Forel. Flashcards

(42 cards)

1
Q

What is nucleosynthesis?

A

The process that forms new atomic nuclei from pre-existing nucleons (fusion), primarily protons and neutrons.

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2
Q

How far can fusion of nuclides go?

A

All the way to 56Ni

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3
Q

How are heavier elements made (heavier than Ni)?

A

Neutron capture:

  • S-process, slow
  • R-process, fast
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4
Q

What are the three main types of meteorites?

A

Stony, iron, stony-iron

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5
Q

What are the common rocks of the continental crust and islandic arc with main minerals and chemical composition?

A

Granite/rhyolite - feldspar, quartz - much SiO2, less FeO and CaO, very little MgO

Diorite/andesite - feldspar, quartz, pyroxene - less SiO2, more Al2O3 and others

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6
Q

What are the common rocks of the oceanic crust?

A

Gabbro/basalts - feldspar, pyroxene, olivine - less SiO2, more CaO

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7
Q

What are the common rocks of the mantle?

A

Peridotite - olivine, pyroxene - less SiO2 than the others, much MgO.

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8
Q

What does refractory mean?

A

Any material that has a relatively high equilibrium condensation temperature is called refractory.

Super: Re, Os, W, Zr

Refractory: Al, Ca, Ti, REE

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9
Q

What are siderophile elements?

A

Iron-loving, e.g., gold, palladium, chromium etc.

Transitional metals

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10
Q

What are lithophile elements?

A

Elements that remains close to the surface because they combine readily with oxygen.

E.g., Al, Ca, Cl, Rb etc.

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11
Q

What are chalcophile elements?

A

Remain close to the surface because they combine with sulfur

Ag, As, Bi, Ga, Ge.

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12
Q

What are atmophile elements?

A

Remain on or above the surface (volatile)

E.g., H, C, N, and noble gases

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13
Q

What permits partial melting?

A

When mixtures of molecules that form solutions in the solid state, melt over a range of temperatures - not ONE temperature.

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14
Q

Which minerals will yield a melt that differ in composition from that of the mineral that is melting?

A

Minerals with solid solution, unless mineral is completely melted -> then same composition in melt as mineral.

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15
Q

What is the upper crust composition?

A

Granodioritic

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16
Q

What are the composition of the middle and lower crust?

A

Middle: andesitic
Lower: basaltic

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17
Q

How is the layering of the oceanic crust?

A
  1. Sediment
  2. Basaltic pillows
  3. Sheeted dikes (ganger)
  4. Isotropic gabbro /layered under
18
Q

What can systematic variations of the MORB composition be explained by?

A
  • Fractional crystallization
  • Ridge-hotspot interactions
  • Degree and depth of melting
19
Q

What is the distribution coefficient?

A

When a mineral is in chemical equilibrium with a liquid, elements are partitioned between the phases according to their chemical activity in each.

Conc. in mineral/conc. in liquid =D

20
Q

Define batch melting

A

Simplest model for partial melting of a complex mineral assemblage.

Liquid remains at the site of melting and is in chemical equilibrium with the solid until mech. conditions allow it to escape as a batch.

21
Q

Describe the batch melting equation

A

Cl/Ci = 1/ (D(1-F)+F

The smaller the degree of partial melting, the higher the concentration of an inkel.

The lower the D, the higher conc. of element.

22
Q

What ar the two main subduction types?

A

Chilean: young lithosphere, shallow dip of W-B, back-arc compression, crustal melts.

Mariana: old lithosphere, steep dip of W-B, back-arc extension, mantle partial melts.

23
Q

What happens when adding volatiles to mantle?

A

The temperatures of solidus are strongly depressed.

24
Q

Name 3 dehydration reactions

A

Amphibole -> CPX
Albite + Epidote -> Plagioclase
Serpentine -> Olivine

25
What are the immobile elements?
HREE (Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu), Ti, Hf, Zr, Ta, Nb. Unmodified under subduction
26
What are the mobile elements?
Sr, Pb, K, Ba, Rb - mobilized in fluids during subduction (shallow) LREE (La, Ce, Pr, Nd, Pm, Sm), U, Th - mobilized in partial melts during subduction (deep).
27
What is a primary magma (basalt) fractional crystallized into?
Basaltic andesite, Andesite, Dacite, Rhyolite
28
What are the mechanisms of crustal growth?
- Subduction-related volcanism - Accretion of island arcs and oceanic plateaus - Continental volcanism - Underplating - Intrusion by small-degree melts
29
What is the full CaCO3 dissolution reaction?
CaCO3 + H2CO3 Ca2+ + 2HCO3
30
What are the guidelines for weathering equations?
1. Al is conserved 2. Si in excess as H4SiO4 3. Na, K, Mg, Ca as ions in solution 4. Balance O by adding H2O 5. Balance H by adding H+
31
What are the factors controlling the dissolution rates?
1. Primary mineral 2. Reaction solution 3. Microbial influence 4. Temperature
32
When is Eh positive?
When water is in equilibrium with O2 in atm. (oxidizing Environment) Mine water, rain, streams, oceans
33
When is Eh negative?
When water is isolated from atm (reducing environment) Waterlogged soils
34
What is the complete pyrite dissolution reaction?
4FeS2 + 15O2 + 14H2O -> 4Fe(OH)3 + 8SO4 + 16H+
35
What are the different redox zoning in sediments?
- Aerobic respiration - Denitrification - Mangan reduction - Iron reduction - Sulfate reduction - Methanogenesis
36
What is the chemical composition of weathered rock?
Loss of: Si, Ca, Mg, Na, K, Mn, P Gain of: Al, Fe, Ti, LOI (water, CO2 from carbs, SO2 from sulfides)
37
What is the average stream water composition?
Ca2+ and HCO3- dominate Na+ > K+ Ca2+ > Mg2+ SO4- > Cl-
38
What is the composition of oceans?
Cl, Na, SO4, Mg, Ca, K, HCO3
39
How is the mass balance for major elements in the oceans?
input = output
40
What is the input of mass in the ocean?
1. Discharge of river water 2. ion exchange between seawater and suspended sedis, 3. ion exchange between seawater and hot basalt
41
What is the output of mass in the ocean?
1. Burial of pore water 2. Ion exchange and water-rock interactions 3. Weathering/diagenesis of seeds and ocean crust 4. Precipitation of carbonates, silica, sulfides, sulfates, phosphates.
42
What is supercritical water?
At 407 degree and 298 bar, the water is no longer liquid or gas