural isomers)

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6
Q

Stereochemical isomers

A

Same constitutional order but different spatial arrangement (includes cis-trans isomers)

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7
Q

Bronsted acid

A

Proton donor

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8
Q

Bronsted base

A

Proton acceptor

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9
Q

What is the order of factors that affect stability?

A
  1. Charge
  2. Atom (Electronegativity or size)
  3. Resonance
  4. Inductive effect
  5. Hybridization
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10
Q

Electrophile

A

an electron-deficient atom or molecule (Lewis acid)

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11
Q

Nucleophile

A

an electron-rich atom or molecule (Lewis base)

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12
Q

How many carbons does the prefix meth- stand for?

A

1

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13
Q

How many carbons does the prefix eth- stand for?

A

2

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14
Q

How many carbons does the prefix prop- stand for?

A

3

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15
Q

How many carbons does the prefix but- stand for?

A

4

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16
Q

How many carbons does the prefix pent- stand for?

A

5

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17
Q

How many carbons does the prefix hex- stand for?

18
Q

How many carbons does the prefix hept- stand for?

19
Q

How many carbons does the prefix oct- stand for?

20
Q

How many carbons does the prefix non- stand for?

21
Q

How many carbons does the prefix dec- stand for?

22
Q

Hydrocarbon functional group with single bonds

23
Q

Hydrocarbon functional group with double bond(s)

24
Q

Hydrocarbon functional group with triple bond(s)

25
Aromatic
At least one ring with double bonds
26
Alkyl
A chain of carbon and hydrogen atoms that is missing a hydrogen atom (R)
27
Aryl
Any functional group or substituent derived from an aromatic ring
28
Phenyl
A cyclic group of atoms with the formula C6H5
29
Alcohol
Group with hydroxy (-OH) group (R-OH)
30
Ether
Characterized by an alkoxy group, an oxygen bonded to two alkyl groups (R-O-R')
31
Ketone
Characterized by carbonyl (C=O) group, bonded to 2 alkyl groups
32
Aldehyde
Characterized by carbonyl (C=O) group, bonded to one alkyl group and one hydrogen atom
33
Carboxylic acid
Characterized by carboxy group (RCOOH)
34
Ester
Characterized by a carbonyl group bonded to an alkyl group and an oxygen that is also bonded to an alkyl group
35
Amide
Characterized by a carbonyl group bonded to an alkyl group and a nitrogen that is bonded to two alkyl groups or hydrogen atoms
36
Primary amine
Characterized by N bonded to one alkyl group and two hydrogen atoms
37
Secondary amine
Characterized by N bonded to two alkyl group and one hydrogen atom
38
Tertiary amine
Characterized by N bonded to three alkyl groups
39
Nitrile
Characterized by cyano group (C triple bond N) (RCN)
40
Thiol
R-S-H
41
Sulfide/thioether
R-S-R