Exam:2 Flashcards

(42 cards)

1
Q

Spectator Ion

A

An ion that doesn’t participate in a reaction

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2
Q

Saturated solution

A

A solution with the maximum possible
amount of a substance dissolved in it (Q=Ksp)

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3
Q

Unsaturated solution

A

A solution with lower concentrations
than a saturated solution (Q<Ksp) (No precipitation)

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4
Q

Supersaturated solution

A

A solution with higher concentrations
than a saturated solution (Q>Ksp) (precipitation will form)

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5
Q

In a rice table, are the products positive while reactants negative?

A

Yes,
Products = Positive (Right)
Reactants = Negative (Left)

Ksp=Products/Reactants

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6
Q

Common ion effect

A

If a solution has an ion in common with a solid, the solid will be less
soluble

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7
Q

Determining which is more soluable in water.

A

If the Ksp is bigger = more soluble
If the Ksp is smaller = less soluble

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8
Q

Sulfate (SO4) Charge
Sulfite (SO3) Charge

A

-2

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9
Q

Phosphate (PO4) ,
Phosphide (PO3) Carges

A

-3

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10
Q

Nitrate (NO3) Charge
Nitrite (NO2) Charge

A

-1

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11
Q

Bicarbonate (HCO3) Charge
Hydroxide (OH) Charge

A

-1

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12
Q

Acetate (C2H3O2) Charge
Ammonium (NH4) Charge

A

Ace. : -1
Amm. : +1

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13
Q

If a Molecule is both a hydrogen donor/acceptor, it is a…?

A

Ambiprotic

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14
Q

Acidic Solution vs. Basic Solution

A

A solution that contains extra [H+] is called acidic
A solution that can absorb extra [H+] is called basic

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15
Q

Protonating vs. De-protenating

A

Adding an [H+] = protonating
Removing an [H+] = de-protonating

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16
Q

When reacting acid with water

A

Acid + Water = H30 + Conjugate Base

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17
Q

When reacting base with water

A

Wase + Water=HO- + Conjugate base

18
Q

Strong Acids (6)

A

[HCI] : Hydrochloric Acid

[HBr] : Hydrobromic Acid

[HI] : Hydroiodic Acid

[HNO3] : Nitric Acid

[HCIO4] : Perchloric Acid

[H2SO4] : Sulfuric Acid

19
Q

For Strong Acids, is the Ka greater than or less than (1) ?

A

Ka&raquo_space; 1

20
Q

Weak Acids (4)

A

[HF] : Hydrofluoric Acid

[HC2H302] : Acetic Acid

[H2SO3] : Sulforus Acid

[H3PO4] : Phosphoric Acid

21
Q

For Weak Acids, what is the Ka constant and is it greater than or less than (1)

A

Ka = 3.5 x 10 ^-4

Ka<1

22
Q

Strong Bases (8)

A

[LiOH] : Lithium Hydroxide

[NaOH] : Sodium Hydroxide

[KOH] : Potassium Hydroxide

[RbOH] : Rubidium Hydroxide

[CsOH] : Cesium Hydroxide

[Ca(OH)2] : Calcium Hydroxide

[Sr(OH)2] : Strontium Hydroxide

[Ba(OH)2] : Barium Hydroxide

23
Q

Weak Bases (Explanation)

A

Similar reactions as Bases (H20–> OH-), However the arrows go both ways indicating that there is partial dissasociation in the presense of water.

24
Q

Moles of Acid = …

A

Moles of Base

25
For Weak Acids and Bases (only) what represents them at equilibrium?
Weak acid: equilibrium constant Ka Weak base: equilibrium constant Kb
26
How to determine which Weak acid or base is stronger...
EX] If A has a LARGER Ka than B, we say A is a stronger acid than B
27
Kw Constant
1.00 x 10^-14
28
Ka X Kb = ...
Kw [C][D]/[A][B]
29
If you have both Kw and Kb; solving for for Ka (vice versa). How would you solve?
[Kb]=[Kw]/[Ka]
30
Turning Scientific Notation into (P) Variables
EX] [H] = 1.0x10^-6 = 0.000006 P[H] = -Log10 (1.0x10^-6) = 6.000
31
All (P) Values (4)
[H+] = pH [OH-] = pOH [Ka] = pKa [Kb] = pKb
32
as pH = -Log10 (H+), how does it look in reverse
10^pH
33
pH vs. H+ (Acid Added) (Base Added)
Acid Added: H+ : Increase pH: Decrease Base Added: H+: Decrease pH: Increase
34
pOH vs. OH- (Acid Added) (Base Added)
Acid Added: H+ : Decrease pH: Increase Base Added: H+: Increase pH: Decrease
35
pH <-> pOH
pH + pOH = 14
36
H+ <-> OH
Kw= [H+][OH]
37
ph --> H H--> pH
1) 10^-ph 2) -Log10[H+]
38
pOH --> OH OH--> pOH
1) 10^-pOH 2) -Log10[OH-]
39
pKa<-->pKb
pKa + pKb = 14
40
pKa --> Ka Ka --> pKa
1) 10^-pKa 2) -Log10(Ka)
41
pKb --> Kb Kb --> pKb
1) 10^-pKb 2) -log10(Kb)
42