FINAL Review Flashcards

(62 cards)

0
Q

What is the definition of density?

A

Density = mass / volume

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
1
Q

To how many decimal places should the volume of liquid in a buret be recorded?

A

2 decimal places

0.01

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

The _____ is the curved surface that appears at the top of the liquid container ( such as a buret it pipet).

A

meniscus

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

How to calculate Rf ( ratio to front)

A

Distance of component / distance of solvent

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

True or False?

Only colored substances can be separated and identified by paper chromatography.

A

False

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

True or False?

If a component in a mixture interacts more strongly with the stationary (paper) phase, it will travel up the paper strip at a faster rate than a component that interacts more strongly with the liquid phase.

A

False

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Standard Deviation

A

s = sqrt [ sum ( xi-xo ) ^ 2 / n — 1 ]

xi = no. given ; xo = mean ; n = tot no.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

% Error

A

( observed value - true value / true value ) * 100

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What is spectroscope?

A

Tool that helps determine atomic hydrogen emission line positions.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

T or F

Electrons in a ground-state can be excited to a high- energy state by absorption of energy.

A

T

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What is

The visible region of wavelength?

A

370-700 nm

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

How to calculate wavelength?

A

1/ wavelength =
Rh • (1/lower#)^2 - (1/higher#)^2

Rh—Rydberg’s constant: 1.10•10^7”

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Wavelength in terms of energy?

A

E=hv
c=wavelength•v

h—Planck’s constant: 6.62608•10^-34
c—speed of light: 3.00•10^8

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Order from highest to lowest energy:

ultraviolet / visible / infrared

A

Ultraviolet - highest

Visible

Infrared - lowest

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

The water that is present in ionic salts are called what?

A

Water of hydration

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What is it called when some hydrates lose water to the atmosphere upon standing?

A

Efflorescence

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What is it called when some anhydrous ionic compounds will tend to absorb water from the air or other sources?

A

Hygroscopic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

What is it called when hygroscopic compounds can take up so much water from the air that they dissolve in the water they absorb?

A

Deliquescence

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

Are carbohydrates hydrates?

A

No!! Foo

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

What is a hydrate?

A

A compound whose formula includes a specific number of water molecules

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

What is the “octet rule”?

A

8 electrons ; stability

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

Can hydrogen be a central atom?

A

No, H can only form 1 bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

T or F

Molecules in which beryllium or boron are the central atom are often electron deficient.

A

T, Foo!

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
23
Q

How do you calculate the formal charge?

A

Valence electrons - dots - lines

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
24
T or F Lower magnitude of formal charges are preferred.
T
25
More negative formal charges are more _______.
Electronegative
26
What is VSEPR?
valence shell electron pair repulsion Predicts shape of a molecule
27
According to the VSEPR, electron pairs, whether bonding or nonbonding attempt to _________.
Move as far apart as possible
28
name geometric shape 2 regions of high electron density —> __________
Linear sp
29
Name geometric shape 3 regions of high electron density —> __________
Trigonal Planar sp^2
30
Name geometric shape 4 regions of high electron density —>__________
Tetrahedral sp^3
31
Name geometric shape 5 regions of high electron density —>__________
Trigonal Bipyramidal dsp^3
32
Name geometric shape 6 regions of high electron density —>__________
Octahedral d^2sp^3
33
How are electronic (geometric shapes determined)?
regions of high electron density
34
How are molecular shapes determined?
By bonds! Foo
35
Molecular Shape? ``` 1 nonbonding: Trigonal planar-_____ Tetrahedral-_____ Trigonal Bipyramidal-_____ Octahedral-_____ ```
Trigonal planar- bent Tetrahedral-Trigonal pyramidal Trigonal Bipyramidal-seesaw Octahedral-square pyramidal
36
Molecular Shape? 2 nonbonding: Tetrahedral-_______ Trigonal Bipyramidal-______ Octahedral-_______
Tetrahedral-bent Trigonal Bipyramidal-t-shaped Octahedral-square planar
37
What is polar?
Bonding pair not shared equally
38
What are isomers?
Different atomic arrangements | Physical and chemical will vary
39
What is an acid?
A substance that produces hydrogen ions, or protons
40
T or F All acids that contain hydrogens, which are bonded to carbon, are acidic.
F, foo!
41
What is molar mass?
Mass (g) of 1 mole of the compound
42
What is equivalence point?
The point in the reaction at which the number of moles of H+ furnished by the acid exactly equals the number of moles of OH- furnished by the base.
43
What is end point?
Point at which the titration should be stopped
44
How to solve a titration problem?
c-concentration v-volume concentration = moles / volume c•v=c•v (H+ = OH-)
45
Which metals are in Group II ?
Alkaline Earth Metals
46
T or F The solubility of the alkaline earth sulfates is found to decrease with increasing cation size
T Ex. BeSO4 very soluble BaSO4 very insoluble
47
What is the solubility trend?
``` Increase from bottom to top Mg- most soluble Ca Sr Ba-least soluble ```
48
Where are the halogens located?
Group 17
49
What is the trend of the halogens in order of increasing oxidizing strength?
Increase from bottom to top Cl2 strongest Br2 I2 weakest
50
Halogens exist as _______ molecules
Diatomic
51
Unlike alkaline earth metals, the halogens tend to ______ electrons and form _____
Gain | X- anions
52
T or F Halogens are oxidizing agents?
T
53
What is a halogen?
Element in group 17 | Are diatomic molecules
54
What are halides ?
Negative ion (anion)
55
What is oxidation?
Loss of electrons
56
What is an oxidizing agent?
What causes oxidation by removing e from other species. Ex. Br2 is ; Br- not
57
How to calculate molarity
Moles of solute / liters of solution
58
Remember! Energy= frequency Energy, frequency = 1 / wavelength
E&f proportional E, f inverse proportional to wavelength
59
E=h•c/wavelength
Remember formula
60
Trans isomer
Nonpolar
61
cis isomer
Polar