Final Flashcards
(35 cards)
ΔHrxn = …
ΔE + PΔV
ΔE = …
q + W
PΔV = …
-W
frequency =
c/wavelength
Energy =
h*frequency = hc/wavelength
de Broglie relation:
wavelength = h/(m*velocity)
Stupid space donut:
z^2
Positive ΔH and q =
Endothermic. Vaporization.
Negative ΔH and q =
Exothermic. Condensation.
Positive work:
Work done ON the system
Negative work:
Work done BY the system
Constant P:
Lower heat production
Constant V:
More heat production
Paramagnetic:
Has unpaired electrons. Interacts with magnetic field.
Diamagnetic:
No unpaired electrons. Does not interact with magnetic field.
Pauli exclusion principle:
No two electrons can have the same quantum number.
Aufbau principle:
Orbitals fill from lowest to highest energy level.
Hund’s rule:
One electrons per orbital with parallel spin until it becomes necessary to double up.
Exceptions to Aufbau principle:
Cr, Cu
Periodic table trends:
IE? Atomic radius? Metallic character?
IE = He
Radius = Rb
Metallic character = Rb
Lowest IE =
Most exothermic
Cations vs atoms vs anions
Cation < atom < anion
What happens to reactivity as IE decreases?
Reactivity increases
What happens to atom size as effective charge increases?
Atom size decreases