Exam 3 Flashcards

(51 cards)

1
Q

Electron

A

Subatomic particle with a negative charge and smallest of the main three subatomic particles.

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2
Q

Proton

A

Subatomic particle with positive electrical charge.

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3
Q

Neutron

A

Subatomic particle with no charge.

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4
Q

Nucleus

A

Small dense, positively charged center of atom containing all protons and neutrons.

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5
Q

Nucleon

A

Any subatomic particle found in nucleus of an atom.

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6
Q

Electron Configuration

A

1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p⁶5s²4d¹⁰5p⁶

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7
Q

Periodic Trends: Atomic Size

A

Top Right to Bottom Left: Increasing atomic size

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8
Q

Periodic Trends - Ionization Energy

A

Bottom Left to Top Right: Increasing ionization energy

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9
Q

Ionic Bond

A

Bond between metal and nonmetal

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10
Q

Covalent Bond

A

Chemical bond involving sharing of electrons between atoms in a molecule (nonmetals)

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11
Q

Bonding Electron

A

Pairs of valence electrons that are shared between atoms in a covalent bond.

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12
Q

Nonbonding electrons(lone pair electrons)

A

Pairs of valence electrons on an atom that are not involved in electron sharing.

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13
Q

HONC(Neutral molecules)

A

1234
Number of bonds

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14
Q

Electron Group Geometry: 2 Electron Groups

A

EG: Linear
Predicted Bond Angle: 180°

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15
Q

Electron Group Geometry: 3 Electron Groups

A

EG: Trigonal Planar
Predicted Bond Angle: 120°

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16
Q

Electron Group Geometry: 4 Electron Groups

A

EG: Tetrahedral
Predicted Bond Angle: 109.5°

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17
Q

Linear Electron Domain

A

MG: Linear

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18
Q

Trigonal Planar Electron Domain

A

All e- domains = Bonds: trigonal planar
One e- domain = Nonbonding: Bent/angular

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19
Q

Tetrahedral Electron Domain

A

All e- domains = BondingPair: Tetrahedral
One nonbonding pair e- domain: Trigonal Pyramidal
Two nonbonding pair e- domain: Bent/angular

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20
Q

Electronegativity

A

Measure of relative attraction that an atom has for the shared electron in a bond. Determined by nuclear charge and number of other electrons present in electron shell.

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21
Q

Bond Polarity

A

Measure of the degree of inequality in the sharing of electrons in a chemical bond.

22
Q

Nonpolar Covalent Bond

A

Covalent bond in which there is equal sharing of electrons between two atoms.

23
Q

Polar Covalent Bond

A

Covalent bond in which there is unequal sharing of electrons between two atoms.

24
Q

Trait of Polar Covalent Bonds

A

The greater the difference in electronegativity, the more polar is the bond.

25
Nonpolar Covalent Bond (Electronegativity)
Difference of 0 - 0.4
26
Polar Covalent Bond (Electronegativity)
Difference of 0.5 - 2.0
27
Ionic Bond (Electronegativity)
Difference of > 2.0
28
Molecular Polarity
Measure of the degree of inequality in the attraction of bonding electrons to various locations within a molecule.
29
Polar Molecule
Asymmetrical distribution of electronic charge.
30
Nonpolar molecule
Symmetrical distribution of electronic charge.
31
Finding Polarity of Molecules
1: Is compound covalent? 2: Are the bonds polar? 3: Is the molecule asymmetrical.
32
Gas
State of matter with no fixed shape and no fixed volume.
33
Pressure
Pressure = Force/Area
34
mm Hg to torr
1 mm Hg = 1 torr
35
atm to mm Hg
1 atm = 760 mm Hg
36
atm to psi
1 atm = 14.7 psi = 101,325 Pa
37
Boyle's Law (Pressure & Volume)
P₁V₁ = P₂V₂
38
Charles's Law (Volume & Temperature)
V₁/T₁ = V₂/T₂
39
Gay-Lussac's Law (Pressure & Temperature)
P₁/T₁ = P₂/T₂
40
Combined Gas Law (Pressure, Volume, Temperature)
P₁V₁/T₁ = P₂V₂/T₂
41
Avogadro's Law (Volume, Number)
V₁/n₁ = V₂/n₂
42
Ideal Gas Law (All)
P₁V₁/n₁T₁ = P₂V₂/n₂T₂
43
Dalton's Law of Partial Pressures
Total pressure exerted by mixture of gases is sum of partial pressure of individual gases present.
44
Standard Temperature and Pressure (STP)
1 atm and 273 K (0° C)
45
Molar Volume
Volume of one mole of gas at STP = 22.4L
46
Heats of Fusion
ΔHբᵤₛᵢₒₙ = kJ/mol
47
Heat of Vaporization
ΔHᵥₐₚ = kJ/mol
48
Intermolecular Force(IMF)
Attractive Force that acts between molecules influencing melting points, boiling points, viscosity and surface tension.
49
Dispersion Force
Weak temporary intermolecular force that occurs between an atom or molecule and another atom or molecule. 1) Number of e- in atom (more e-, more dispersion force) 2) Size of atom/molecule/molecular weight. 3) Shape of molecules with similar masses (more compact, less dispersion force)
50
Dipole-dipole interactions
IMF that occurs between polar molecules. 1) Greater the polarity, the greater the dipole-dipole interaction.
51
Hydrogen Bonding
Extra strong dipole-dipole interaction involving molecules with an H atom covalently bonded to small, very electronegative atom. H-F H-O H-N