final Flashcards

(28 cards)

1
Q

electronegativity trend

A

increases to the right, decreases going down

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2
Q

atomic radius trend

A

decreases from right to left, increases down

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3
Q

sigma bond

A

e- sit between 2 bonded atom, single bonds

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4
Q

pi bond

A

out of plane of molecules, every triple bond, 2 are pi, one is sigma, double bond, one is pi and one is sig

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5
Q

longer the bond

A

lower the energy

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6
Q

photon energy and wavelength equations

A

epho: (planck constant)(frequency)

speed of light = wavelength (frequency)

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7
Q

amorphus solid

A

without structure, no long-range structure, no sharp mp

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8
Q

crystalline solids

A

well-ordered array of atoms or molecules and have wlell defined mp

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9
Q

molecular solid

A

have moderate BP, split apart with IMF’s, formed by molecular compounds, particle type: molecule

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10
Q

network covalent solid

A
  1. have high MP

2. particles are held by VERY strong covalent bonds

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11
Q

ionic solids

A
  1. ionic compounds
  2. lattice pts: cations and anions
  3. breaking ionic bonds (stronger than IMF’s), high MP
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12
Q

metallic solids

A
  1. sea of highly mobile e- and nucleus of particular metal and the core electrons
  2. no generalization of if they all melt high or low
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13
Q

atomic bonds

A
  1. noble gases
    2, lattice pts: atoms
  2. to break, must disrupt dispersion forces
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14
Q

vaporization

A

liquid -> gas, ΔH gas - ΔH liq

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15
Q

condensation

A

gas -> liq, -ΔH vap

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16
Q

fusion

A

solid -> liq, ΔHf liq - ΔH f solid

17
Q

freezing

18
Q

sublimation

A

solid - > gas, ΔH f gas - ΔH f solid

19
Q

deposition

A

gas - > solid, -ΔH sublimation

20
Q

high vapor pressure

21
Q

low vapor pressure

22
Q

dipole forces

A

only in polar substances

23
Q

hydrogen bonds

A

hydrogen atom is covalently-bonded to a small, highly electronegative atom with the lone electron pairs (N, O, or F)

24
Q

hydrocarbons are always

25
dispersion forces
universal force in all substances
26
polarizability
refers to the shiftability of electrons, generally increases as MM increases
27
substances with the same molar mass...
shape differences will determine which has the higher dispersion forces. the stronger dispersion forces will be applied when there can be more points of contact
28
formal charge equation
V.E - (lone pairs + 1/2 bonds)