Formulae, equations and amount of substance Flashcards

(32 cards)

1
Q

What are moles

A

.The amount of substance that
.Contains the same number of particles
.as the number of carbon atoms
.in exactly 12g of 12C

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2
Q

What is the Avogadro constant

A

.Very large

.Approximatey 6.02 X10 power 23

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3
Q

What is the relative atomic mass

A

The weighted mean mass of an atom of an element compared to 1/12th the mass of 12C atom

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4
Q

What is the relative formulae mass

A

Calculated by adding together all Ar value for all the atoms present in a unit of a substance

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5
Q

What is molar mass

A

.Is the mass per mole of a substance

.has the units gmol-1

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6
Q

Whats the formulae for calculating moles

A

n=M/mr

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7
Q

What is a molecular formulae

A

Shows the actual numbers of atoms of each element in its molecules

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8
Q

What is the molecular formula for butane

A

C4H10

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9
Q

What is an empirical formulae

A

The simplest whole number ratio of the atoms of each element it contains

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10
Q

What’s the empirical formulae for butane

A

C2H5

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11
Q

How are organic compounds represented

A

Using structural formula

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12
Q

What is Avogadro’s law

A

It states that equal volumes of gases under the same conditions of temperature and pressure contain the same number of molecules

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13
Q

When does the volume of a fixed amount of gas increase

A

as the:
Temperature increases
Pressure Increases

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14
Q

What’s the molar mass of any gas

A

24.0dm3

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15
Q

What’s the ideal gas equation

What does each one stand for

A
Pv=nRT
P=Pressure in pa
V=volume in m3
n=amount of gas in  mol
R=gas constant 8.31
t=temeprature in K
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16
Q

Whats the formulae for concentration

17
Q

How do you convert cm3 —>dm3

A

divide by 1000

18
Q

How do you convert dm3 to cm3

A

multiply by 1000

19
Q

What is a titration

A

A method in which the volumes of two reacting solutions are measured so that the concentration of one of the solutions can be determined

20
Q

What are the main steps of an acid-alkali titration

A

1) Use a pipette to transfer 25cm3 of alkali to the conical flask and added some indicator
2) Add acid from the burette to the flask until the endpoint is reached
3) Record the burrette reading before and after adding the acid

21
Q

What is meant by the following words:

a) Meniscus
b) Endpoint
c) Titre
d) Concordant results
e) Equivalence point

A

a) The curve in the upper surface of the liquid
b) Where the indicator first changes color
c) The volume of solution added to reach the endpoint
d) When two or more titres are within 0.10cm3 of each other
e) Where the reaction is exactly completed

22
Q

Give 5 tips for accurate results

A

1) Add only a few drops of indicator
2) keep the burette verticle
3) Add dropwise near the endpoint
4) Stop adding when the indicator first changes color
5) Record reading to 0.05cm3

23
Q

What are the 4 steps you need to take for titration calculations

A

1) Calculate the mean titre of the titrant
2) Calculate the amount of solute in the titrant
3) Calculate the amount of solute in the analyte (unknown solution)
4) Calculate the concentration of the analyte

24
Q

What needs to be selected in order to calculate mean titre

A

Two concordant results

add them together and divide by 2

25
What's the expression for percentage yield
Percentage yield = actual yield/theoretical yield X100
26
What are three reasons why the percentage yield is usually less than 100%
1) The reaction may be reversible and not go to completion 2) Side reactions may lead to by-products 3) Product may be lost during purification
27
What is the definition of the following words: a) desired products b) Yield c) Actual Yield d) Theoretical Yield
a) Useful substances you want to make b) The mass of desired product obtained in a reaction c) The measured yield from a particular reaction d) The maximum possible yield determined from reacting mass calculations for a reaction
28
What is the atom economy
A measure of how many atoms of the reactant end up in the desired product
29
What's the equation of atom economy
Molar mass of the desired product ---------------------------------------------- X100 Sum of the molar masses of all products
30
What does it mean if there's high atom economy
There is less waste to dispose of
31
How can the atom economy be improved
If by-products are sold rather than disposed
32
What type of reactions usually have 100% atom economy
Addition reactions