Exam 4 Flashcards

(49 cards)

1
Q

Defined as one-half the distance between the centers of two adjacent atoms

A

Metallic radius

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2
Q

Defined as one-half the distance between the centers of the atoms in the molecules

A

Covalent radius

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3
Q

The minimum energy(kJ/mol) required to remove sn electron from a gaseous atom in its ground state

A

Ionization energy

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4
Q

The negative of the energy change that occurs when an electron is accepted by an atom in the gaseous state to form an anion

A

Electron affinity

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5
Q

X + e = X-

A

Electron affinity

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6
Q

Have the same number of electrons, and hence the same ground-state electron configuration
Ex. Na+, Al3+, F-, O2-, and N3-

A

Isoelectronic

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7
Q

The positive charge felt by an electron

A

Effective nuclear charge(Zeff)

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8
Q

The outer shell electrons of an atom. Participate in chemical bonding

A

Valence electrons

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9
Q

The electrostatic force that holds ions together in an ionic compound

A

Ionic bond

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10
Q

The energy required to completely separate one mole of a solid ionic compound into gaseous ions

A

Lattice energy

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11
Q

A chemical bond in which two or more electrons are shared by two atoms

A

Covalent bond

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12
Q

Two atoms share two pairs of electrons

A

Double bond

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13
Q

Two atoms share three pairs of electrons

A

Triple bond

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14
Q

A covalent bond with greater electron density around one of the two atoms

A

Polar covalent bond or polar bond

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15
Q

The ability of an atom to attract toward itself the electrons in a chemical bond

A

Electronegativity

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16
Q

The difference between the number of valence electrons in an isolated atom and the number of electrons assigned to that atom in a leeis structure

A

Formal charge

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17
Q

One of two or more lewis structures for a single molecule that cannot be represented accurately by only one lewis structure

A

Resonance structure

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18
Q

The enthalpy change required to break a particular bond in one mole of gaseous molecules

A

Bond enthalpy

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19
Q

The distance between identical points on successive waves

A

Wavelength

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20
Q

The vertical distance from the midline of a wave to the peak or trough

21
Q

The number of waves that pass through a particular point in 1 second

22
Q

The interaction between waves

23
Q

Waves that interact so that they add to make a larger wave are said to be in phase

A

Constructive interference

24
Q

Waves that interact so that they cancel each other are said to be out of phase

A

Destructive interference

25
n-l-1
Equation to find nodes
26
Represents the total probability at a certain distance from the nucleus
Radial distribution function
27
Principle quantum number(energy level)
n
28
Angular momentum quantum number(orbital type)
l
29
Magnetic quantum number(position of orbital)
ml
30
Spin quantum number(orientation of the spin)
ms
31
The more accurately you know the position of a small particle, such as an electron, the less you know about its speed(momentum), and vice versa
heisenberg's uncertainty principle
32
Allows us to calculate the probability of finding an electron with a particular amount of energy at a particular location in the atom
Schrodinger's equation
33
A probability distribution map of a region where the electron is likely to be found
Orbital
34
Represents the total probability of finding an electron at a particular point in space
Probability density function
35
Same sign
Phase
36
Opposite signs
Out of phase
37
The sign of the wave function
Phase
38
Distance of electrons from the nucleus
n
39
Spherical
S orbitals
40
Like two balloons tied at the knots(dumbbell shape)
P orbital
41
Like four balloons toed at the knots
D orbital
42
Like eight balloons tied at the knots
F orbital
43
Shape of the volume of space that electron occupies
l
44
Orientation of the orbital in space
ml
45
No two electrons in an atom can have the same four quantum numbers
Pauli exclusion principle
46
Fill-up electrons in lowest energy orbitals
Aufbau principle
47
The most stable arrangement of electrons in subshells is the one with the greatest number of parallel spins
Hund's rule
48
Unpaired electrons
Paramagnetic
49
All electrons paired
Diamagnetic