Final Flashcards

(45 cards)

0
Q

What does TLC stand for?

A

Thin Layer Chromatography

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1
Q

What is the mobile phase of TLC experiment?

A

The solvent

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2
Q

What are 4 reasons why TLC is used?

A

Analyze compounds
Determine purity of products
Identify a substance
Follow progress of a reaction

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3
Q

How does the compound rise up the TLC plate?

A

By capillary action

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4
Q

The compound that moves the greatest distance on the TLC plate is…

A

Least tightly absorbed to the stationary phase

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5
Q

What are the most common things that cost the TLC plate?

A

Iodine
Sulfuric acid
PMA

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6
Q

What two things did we use in the TLC lab to develop and visualize the spots on the TLC plates?

A

Vinegar

Ammonia

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7
Q

What does Rf stand for?

A

Retention factor

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8
Q

How is the Rf value defined?

A

The ratio of the distance traveled by a particular compound to the distance traveled by the solvent front

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9
Q

What did we soak the filter paper with during the TLC lab?

A

Ethanol:Water

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10
Q

What was our eluent in the TLC lab?

A

Ethanol:Water

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11
Q

What are the three components of the universal indicator?

A

Methyl orange
Bromethyl Orange
Trinitrobentic acid

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12
Q

How many sig figs should be used when calculating Rf value?

A

Record to 2 decimal places

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13
Q

Name some colligative properties

A
Density 
Viscosity
Surface tension 
Boiling point 
Freezing point 
Osmotic pressure 
Vapor pressure
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14
Q

What is a colligative property?

A

Any property that is affected by the amount of solute particle present

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15
Q

What are the units of the freezing point constant? (Kf)

A

K/m

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16
Q

What acid did we use in the freezing point depression lab to determine its molecular weight?

A

Stearic acid

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17
Q

What are the 6 sections that should appear in every lab report?

A
Purpose 
Pre lab assignment 
Procedure 
Data/observations 
Calculations/analysis 
Conclusion
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18
Q

What do the variables stand for in Beer’s Law

A=elc

A

A=absorbable
e=constant
l=cell path length
c=concentration

19
Q

What are the variables in the Arrhenius equation?

A

A=frequency factor
Ea=activation energy
R=universal gas constant
T=temperature in K

20
Q

How can you calculate the activation energy of a reaction given a graph?

A

Multiply the slope by R

21
Q

What is the universal gas constant?

A

8.314J/(mol•K)

22
Q

What exactly is the activation energy?

A

The energy value that must be overcome to turn reactants into products

23
Q

Equation of iron and phenanthroline

A

Fe + 3 phenan. —-> Fe (phen)

                               Orange
24
What are ligands?
Molecules that are able to form coordinate covalent bonds with transition metals
25
Example of Ligands
Ammonia Water Hydroxide
26
Decomposition of 1,10 phenanthroline
Fe(phen) (2+) ----> Fe + 3 phen Red/orange. Colorless
27
What was used as a catalyst in the chemical kinetics lab?
Sulfuric acid
28
Describe le chatliers principe
If stressed is placed on system things shift to reduce stress
29
What is heterogenous equilibrium?
Phases aren't the same
30
What is a saturated solution?
Some salt is in excess of Jenkins that dissolve in the solution
31
What is homogenous equilibrium?
All ions or complexes are in he same phases
32
Fe(3+) + SCN(-) -----> Fe(SCN) (2+) Colorless Red
Thresh
33
What is the common ion effect
2 dissolved solutes that contain the same ion
34
Example of be common ion effect
NaCl and HCl
35
Acidic solution in terms of H+
>1.0 • 10^-7
36
Basic solution in terms of H+
<1.0 • 10^-7
37
What is transmittance?
Amount of light that passed through a solution
38
What is absorbance?
Amount of light grasped by a solution
39
Is water a weak or strong electrolyte?
Weak
40
Equation for ionization of water
H2O H+ + OH-
41
What two ions does the ionization of water produce?
Hydrogen cation | Hydroxide anion
42
Ph for acidic solutions
<6
43
Ph for neutral solutions
6-8
44
Ph for basic solutions
>8