Forensic chemistry Flashcards

(32 cards)

1
Q

What is Catenation?

A

The ability to form bonds between atoms of the same element

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2
Q

What is the suffix and example of an alkane?

A

-ane
Ethane

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3
Q

What is the suffix and example of an Alkene?

A

-ene
Ethene

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4
Q

What is the suffix and example of an Alkyne?

A

-yne
Ethyne

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5
Q

What is the suffix and example of an Haloalkane?

A

halo-
Chloroethane

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6
Q

What is the suffix and example of an Alcohol?

A

-ol
Ethanol

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7
Q

What is the suffix and example of an Aldehyde?

A

-al
Ethanal

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8
Q

What is the suffix and example of an Ketone?

A

-one
Ethanone

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9
Q

What is the suffix and example of an Carboxylic acid?

A

-oic acid
Ethanoic acid

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10
Q

What is the suffix and example of an Acyl chloride?

A

-oyl chloride
Ethanoyl chloride

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11
Q

What is the suffix and example of an Amide?

A

-amide
Ethanamide

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12
Q

What is the suffix and example of an Ester?

A

-yl -oate
Methyl ethanoate

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13
Q

What is the suffix and example of an Nitrile?

A

-Nitrile
Ethanenitrile

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14
Q

What is the suffix and example of an Amine?

A

-amine
Methylamine

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15
Q

What is the suffix and example of an Nitro?

A

Nitro -
Nitroethane

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16
Q

What is the suffix and example of an Sulphonic acid?

A

-sulphonic acid
benzene sulphonic acid

17
Q

What is the suffix and example of an Ether?

A

-oxy -ane
Ethoxyethane

18
Q

What is a free radical?

A

Reactive species which possess an unpaired electron

19
Q

What are some ways a free radical is formed?

A

Homolytic fission of covalent bonds
Formed during chlorination
Formed during thermal cracking

20
Q

What are the conditions needed in the Chlorination of Methane?

A

Uv light
Sunlight

21
Q

What type of reaction is the chlorination of methane?

A

Free radical substitution

21
Q

What are the bond angles around a C=C bond?

22
Q

What is CIS isomerism?

A

Groups/atoms are on the same side of the double bond

23
Q

What is Trans isomerism?

A

Groups/atoms are on Opposite sides across the double bond

24
What mechanism do Alkenes often undergo?
Electrophilic addition
25
What is the structure of a carbonyl group?
C=O bond bond is polar due to electronegativity
26
How are aldehydes formed?
Oxidation of primary alcohols
27
How are Ketones formed?
Oxidation of secondary alcohols
28
Where do carbonyls have an IR peak?
1600-1900cm-1
29
What compound forms an orange precipitate with carbonyls?
2,4-dinitrophenylhydrazine
30
What is tollens reagent and what does it do?
Ammoniacal silver nitrate Oxidises aldehydes forming a silver mirror
31
What is the equation involving the silver mirror test?
[Ag(NH3)2]+