Exam III Flashcards

(54 cards)

1
Q

What is ideal gas law?

A

PV = nRT; P=pressure, V=volume, n=# of mols, T=temp in Kelvin, R=0.0821

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2
Q

convert 760mmHg to torr, atm, psi, pascals

A

760 torr, 1 atm, 14.7 psi, 101,325 pascals

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3
Q

Which Gas Law? For a fixed amount of a gas at constant temp, the volume is inverse to the pressure

A

Boyle’s Law

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4
Q

What is Boyle’s Law?

A

P1V1 = P2V2

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5
Q

Which Gas Law? The volume of a fixed amount of gas at constant pressure is directly propotional to its temp in K

A

Charle’s Law

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6
Q

What is Charle’s Law?

A

V1/T1 = V2/T2

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7
Q

Which Gas Law? At a fixed temp and pressure, the volume of a gas is directly proportional to the # of mols of that gas

A

Avogadro’s Law

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8
Q

What is Avogadro’s Law?

A

v1/n1 = V2/n2

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9
Q

Which Gas Law? Relates pressure, volume, # of mols, temp all in one equation

A

Ideal gas low

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10
Q

What is General Gas Equation?

A

P1V1/T1 = P2V2/T2

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11
Q

Which Gas Low? The sum of the partial pressures exerted by each individual gas is the total pressure of the system

A

Dalton’s Law of Partial Pressures

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12
Q

What is Dalton’s Law of Partial Pressures?

A

Pt = P1 + P2 + P3?

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13
Q

Average Kinetic Energy is?

A

directly proportional to the temp of the system

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14
Q

What is Diffusion?

A

molecular movement of a gas going high consentration to lower

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15
Q

What is Effusion?

A

movement of gas through an opening

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16
Q

What is Graham’s Law?

A

rates of effusion of 2 different gases in inversely proportional to the square root of their molar masses

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17
Q

What is Polarity?

A

the tendency for a partial charge separation to occur within a molecule, either via lack of symmetry or via differences in electronegativity

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18
Q

What is intermolecular forces?

A

those in addition to bonds, that exist among different molecules

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19
Q

What is intramolecular forces?

A

those forces that exist within a molecule and help determine its preferred conformation

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20
Q

What is Dipole-Dipole interaction?

A

in polar compounds, the partially positive (delta+) end aligning itself with the partially negative (delta-) end of another molecule

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21
Q

What is Hydrogen Bonding?

A

the electrostatic attraction between polar molecules that occurs when a H atom bound to a highly electronegative atom such as FON

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22
Q

What is London Dispersion Forces?

A

The weakest intermolecular force. A temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

23
Q

What are the forces acting among molecules called?

24
Q

What are the forces acting between molecules and the surface of the container called?

25
What is the tendency of a liquid to rise in narrow tubes or to be drawn into small openings?
capillary action
26
What is the phase? Change between liquid and gaseous states of matter
Vavorization/evaporation
27
What is the pressure a liquid excerts on the atmosphere?
vapor pressure
28
What is the pressure the atmosphere excerts on the liquid?
atmospheric pressure
29
Increase atmospheric pressure = (increase/decrease) vapor pressure = (increase/decrease) boiling point
decrease VP, increase BP
30
Increase temp = (increase/decrease) kinetic energy = (increase/decrease) vapor pressure
increase KE, increase VP
31
Increase surface area of liquid = (increase/decrease) molecules intencity with atomospheric pressure = (increase/decrease) evaporative rate
increase MI, increase ER
32
What is this phase change? Solid -> Liquid -> Gas
melting, evaporation
33
What is this phase change? Gas -> Liquid -> Solid
condensation, freezing
34
What is this phase change? Solid -> Gas
sublimation
35
What is this phase change? Gas -> Solid
deposition
36
What is Heating Curves?
graphically represent the phase changes for a substance
37
What is Phase Diagram?
represents the conditions supporting different states of matter for a substance
38
What is tha set of contions that supports all 3 states of matter (solid, liquids, and gas)?
triple point
39
What is Covalent Solids?
have a network of covalent bonds throughout the crystal unit
40
What is Ionic Solids?
contain gaseous cations and anions hold together in a matrix
41
What is crystalline solids?
highly regular repeating network of atoms
42
What is amorphous solid?
no order in the network of atoms
43
What is the system? Neither heat nor matter is exhanged with the surroundings
isolated
44
What is the system? Can exchange evergy, but not matter with the surroundings
closed
45
What is the system? Exchanges both energy and matter with the surroundings
open
46
Processes - conducted at some temp
isothermal
47
Processes - conducted at some pressure
isobaric
48
Processes - not heat exchange occurs
adiabatic
49
stored energy
potential
50
energy in motion
kinetic
51
Derived from molecular motion, or temp of the system, also known as enthalpy
termal energy
52
energy released as heat
friction
53
1 calorie = ? Joules
4.184
54
regardless of the multiple stages or steps of a reaction, the total enthalpy change for the reaction is the sum of all changes
Hess's Law