F322-Enthalpy Flashcards

0
Q

What would happen to the temperature of the surroundings in an exothermic reaction?

A

It would rise

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1
Q

Define exothermic

A

Heat is given out to the surroundings (reactants lose energy)

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2
Q

Which direction does Delta H go on an exothermic enthalpy diagram?

A

Downwards

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3
Q

Define endothermic

A

Heat is taken in from the surroundings (reactants gain energy)

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4
Q

What would happen to the temperature of the surroundings in an endothermic reaction?

A

It would fall

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5
Q

Which direction does Delta H go on an endothermic enthalpy diagram?

A

It goes upwards

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6
Q

Define standard enthalpy change of formation

A

The enthalpy change that takes place when one mole of a compound is formed from it’s constituent elements(all reactants and products in their standard states and under standard conditions)

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7
Q

Define standard enthalpy change of combustion

A

The enthalpy change that takes place when one mole of a compound reacts completely with oxygen(all reactants and products in their standard states and under standard conditions)

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8
Q

Define standard enthalpy change of reaction

A

The enthalpy change that accompanies a reaction in the molar quantities expressed in the chemical equation(all reactants and products in their standard states and under standard conditions)

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9
Q

Define standard conditions

A

1 atmosphere, 25*C, 1mol dm-3 for all solutions

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10
Q

Write an equation for the enthalpy change of combustion of Propane (C3H8)

A

C3H8(g) + 5O2(g) > 3CO2(g) + 4H2O(l)

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11
Q

Write an equation for the enthalpy change of combustion of CH3OH

A

CH3OH(l) + 1.5O2(g) > CO2(g) +2H2O(l)

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12
Q

Write an equation for the enthalpy change of formation of Sodium Carbonate (Na2CO3)

A

2Na(s) + C(s) + 1.5O2(g) > Na2CO3(s)

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13
Q

What is the equation do find the enthalpy change of reaction using DHF?

A

Products - reactants

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14
Q

Define Average bond enthalpy

A

The average enthalpy change that take place when breaking, by Homolytic bond fission, one mole of a give bond type in the molecules of a gaseous species

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15
Q

How do you calculate average bond enthalpy?

A

Add all the reactants enthalpy together, then add all the products enthalpy together but with a MINUS sign infront. Then add the two values together

16
Q

What is the formula for heat energy lost/gained (Q)

A

Q=mcDeltaT

17
Q

How do you calculate delta H?

A

Q(in kJ) / moles of reactant

18
Q

How do you calculate the enthalpy of formation using DHC

A

Reactants - products

19
Q

What sign shows exothermic

A

Negative

20
Q

What sign shows endothermic

A

Positive

21
Q

Why is the experiment value different to the data book value?

A

Because heat can get lost in the surroundings

22
Q

Why is the value for the average enthalpy different from the real value?

A

Because it is only an average value