Final Flashcards

(35 cards)

1
Q

ΔHrxn = …

A

ΔE + PΔV

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2
Q

ΔE = …

A

q + W

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3
Q

PΔV = …

A

-W

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4
Q

frequency =

A

c/wavelength

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5
Q

Energy =

A

h*frequency = hc/wavelength

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6
Q

de Broglie relation:

A

wavelength = h/(m*velocity)

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7
Q

Stupid space donut:

A

z^2

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8
Q

Positive ΔH and q =

A

Endothermic. Vaporization.

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9
Q

Negative ΔH and q =

A

Exothermic. Condensation.

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10
Q

Positive work:

A

Work done ON the system

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11
Q

Negative work:

A

Work done BY the system

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12
Q

Constant P:

A

Lower heat production

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13
Q

Constant V:

A

More heat production

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14
Q

Paramagnetic:

A

Has unpaired electrons. Interacts with magnetic field.

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15
Q

Diamagnetic:

A

No unpaired electrons. Does not interact with magnetic field.

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16
Q

Pauli exclusion principle:

A

No two electrons can have the same quantum number.

17
Q

Aufbau principle:

A

Orbitals fill from lowest to highest energy level.

18
Q

Hund’s rule:

A

One electrons per orbital with parallel spin until it becomes necessary to double up.

19
Q

Exceptions to Aufbau principle:

20
Q

Periodic table trends:

IE? Atomic radius? Metallic character?

A

IE = He
Radius = Rb
Metallic character = Rb

21
Q

Lowest IE =

A

Most exothermic

22
Q

Cations vs atoms vs anions

A

Cation < atom < anion

23
Q

What happens to reactivity as IE decreases?

A

Reactivity increases

24
Q

What happens to atom size as effective charge increases?

A

Atom size decreases

25
Boyle's law:
V -> 1/P
26
Charles' law:
V -> T
27
Avogadro's law:
V -> n
28
What goes up when IMF goes up?
SA, mm, viscosity, length, pressure
29
What goes down when IMF goes up?
Vapour pressure
30
What happens to viscosity when temp goes up?
Viscosity decreases
31
What happens to average energy when temp goes up?
Average energy increases
32
What happens to boiling point as pressure increases?
Boiling point increases
33
Metal/halogen reaction:
2M + X(2) -> 2MX
34
Millikan oil drop experiment:
Charge of electron
35
Rutherford gold foil experiment:
Atom model, nuclear theory