formulas Flashcards

(41 cards)

1
Q

What is the pressure formula?

A

Pressure = Force / Area

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2
Q

What is the Ideal Gas Law?

A

PV = nRT

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3
Q

What is Dalton’s Law of Partial Pressures?

A

P(total) = P1 + P2 + P3 + ….

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4
Q

What is Boyle’s Gas Law (and what is fixed)?

A

P1V1 (n and T are fixed)

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5
Q

What is Charles’ Gas Law (and what is fixed?)

A

V1/T1 (n and P are fixed)

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6
Q

What is Avogadro’s Gas Law (and what is fixed)?

A

V1/n1 ( T and P are fixed)

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7
Q

What’s the formula for finding total vapor pressure?

A

P(total) = P(atm) = P(gas) + P(water)

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8
Q

At STP, what atmosphere do we use?

A

1 atm

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9
Q

At STP, what temperature do we use?

A

273.15K

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10
Q

If we change the ideal gas law, to solve for Molar mass, what would the equation look like?

A

M = mRT/PV

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11
Q

If we change the ideal gas law, to solve for density, what would the equation look like?

A

d = PM/RT

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12
Q

What is the formula to find partial pressure?

A

P1/P(total) = n1/n(total)

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13
Q

What is the conversion of torr to atm?

A

760 torr = 1 atm

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14
Q

What is the conversion of atm to mmHg?

A

1 atm = 760 mmHg

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15
Q

First Law of Thermodynamics

A

qsystem= -qsurr

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16
Q

Total energy of a system

A

∆E = heat (q) + work (w)

Heat is the diff. in T between surr. and sys. and w the work applied

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17
Q

Calorimeter equation

A

qcalorimeter= heat capacitycalorimeter * ∆T

18
Q

Graham’s Law of Effusion

A

Reff∝ 1/√M

Reff is inversely proportional to the square root of M.

19
Q

When comparing eff. rates for two gases at same temp.

A

RateA/RateB = √MB/√MA

This proves that Graham’s Law of effusion is true

20
Q

barometric equation

A

Pgas=Patm,
Pgas=Patm-∆h,
Pgas=Patm+∆h

21
Q

Combined gas law

A

P1V1/T1=P2V2/T2

22
Q

Enthalpy ∆H

For limiting reactant

A

∆Hrxn=-qrxn/mols of limited reactant

23
Q

At STP, what is 1 mole of any gas?

A

1mol any gas = 22.4L (not exact)

24
Q

Vrms

A

Vave = √((3RT)/M)

25
In van der walls equation, what does a represent? b?
a represents the effect of intermolecular attractive forces on pressure. b represents the effect of particle size on volume.
26
What is a state function?
The property of a system where the starting and ending points are essential, not *how* it got from point a to point b.
27
In terms of calorimetry, what is ∆Hsoln?
∆Hsoln = (qsolute)/moles of solute
28
∆Hrxn heat abosrbed/released by the whole reaction
∆Hrxn = (qrxn -)/mols of limiting reactant
29
Converting from Celsius to Fahrenheit
F=(ºC*9/5)+32
30
Converting from Fahrenheit to Celsius
C=(ºF-32)5/9
31
Equation used for a whole system/calorimeter
q=C∆T | C=specific heat capacity for entire calorimeter/system.
32
Enthalpy change's relation to internal energy.
∆H=∆E+P∆V
33
calculating actual yield
actual yield = (% yield)(theoretical yield)
34
Average amu calculation
Average amu = ∑(abundance * amu)
35
% yield
actual/theoretical
36
m/m
g solute / g solution * 100%
37
w/v
mass/volume * 100
38
v/v
v/v (mL solute/mL solution) * 100%
39
Dilutions formula
M1V1=M2V2
40
standard thermochemical conditions (STC)
25ºC 1 atm and 1M
41
∆Hºrxn
∆Hºrxn = ∑m∆ Hºf(products) - ∑n∆Hºf(reactants) | set the equation to a net ionic equation first and then use this