Foundations in Chemistry Flashcards

(67 cards)

1
Q

what is relative atomic mass?

A

the weighted mean mass of an atom compared to 1/12 of a C-12 atom

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2
Q

what is an isotope?

A

different forms of the same element with same proton and electron numbers but different neutron number

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3
Q

what is ionic bonding?

A

the electrostatic attraction between oppositely charged ions

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4
Q

what is covalent bonding?

A

the electrostatic attraction between bonding electrons and the nuclei of bonded atoms

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5
Q

what is metallic bonding?

A

electrostatic attraction between positive ions and delocalised electrons

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6
Q

what is relative isotopic mass?

A

the mass of an isotope compared to 1/12 of a C-12 atom

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7
Q

what is molecular formula?

A

the actual number of elements in a compound

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8
Q

what is empirical formula?

A

the smallest number ratio of elements in a compound

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9
Q

how many electrons can be in the first shell?

A

2

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10
Q

how many electrons can be in the second shell?

A

8

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11
Q

how many electrons can be in the third shell?

A

18

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12
Q

how many electrons can be in the fourth shell?

A

32

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13
Q

what are the four orbitals called?

A

s, p, d, f

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14
Q

what is an orbital?

A

a region around a nucleus of an atom that can hold up to 2 electrons of opposite spins

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15
Q

what is the shape of an s-orbital?

A

spherical

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16
Q

what is the shape of a p-orbital?

A

3D dumbbell

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17
Q

what is the formula for ammonium?

A

NH4 (+)

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18
Q

what is the formula for silver?

A

Ag (+)

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19
Q

what is the formula for zinc?

A

Zn (2+)

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20
Q

what is the formula for hydroxide?

A

OH (-)

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21
Q

what is the formula for nitrate?

A

NO3 (-)

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22
Q

what is the formula for manganate(VII)?

A

MnO4 (-)

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23
Q

what is the formula for hydrogencarbonate?

A

HCO3 (-)

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24
Q

what is the formula for hydrogensulfate?

A

HSO4 (-)

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25
what is the formula for carbonate?
CO3 (2-)
26
what is the formula for sulfate?
SO4 (2-)
27
what is the formula for dichromate?
Cr2O7 (2-)
28
what is the formula for phosphate?
PO4 (3-)
29
what is an acid?
proton donor
30
what is a base?
proton acceptor
31
what is an alkali?
base that releases OH- ions when dissolved in water
32
what is a strong acid?
completely dissociates into its ions in aq solutions
33
what is a weak acid?
partially dissociates into its ions in aq solutions
34
what is a salt?
produced when the H+ ion of an acid is replaced by a metal ion/NH4 (+)
35
how to work out number of particles?
moles x avogadros constant
36
how to work out moles?
mol = mass / Mr
37
how to work out percentage yield?
actual mass/mol / theoretical mass/mole x 100
38
how to work out atom economy?
Mr of desired product / Mr of all products x 100
39
how to work out mole from volume and conc?
mole = conc x vol (/1000)
40
how to work out mole from volume?
mole = vol / 24/24000
41
what is hydrated?
when water of crystallisation is present in a compound
42
what is anhydrous?
when water of crystallisation is removed from a compound?
43
what is water of crytallisation?
water present in a compound giving it a crystalline appearance
44
what is reduction?
gain of e-
45
what is oxidation?
loss of e-
46
what is disproportion?
when an element is reduced and oxidised
47
what is the oxidising agent?
reagent that is reduced
48
what is the reducing agent?
reagent that is oxidised
49
why is metallic bonding good conductor?
mobile e- can carry charge
50
why is aqueous ionic bonding good conductor?
mobile ions can carry charge
51
what is a dative covalent bond?
when one atom provides both electrons being shared
52
what is average bond enthalpy?
measurement of covalent bond strength
53
what is the bond angle of a linear shape?
180 degrees
54
what is the bond angle of a tetrahedral shape?
109.5 degrees
55
what is the bond angle of a trigonal planer shape?
120 degrees
56
what is the electron-pair repulsion theory?
- bonding pairs repel as far apart as possible - lone pairs repel more than bonding pairs
57
what is the bond angle of an octohedral?
90 degrees
58
how to work out bond angle of shape with lone pairs?
minus 2.5 from bond angle of shape
59
why makes a molecule non-polar?
- symmetrical shape - dipoles cancel out - no net dipole across molecule
60
what makes a molecule polar?
- asymmetrical shape - dipoles dont cancel out - one element is more electronegative
61
which molecules have induced dipole-dipole forces?
non-polar covalent molecules
62
which molecules have permanent dipole forces?
polar covalent molecules (without H-N, H-F, H-O)
63
which molecules have hydrogen bonds?
polar covalent molecules with H-N, H-F, H-O
64
how to show a hydrogen bond?
dashed line
65
which IMF is strongest to weakest?
- hydrogen - permanent - induced
66
what are the two properties of water?
- ice is less dense than water due to further apart hydrogen bonds - water has higher than expected mp/bp due to relatively strong hydrogen bonds
67
which covalent molecules are giant?
- diamond - graphene - silicon dioxide - silicon - buckminster fullerene