Final Flashcards

0
Q

Millikan experiments

A

Determined charge measurement of e-‘s

Neg charged oil and negatively charged plate

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1
Q

Describe the Thompson experiment and model

A

Cathode ray tube = negatively charged particles

Plum pudding model–negatively charged particles randomly dispersed in a positive cloud

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2
Q

Rutherford experiment and model

A

Alpha particle bombardment of metal foil

Lead to nuclear model of positive proton center

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3
Q

Isotope

A

Same atomic number bit different mass number

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4
Q

Where do atomic number and atomic mass go?

A

Atomic number is bottom left, atomic weight is upper left

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5
Q

Lambda nu=

A

Speed of light

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6
Q

Speed of light =

A

3.00 x 10^8 m/s

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7
Q

h =

A

Planck’s constant

6.626 x 10^-34 J/s

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8
Q

What happens when light strikes a metal surface

A

Electrons are emitted

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9
Q

Einstein suggested that electromagnetic radiation can be viewed as a

A

Stream of photons

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10
Q

The emission spectrum of H shows

A

Discrete wavelengths

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11
Q

What do the discrete wavelengths of the emission spectrum of H indicate?

A

That H has discrete energy levels

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12
Q

Orbitals are characterized by the quantum numbers

A

n, l, msubl

msubs describes e- spin

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13
Q

Pauli exclusion principal

A

No 2 e- in a given atom can have the same set of quantum numbers

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14
Q

Aufbau

A

Building up

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15
Q

Hund’s rule

A

Maximize spin

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16
Q

First , second, third ionization energy

A

The amount of energy required to remove the (highest, second highest etc) energy e- from a given atom

17
Q

Ionization E _______ from left to right on the PTE

18
Q

Ionization energy ________ going down a group

19
Q

E of a photon

A

Delta E = hn
E given in J per photon
Where h = Planck’s constant 6.626 x 10^-34 J/s
n = frequency in s-1

20
Q

De broglies equation

A

Wavelength = Planck’s constant / mass x velocity

21
Q

Atomic mass in g

A

The mass of one mole of an element

22
Q

What is the root mean square velocity?

A
The avg of the squares of the velocity of the particles
Square root of (3RT/M) 
Where R = 8.3145 J/K m
T is in K
M is the molar mass in kg/mol
23
Q

Joule?

A

Kg m^2 / s^2

24
What are the condensed states of matter?
Liquids and solids
25
Intermolecular forces
Interactions btwn molecules that cause liquids and solids to form
26
What are the 3 main types of intermolecular forces?
Dipole-dipole (incl h "bond") induced dipole London dispersion forces
27
What type of dip-dip is unusually strong?
H bond
28
H bonding occurs btwn H and what other atoms
Highly electronegative ones like O, N, F and these have at least one lone pair of e-'s
29
How do we know that molecules without dipole moments exert forces on each other?
All substances, even noble gasses, will exist in liquid and solid states given the right conditions
30
London dispersion forces
Instantaneous dipole moment triggers one in the next molecule and so on
31
The more massive a particle, the _______ the London dispersion forces
Stronger
32
As van der waal forces increase: boiling point _______, freezing point _______, vapor pressure _______, surface tension ________
Increases Increases Decreases Increases
33
Surface tension
The resistance of a liquid to increase its surface area due to intermolecular forces
34
Capillary action
The spontaneous rising of a liquid in a narrow tube
35
Cohesive forces
The intermolecular forces among the molecules of a liquid
36
Adhesive forces
The forces between the liquid molecules and the container
37
The concave shape of a meniscus indicats
Adhesive forces that are stronger than cohesive forces
38
A convex meniscus
Indicates cohesive forces that are stronger than adhesive forces
39
Why is it difficult to form a model for liquids
They exhibit the strong intermolecular forces of a solid but the significant molecular motions of a gas
40
What is allowing our models of liquids to be more accurate?
Spectroscopy