Final review Flashcards
addition of OH and Br to (alkene to alkane)
Br2+ H20
Br attaches and makes a triangle, h20 attacks from the other side and opens up triangle
maokovnikov addition of OH
maokovnikov addition of OH to alkene
Oxymerc/demurc
Hg(OAC)2, H20
NaBH4, OH-
anti addition of OH to alkene
Bh3, THF
H202,h20, NaOh
mcpba forms a ___ on a _____
it attacks the_____
forms a triangle bond of O
on an alkene
it attacks the richest pi bond (the one with more activating groups attached)
syn addition of two Oh’s on (alkene–>alkane)
vicinal diol sythesis
OSO4,THF
H2s
antimarkovnikov addition of Br (alkene to alkane)
HBr and ROOR (peroxide)
Internal alkyne synthesis (alkane to alkyne)
2NaNH2
NH3 (l)
terminal alkyne synthesis (alkane to alkyne)
3NaNH2
NH3(l)
addition of Br(s) to terminal alkyne
H-Br
adds markovnikovly
addition of halogen to internal alkynes
Br2
markovnkov addition of =O (alkyne to alkane)
H20, H2SO4
first adds OH (enol) then touts to ketone
alkyne to alkane
H2, PD
alkyne to alkene
H2 and Lndlards
E alkene synthesis
anti addition of H’s (alkyne to alkene
Na
Nh3
antimarkovnikov addition of =O (alkyne to alkene)
BH3,THF
H202,OH-
if Borane is big it doesn’t add c=o
ozonolysis of an alkene can make?
aldehydes and ketones
reagents: 03, (Ch3)2S
addition of Br to allylic (one carbon away from double bond)
NBS CCl4 hv
addition of hydrogen and halogen 1,4
Hx and high T
additionof hydrogen halogen 1,2
HX and low T
addition of halogens 1,4
X2 and high T
addition of halogens 1,3
x2 and low T
conroatory
4n with heat
4n+2 with light
hydrogenation of benzene
H2, catalys
addition of halogen to benzene
x2, Fex3
