final Flashcards
(28 cards)
electronegativity trend
increases to the right, decreases going down
atomic radius trend
decreases from right to left, increases down
sigma bond
e- sit between 2 bonded atom, single bonds
pi bond
out of plane of molecules, every triple bond, 2 are pi, one is sigma, double bond, one is pi and one is sig
longer the bond
lower the energy
photon energy and wavelength equations
epho: (planck constant)(frequency)
speed of light = wavelength (frequency)
amorphus solid
without structure, no long-range structure, no sharp mp
crystalline solids
well-ordered array of atoms or molecules and have wlell defined mp
molecular solid
have moderate BP, split apart with IMF’s, formed by molecular compounds, particle type: molecule
network covalent solid
- have high MP
2. particles are held by VERY strong covalent bonds
ionic solids
- ionic compounds
- lattice pts: cations and anions
- breaking ionic bonds (stronger than IMF’s), high MP
metallic solids
- sea of highly mobile e- and nucleus of particular metal and the core electrons
- no generalization of if they all melt high or low
atomic bonds
- noble gases
2, lattice pts: atoms - to break, must disrupt dispersion forces
vaporization
liquid -> gas, ΔH gas - ΔH liq
condensation
gas -> liq, -ΔH vap
fusion
solid -> liq, ΔHf liq - ΔH f solid
freezing
-ΔH fusion
sublimation
solid - > gas, ΔH f gas - ΔH f solid
deposition
gas - > solid, -ΔH sublimation
high vapor pressure
low IMF
low vapor pressure
high IMF
dipole forces
only in polar substances
hydrogen bonds
hydrogen atom is covalently-bonded to a small, highly electronegative atom with the lone electron pairs (N, O, or F)
hydrocarbons are always
nonpolar