Experiment #12: QUALITATIVE ANALYSIS OF LIPIDS Flashcards

(59 cards)

1
Q

Acrolein test

A

Test for the presence of glycerol in a molecule

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2
Q

A strong acid and a strong dehydrating reagent

A

Potassium bisulfate

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3
Q

When potassium bisulfate is heated with fat

A

Hydrolysis occurs

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4
Q

The glycerol produced is dehydrated to form

A

Acrolein

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5
Q

General formula of Acrolein

A

CH2=CHCHO

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6
Q

The reaction between ______ and _________ results in _________

A

Glycerol, potassium hydrogen sulfate (potassium bisulfate), acrolein formation

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7
Q

The acrolein formation is characterized physically by the release of

A

Pungent smell

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8
Q

Has alcohol functional group

A

Glycerol

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9
Q

Also called glycerine

A

Glycerol

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10
Q

Characteristics of glycerol

A

Colorless, odorless, viscous liquid, sweet tasting, non-toxic

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11
Q

Glycerol backbone found in lipids

A

Glycerides

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12
Q

Glycerol( positive control)

A

Positive with glycerol

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13
Q

Coconut oil

A

Positive with glycerol

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14
Q

Canola oil

A

Positive with glycerol

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15
Q

Butter

A

Positive with glycerol

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16
Q

Lard

A

Positive with glycerol

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17
Q

Test to determine the unsaturation of the oil (with atleast one double bond)

A

Bromine test

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18
Q

2 types of lipids

A

Saturated & Unsaturated

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19
Q

Saturated

A

Solid at room temperature

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20
Q

Liquid at room temperature

A

Unsaturated

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21
Q

Higher is the degree of unsaturation

A

Unsaturated

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22
Q

Lower is the temperature to liquefy it

A

Unsaturated

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23
Q

______ can react with_____ like_____ or _____ due to the presence of

A

Unsaturated fatty acid, halogens, bromine, iodine, double bonds

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24
Q

Bromine goes into the solution forming a______

25
If there is presence of double bonds, the bromine solution will______
Decolorize
26
Absence of double bonds, it imparts its______
Own colors
27
If your sample contains ______, it will ______ with _____ and the ____color of bromine will _______
no double bonds, not react, bromine, yellow, not disappear
28
Even if only ____ drop of bromine is added. If the sample contains _____ bonds, it will react with the added bromine and the ______ color will_____
One, double, yellow, disappear
29
The _____ double bonds present in the sample , the more____ will be needed to react with the sample
more, bromine
30
The ____ color of bromine remains in the solution when all the double bonds have_____
yellow, reacted
31
Oleic acid
2 drops of iodine, unsaturated
32
3 drops of iodine, saturated
Coconut oil
33
Canola oil
2 drops of iodine, unsaturated
34
18 drops of iodine, saturated
Butter
35
20 drops of iodine, saturated
Lard
36
Has one double bonds
Oleic acid
37
One double bonds
Canola oil
38
Unsaturated fats are____ than saturated fats
Healthier
39
Benefits of unsaturated fats
Improve blood cholesterol levels, ease inflammation, stabilize heart rhythms
40
Saturated fats can cause ______, which increases the risk of_______ and _____
Bad LDL cholesterol, heart disease, stroke
41
Saturated fats are _____ and can cause fatty deposits in blood vessels
Solid
42
Fatty Acids
Long chain of carboxylic acids (unbranched)
43
General formula of lauric acid
CH3 (CH2)10COOH
44
Major component of coconut oil
Lauric acid
45
Lauric acid is ____ fatty acid
Saturated
46
Formic acid
The simplest carboxylic acid
47
Secreted by ants and bees
Formic acid
48
All carboxylic acid have_____
COOH
49
Carboxylic acid that can be found at home
Vinegar
50
Organic acid
CH3 COOH
51
a chemical reaction that occurs when a vegetable oil or animal fat (triglycerides, ester) mixed with a strong alkali (NaOH, KOH)
Saponification
52
The products of the reaction of saponification
Soap(fatty acid and salt) and glycerol (free alcohol)
53
The soap produced can be_____ by adding ______ solution, if necessary
Precipitated, concentrated sodium chloride
54
gives "hard soap"
Sodium hydroxide (NaOH)
55
gives "soft" soap or liquid soap because of its greater solubility
Potassium hydroxide (KOH)
56
Soaps are______,_______,_____ and even can lower the surface__________
Cleansing agents, surfactants, emulsifiers, tension of water
57
Mineral salts of fatty acids
Soap
58
The soap is _____ in water but _____ in ether
Soluble, Insoluble
59
Soap works on ________ of oils and fats in the water as it works to reduce the _______ of the solution
Emulsification, attraction surface