FINAL EXAM Flashcards
(202 cards)
what are conventional fossil fuels?
the least expensive fuels to produce and supply nearly all of the energy provided by fossil fuels (coal, oil, natural gas)
what are unconventional fossil fuels?
more expensive to produce than coal, oil, natural gas, may eventually replace FF;oil shales and tar sands
what is the most widely used FF?
crude oil, then coal, natural gas
what is traditional biomass comprised of?
fuelwood, charcoal, agricultural residues, animal dung
what is the relationship between traditional biomass and agriculture?
its most widely used in rural areas where agriculture is the principal economic activity
why is coal production highest in china?
to generate electricity, power the rapid expansion of their economy
layers of the atmosphere in order
- troposphere
- stratosphere
- mesosphere
- thermosphere
characteristics of the troposphere
temperature declines with higher altitude (negative correlation between temp and altitude), lapse stops sealing in earth’s atmosphere
characteristics of the stratosphere
“just right” for ozone development, waste heat from ozone reactions warms temperature
what is the role of ozone in the stratosphere?
ozone is essential and most abundant here, where it absorbs solar energy (UV-B) that is harmful to organisms
describe the stratospheric cycle of ozone
it first forms when molecular oxygen absorbs solar energy and photodissociation occurs. ozone forms when the single oxygen atoms from photodissociation combine with molecular oxygen. the ozone gets split again when it absorbs ultraviolet radiation
stratospheric ozone vs tropospheric ozone
smaller amounts of ozone in the troposphere, but still harmful to human health and ecosystems; its considered a pollutant, it combines with NO and VOCs to form photochemical smog
how does the stability of the CFC molecule reduce stratospheric ozone
CFCs are inert chemicals meaning they do not break down easily and do not react with other chemicals; they eventually reach the stratosphere where the molecules are broken down by photodissociation, freeing chlorine, which causes a sequence of reactions in which a chlorine atom changes an ozone molecule into molecular oxygen, freeing the chlorine atom from chlorine monoxide, allowing that atom to destroy multiple atoms of ozone; O is also converted into O2 which reduces the amount of single oxygen atoms to form more ozone
what is the halogen depletion hypothesis?
- fugitive CFCs can make their way into the atmosphere
- photodissociation frees all the chlorine atoms from the og CFC molecule
- the chlorine atom reacts with O3 and O to reduce total O3 in the stratosphere
how was the halogen depletion hypothesis proved?
spy planes were turned into research vehicles equipped with special instruments and flown over the south pole where they found high concentrations of chlorine atoms in areas of low stratospheric ozone concentrations
what were the readily available forms of replacement for CFCs?
HFCs
what is lapse rate?
the rate at which temperature changes with altitude; raising a parcel of air will cause it to expand, thus cool
what is adiabatic lapse rate?
the default; a given parcel of air in which temperature change due to compression or expansion is associated with changes in altitude, but does not exchange heat with surrounding air; abt 1 degree celcius per 100 m
what is the process of cooling for the adiabatic lapse rate?
as air rises, pressure reduces, volume expands, fewer collisions between molecules occur, air cools (happens without any input)
what happens if the observed lapse rate is faster than the adiabatic lapse rate?
air parcels experience **more rapid cooling **and are cooler than surrounding air at higher altitudes, which means they are more dense and will sink back towards their og location
what happens if the observed lapse rate is slower than the adiabatic lapse rate?
air** does not cool** as quickly and becomes warmer than surrounding air at higher altitudes, making it less dense, meaning it can rise further and move away from its og location
what does the southern polar vortex do?
traps gases (CFCs)
forms polar stratospheric clouds (where the breakdown of CFCs is accelerated
how do the seasons affect the southern polar vortex?
- cold winter air forms vortex
- early spring brings increased solar radiation, photodissociation more Cl from CFCs
- in late spring, warmth returns, breaking up polar vortexes, throughout summer ozone levels increase again as polar air mixes with surroundings
why are polar vortexes less of an issue in the north pole?
- land mass is unevenly distributed –> weaker vortex, trapping less air
- comparatively warmer temperatures: limiting formation of polar winds forming vortex & limiting formation of stratospheric clouds