Flame Tests Flashcards
(17 cards)
Flame tests are used to test for…
cations - metal ions
Steps for a flame test:
- take a nichrome wire loop
- clean it by dipping it into hydrochloric acic, then rinsing it in distilled water before running it through the bunsen burner.
- dip the wire loop into the compound you want to test for
- hold the wire in the blue part of a bunsen burner
- see what colour the flame burns
a limitation of flame tests
A limitation of the flame test is that if you have 2 or more different metals in your sample, then the colours of the flames will mix together, and you probably won’t be able to tell which metals you have.
colours flame test
sodium - yellow
lithium - crimson
potassium - lilac
copper - green
calcium - orange-red
Alternative to flame tests:
Another test we can do for metal ions is react them with a solution of sodium hydroxide (NaOH), and see what colour the solution turns.
This is possible because some metal ions form coloured precipitates when they react with hydroxide ions, and these coloured precipitates then determine the colour of the solution.
copper and hydroxide ions
blue
calcium and hydroxide ions
white
iron II and hydroxide ions
green
magnesium and hydroxide ions
white
aluminium and hydroxide ions
initially white, but if the solution is in excess, it might turn colourless
iron III and hydroxide ions
brown
comparing metals with flame tests can be difficult…
since they might have similar colours/ a sample may have multiple different metals
Instead of a flame test we can use a….
spectroscope in a test called flame emission spectroscopy
every metal ion produces…
a different pattern of wavelengths
the main advantage of flame emission spectroscopy is…
if there are multiple metal ions in a sample, the spectrum will show the lines for all of them.
if scientists have a sample of an unknown metal then they can compare that to the spectrum of known metals and figure out what ions they are composed of.
through this they can also find the concentration of ions
Pros and cons of flame tests (manual method) and flame emission spectroscopy (instrumental method)
instrumental:
very accurate/ fast/ sensitive
manual:
basic and cheap