Exam 2 Cards (Aqueous solutions, Strong/Weak Electrolytes, Enthalpy..) Flashcards

(60 cards)

1
Q

NH4+

A

Ammonium

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2
Q

Charge on Ag

A

Ag+

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3
Q

Carbonate

A

CO3(2-)

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4
Q

Phosphate

A

PO4(3-)

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5
Q

Phosphoric acid

A

H3PO4

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6
Q

Oxidation Rule 1: Sum of oxidation numbers for a neutral compound?

A

The sum of oxidation numbers for a neutral is ZERO

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7
Q

Oxidation Rule 2: Sum of oxidation numbers for a polyatomic ion?

A

The sum will be the same as the charge of the polyatomic ion

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8
Q

Oxidation Number of an atom in its elemental state

A

0

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9
Q

Oxidation Number of a monatomic ion

A

same as the charge on the ion

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10
Q

Oxidation Number of F

A

ALWAYS -1

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11
Q

Oxidation Number of Group 1A?

A

Always +1

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12
Q

Oxidation Number of Group 2A

A

Always +2

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13
Q

Oxidation Number of Aluminum

A

Always +3

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14
Q

Oxidation Number of Hydrogen

A

if in a compound with NONMETALS: +1

if in a compound with METALS: -1

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15
Q

Oxidation Number of Oxygen

A

Usually -2

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16
Q

Units of ΔHfO

A

kJ/mol

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17
Q

Determination of ΔH from ΔHfO values

A

Summation of (a)(ΔHfO) [products] - Summation of (b)ΔHfO[reactants]

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18
Q

micro

A

10^-6

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19
Q

pico

A

10^-12

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20
Q

oxidation numbers of: Cl, Br,I

A

usually -1

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21
Q

cal

A

calorie: 1 cal = 4.184 J exactly

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22
Q

milli

A

10^-3

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23
Q

centi-

A

10^-2

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24
Q

deci-

A

10^-1

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25
giga
10^9
26
mega
10^6
27
kilo
10^3
28
Polyatomic molecules
P4, S8
29
ΔH is dependent on these 4 properties
1. temp 2. pressure 3. concentration 4. physical state of matter
30
Diatomic molecules
Br2, Cl2, F2, O2, N2, I2, H2
31
nano
10^-9
32
C to K
C + 273= K
33
Hess' Law
rearrange the given equations to match the desired equation- be sure to manipulate the ΔH as necessary
34
kcal
kilocalorie 1kcal= 1000 cal, 1 CAL = 1 food calorie
35
standard enthalpy of formation
1 MOL ΔH = ΔHfO
36
q
heat
37
if q
exothermic (energy is being released)
38
if q>0
endothermic (energy is being absorbed)
39
Bomb calorimetry
qrxn= CcalΔT + cH2OMH2OΔT **THIS IS ENDOTHERMIC
40
kJ
1000J
41
Common Strong Bases (4)
M*OH (M = metal group 1A) Ca(OH)2 Sr(OH)2 Ba(OH)2
42
Hydrogen Displacement reaction
M + HX--> MX + H2 (g) M> H2 on activity scale for a reaction M= cation X= anion
43
Metal Hydroxide Bases (Acid-Base neutralization Reactions)
acid + base--> salt + H2O | salt formation: the cation is from the base and the anion is from the acid
44
Metathesis Reactions Rule
AB + CD--> AD + CB A & C = cations B & D= anions
45
Common weak acids
if not listed as strong, then weak
46
common weak bases
NH3
47
Salts
any compound where the anion is NOT OH-
48
Common Strong Acids
``` HCl HBr HI HNO3 H2SO4 HClO4 ```
49
Precipitate Reactions
AB + CD--> AD + CB A/C= cations B/D= anions either AD or CB MUST be insoluble for a reaction to occur
50
c
specific heat (J/gxC)
51
NH3 as a weak base in acid-base neutralization
acid + NH3--> SaltNH+ the cation is NH3, the anion come from the acid the saltNH4+ is ALWAYS soluble
52
Gas formation reaction
metal carbonate + acid --> salt + CO2 (g) + H2O (l) salt formation: anion from acid, cation from carbonate metal carbonate M(CO3(2-))
53
metal displacement reaction
M + M'X --> M' + MX X= anion (goes unchanged) M'= cation M>M' on activity series for a reaction to occur
54
C
heat capacity | C= cm
55
Dilution of a solution
M1V1= M2V2
56
M (molarity)
mol/L
57
Calorimetry equation
q= cmΔT or q= CΔT
58
% yield equation
experimental/theoretical x 100
59
ΔHO--> ΔHOf
elements --> 1 MOL substance
60
ΔT
temperature change (Tfinal-Tinitial)