First Law of Thermodynamics (Closed System) Flashcards

(42 cards)

1
Q

form of energy that is transferred between two systems (or a system and its surroundings) by virtue of a temperature difference

A

heat

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2
Q

state functions

A

Pressure, Temperature, Volume, Mass, Internal Energy

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3
Q

Conditions for reversibility

A

Absence of friction
Quasi-static process
No heat loss
Ideal fluid

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4
Q

based on the law of conservation of energy

A

first law of thermodynamics

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5
Q

path functions

A

heat and work

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6
Q

performed whenever a force acts through a distance

A

work

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7
Q

energy that a system possesses as a result of its elevation in a gravitational field

A

potential energy

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8
Q

Real world thermodynamic processes are?

A

irreversible

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9
Q

thermal energy transferred to or from the system to overcome the intermolecular forces between the molecules resulting to a phase change

A

Latent energy or Latent heat

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10
Q

energy that a system possesses as a result of its motion relative to some reference frame

A

kinetic energy

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11
Q

represents the heat storage capability of a material

A

specific heat

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12
Q

defined as the energy required to raise the temperature of a unit mass of a substance by one degree

A

specific heat

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13
Q

sum of the internal energy and flow work

A

enthalpy

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14
Q

the internal energy of a system associated with the kinetic energies of the molecules

A

sensible energy

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15
Q

a process whose direction can be reversed by infinitesimal changes in some properties of the surroundings, such as pressure

A

reversible process

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16
Q

four components of internal energy

A

sensible, latent, chemical, and nuclear

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17
Q

sum of all the microscopic forms of energy

A

internal energy

18
Q

the energy required to raise the temperature of a unit mass of a substance by one degree as the volume is held constant

A

Specific heat at constant volume

19
Q

Constant Temperature

A

ISOTHERMAL PROCESS

20
Q

a process in which the system and the surroundings do not return to their original condition once the process is initiated

A

irreversible process

21
Q

thermal energy transferred to or from the system to overcome the intermolecular forces between the molecules resulting to a phase change

22
Q

refers to the process where an ideal gas expands into a vacuum without any resistance, work being done, or heat transfer

A

free expansion of an ideal gas

23
Q

consigned the caloric theory of heat to a footnote in history

A

Joule’s experiment

24
Q

“The energy of a thermodynamic system in equilibrium is partitioned equally among its degrees of freedom.”

A

equipartition theorem

25
Constant Volume
ISOCHORIC PROCESS
26
It is recognized only as it crosses the boundary of a system
heat
27
An idealized concept that serves as a theoretical benchmark for understanding real processes.
reversible process
28
the energy required to raise the temperature of a unit mass of a substance by one degree as the pressure is held constant
Specific heat at constant pressure
29
refer to the sensible and latent forms of internal energy
thermal energy
30
the internal energy associated with the atomic bonds in a molecule
chemical energy
31
Lavoisier called heat as?
calorific fluid
32
what type of function is enthalpy
state function
33
𝐶𝑣 and 𝐶𝑝 are dependent of?
temperature
34
the internal energy associated with the atomic bonds in a molecule
nuclear energy
35
is energy in transition
heat
36
the system can be returned to its initial state without any net change in the surroundings
reversible process
37
Constant Pressure
ISOBARIC PROCESS
38
property whose value doesn’t depend on the path taken to reach that specific value is known as
state function or point function
39
thermal energy transferred to or from the system which changes the kinetic energy of molecules resulting to a temperature change
Sensible energy or Sensible heat
40
are the mechanisms of energy transfer
heat and work
41
Internal energy is related to the?
molecular structure and degree of molecular activity
42
the internal energy associated with the intermolecular force of attraction between molecules
latent energy